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CAS No. : | 34373-96-1 | MDL No. : | MFCD00092257 |
Formula : | C16H12Br2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | YHEMDXGFCREMGG-UHFFFAOYSA-N |
M.W : | 364.07 | Pubchem ID : | 609355 |
Synonyms : |
|
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P280-P305+P351+P338-P310 | UN#: | 3261 |
Hazard Statements: | H302-H314 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
69.2% | at 150℃; for 12 h; Inert atmosphere | Use a 50 mL two-port bottle as the reaction vessel.The reaction device is subjected to anhydrous treatment,Reflux reaction, argon gas protection,Add in a two-port bottleCompound 1 (421 mg, 1.15 mmol, 1.0 eq),Triethyl phosphite (6mL),The oil bath was refluxed at 150 ° C for 12 h.The mixture in the two-necked bottle was extracted with a small amount of ethyl acetate and water for 5 times using a separatory funnel.Pour the organic phase into a round bottom flask and spin dry.Add silica gel and mix.After stirring evenly, the product was spin-dried by column chromatography (dichloromethane / ethyl acetate = 1/2: v / v).Obtained a yellow product of 1.813 g,That is compound 2,The theoretical yield is 2.628g,The yield was 69.2percent. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68% | at 180℃; for 8 h; | The 9,10-Bis(bromomethyl)anthracene (1.2 g, 3.3 mmol) was mixed with triethyl phosphate (10 mL). Resulting mixture was refluxed at 180°C for 8 h in order to obtain the pure product. The solvent was then removed at vacuum and the residue product was purified by a column chromatography on silica gel using ethyl acetate/CH2Cl2 as the eluent. Yield: 1.05 g (68percent). 1H NMR (300 MHz, CDCl3): δ 8.38 (m, 4H), δ 7.6 (m, 4H), 4.25 (d, 4H), 3.8 (m, 8H), 1.06 ppm (t, 12H). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
89.98% | With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; chloroform; for 1.8h;Reflux; | Take a 250ml three-necked flask, add 9,10-dimethylanthracene (compound B1, 1.13g, 5.48mmol), N-bromosuccinimide (2.16g, 12.12mmol), benzoyl peroxide (20mg , 82.4μmol), 20mL of chloroform, 40mL of carbon tetrachloride, refluxed for 1.8h. Then, the reaction solvent was removed by vacuum drying, and 50 mL of methanol was added. The mixture was stirred for 10 minutes, filtered, and washed with 5 mL of methanol. The solid powder was dried under reduced pressure to obtain a yellow solid powder (compound B2, 1.7916 g, 89.98%). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
95% | With hydrogen bromide; acetic acid; at 60℃; for 12h;Inert atmosphere; | Use a 50mL two-port bottle as the reaction vessel.The reaction device is subjected to anhydrous treatment,Argon protection.In the dual-port flask was added anthracene (2.67g, 15mmol, 1.0eq),Paraformaldehyde (2.972g, 33mmol, 2.5eq),Ventilate, add under stirringHydrobromic acid (5 mL, 30% wt HOAc).The oil bath reacted at 60 C for 12 h.The product was dried under reduced pressure.Toluene was added dropwise at 60 C in an oil bath and shaken to dissolve the crude product.Hot and suction filtration,The filtrate was cooled to room temperature and then filtered.The toluene was again added dropwise at 60 C in an oil bath and shaken to dissolve the crude product.Hot and suction filtration,The filtrate was cooled to room temperature and then filtered.Obtaining a yellow product of 3.878 g,That is Compound 1,The yield was 95%. |
