Alternatived Products of [ 337535-27-0 ]
Product Details of [ 337535-27-0 ]
CAS No. : | 337535-27-0 |
MDL No. : | MFCD06201352 |
Formula : |
C13H11BrO
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
263.13
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 337535-27-0 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 337535-27-0 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 337535-27-0 ]
- 1
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[ 337535-27-0 ]
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[ 162607-20-7 ]
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[ 1233720-83-6 ]
- 2
-
[ 1003858-50-1 ]
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[ 17878-47-6 ]
-
[ 337535-27-0 ]
Yield | Reaction Conditions | Operation in experiment |
71% |
With dichloro(N-(diphenylphosphino)-N-isopropyl-1,1-diphenylphosphinamine) digold(I); [bis(acetoxy)iodo]benzene; silver(I) 4-methylbenzenesulfonate; In 1,1,2-trichloroethane; at 110℃; for 1h;Schlenk technique; Inert atmosphere; |
General procedure: To a dried Schlenk tube was added 1f (8.9 mg, 0.01 mmol), AgOTs (11.2 mg, 0.04mmol), PhI(OAc)2 (84.0 mg, 0.26 mmol) and anhydrous TCE (1,1,2-trichloroethane, 1mL) at room temperature under an argon atmosphere. After vigorously stirring for 30min at room temperature, 2 (0.20 mmol) and 3 (0.26 mmol) in 1 mL anhydrous TCEwas added under an argon atmosphere, and then the reaction mixture was stirred at 110oC for 1-2 h. The reaction mixture was concentrated under reduced pressure and theresulting residue was purified by flash chromatography on silica gel (petroleumether/ethyl acetate) to give desired coupling product 4. |