87% | With hydrogen bromide; acetic acid; at 80℃; | Anthracene (10g, 56mmol) and paraformaldehyde (3.4g) were dissolved in acetic acid (40mL) and stirred uniformly at room temperature.Hydrobromic acid in acetic acid (33wt%, 55mL) was added dropwise to the above solution within one hour,Then heat up to 80 , keep it overnight,After cooling to room temperature, the resulting solid was filtered and washed with water,Dry in air to get a crude product.Then recrystallize (1 L) in toluene to obtain compound 15 (18.7 g, 87%) as a yellow solid. |
54% | With aluminum (III) chloride; hydrogen bromide; In acetic acid; at 60℃; for 6h; | The synthesis route of An-CHO was displayed in Scheme S1. At first, the intermediate products of 9,10-bis(bromomethyl)anthracene and 9,10-bis(diethylphosphorylmethyl)anthracene were synthesized by previous report (Zhang, Wang, Zhu, et al., 2013). For the preparation of 9,10-Bis(bromomethyl)anthracene: the mixture of anthracene (7.6 g, 40 mmol), (CH2O)n (4.8 g), AlCl3 (5.0 g) and solution of 33% HBr in acetic acid (60 mL) was stirring at 60C for 6 h. The obtained solid was put into water and stirring 30 min to remove residual reactants, filtration and dry in vacuum one night. The residue product was recrystallized in toluene three times to obtain yellow solid. Yield: 7.8 g (54%). 1H NMR (300 MHz, CDCl3): δ 8.38 (m, 4H), δ 7.65 (m, 4H), δ 5.54 ppm (m, 4H). |
21% | With hydrogen bromide; cetyltrimethylammonim bromide; In water; acetic acid; at 80℃; for 5h;Inert atmosphere; | To a round-bottom flask containing anthracene (1.00 g, 5.60 mmol), paraformaldehyde (0.17 g, 5.6 mmol), CTAB (22.4 mg, 0.06 mmol) and acetic acid (1.4 mL), 4.12 mL HBr aqueous solution (concentration 40%) were added dropwise. The flask was placed under N2 at 80 C for 5 h. The mixture was cooled to room temperature and filtered, washed with 100 mL distilled water, dried under vacuum and recrystallized from toluene to give yellow needle-shaped crystals, 0.43 g, 21% yield. 1H NMR (400 MHz, CDCl3, ppm): 7.57-7.59 (m, 4H), 7.36-7.33 (m, 4H), 4.46 (s, 4H). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
92% | With hydrogen bromide; cetyltrimethylammonium bromide; acetic acid; at 80℃; | / V, / V- D i b u t y 11 h i o p h c n - 2 - a m i n c (2.17, 160 mg, 0.8 mmol) obtained in step 1 and croconic acid (55 mg, 0.4 mmol) was refluxed in to luene/l -butanol (1 : 1, 10 ml) for a few minutes. The reaction mixture was evaporated to dryness. The crude product was purified by gradient column chromatography (heptane to 50 % ethylacetate in heptane) affording 3.3 as a dark solid (159 mg, 78 %). 'H NMR (500 MHz, Chloroform-;/) d 8.85 - 8.71 (m, 2H), 6.50 - 6.43 (m, 2H), 3.56 - 3.52 (m, 8H), 1.77 - 1.71 (m, 8H), 1.45 - 1.38 (m, 8H), 1.00 - 0.97 (m, 12H). 13C NMR (126 MHz, Chloroform-;/) d 186.30, 185.58, 183.15, 173.49, 172.98, 172.90, 141.61, 140.93, 140.66, 137.21, 136.28, 136.17, 123.74, 123.68, 123.49, 112.73, 112.71, 112.66, 112.57, 54.58, 29.57, (0092) 20.19, 20.17, 13.81, 13.79. MALDI-HRMS: m/z = 529.2555 [M+H+] (Calculated 529.2553). kmax (CHCh) = 798 nm, e (CHCh) 3.0 105 L mol 1 cm 1, t (CHCh) = 0.06. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
69.2% | at 150℃; for 12h;Inert atmosphere; | Use a 50 mL two-port bottle as the reaction vessel.The reaction device is subjected to anhydrous treatment,Reflux reaction, argon gas protection,Add in a two-port bottleCompound 1 (421 mg, 1.15 mmol, 1.0 eq),Triethyl phosphite (6mL),The oil bath was refluxed at 150 C for 12 h.The mixture in the two-necked bottle was extracted with a small amount of ethyl acetate and water for 5 times using a separatory funnel.Pour the organic phase into a round bottom flask and spin dry.Add silica gel and mix.After stirring evenly, the product was spin-dried by column chromatography (dichloromethane / ethyl acetate = 1/2: v / v).Obtained a yellow product of 1.813 g,That is compound 2,The theoretical yield is 2.628g,The yield was 69.2%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
78% | In toluene; at 80℃; for 96h;Inert atmosphere; | A solution of 9,10-bis (bromomethyl) anthracene (1.0 g, 2.7 mmol) and 1-octadecylimidazole (1.8 g, 5.6 mmol) in toluene (25 ml) was stirred at 80 C for 4 d. The reaction mixture was cooled to room temperature to give a precipitate which was filtered and washed with dry acetonitrile. The precipitate was redissolved in water; the aqueous solution was extracted with CH2Cl2 and then CH2Cl2 was removed under vacuum to give a crude product which was recrystallized from mixture solvent of water and methanol with a volume ratio of 1:3 to give a pure product of L-Cl as a pale yellow solid (2.17 g, 78 %), m.p. 223-225 C. 1H NMR (400 MHz, CDCl3, δ ppm): 0.88 (t, 6H), 1.00-1.47 (m, 62H), 1.55-1.79 (m, 6H), 4.07 (s, 4H), 6.43-6.72 (d, 4H), 6.90-7.12 (m, 2H), 7.67-8.12 (d, 4H), 8.96 (m, 2H), 9.33 (m, 2H). Anal. calcd for C58H92N4Cl2: C 75.74, H 10.08, N 5.91; C 76.03, H 10.12, N 6.11. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With triethylamine; In tetrahydrofuran; at 20℃; for 4h; | The yellow solid obtained in step (3) is dissolved in tetrahydrofuran and reacted with bis(2-pyridylmethyl)amine and triethylamine for 4h,The mass ratio of yellow solid to bis(2-pyridylmethyl)amine is 3:1.Step (5): Step (4) The reaction gradually precipitates to obtain a yellow solid; use a rotary evaporator, the temperature of the rotary evaporator is 38-39C,The pressure is that the rotation rate is 160-180r/min and the pressure is 0.08Mpa. The solvent is completely evaporated by rotary evaporation to obtain a yellow solid.Step (6): The yellow solid obtained by the reaction of step (5) is mixed with ethyl acetate and silica gel, packed in a column,Pass the chromatographic column (Xinweier's grinding mouth is 24/40), remove the impurities, the solvent for the sample is ethyl acetate,The column solvent is a mixed solvent composed of methanol and ethyl acetate, the volume ratio of the two is 1:30 to remove impurities, and the volume ratio of 1:15 is used for the target compound for zinc ion detection.The structure of the target compound is shown in Figure 1, and the yield is 15.1%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With potassium carbonate; In N,N-dimethyl-formamide; at 20 - 90℃; | A solution of 4 (1.5 g, 2.6 mmol) and 9.10-bis(bromomethyl)anthracene (950 mg, 2.6 mmol) in dry DMF(250 ml) was added dropwise over 4 h to a suspension ofpotassium carbonate (1.8 g) in DMF (300 ml) at 90 C,resulting mixture was stirred for overnight at room temperature.The solvent was evaporated to dryness underreduced pressure. Distilled water (1000 ml) was added tothe residue. The resulting mixture was then stirred for 1 hat room temperature, insoluble materials were collected byfiltration. The residue was chromatographed on a columnof silica gel (SiO2) with chloroform as eluent. The productfraction was evaporated to dryness under reduced pressureto give a pale yellow solid (510 mg, 26 %): 1H NMR(400 MHz, CDCl3, 298 K) d 3.32 (s, 4 H), 5.84 (s, 8 H),6.28 (d, J = 8.0 Hz, 8H), 6.58 (d, J = 8.0 Hz, 8H), 7.53(m, 4H), 7.57 (dd, J = 10.1 Hz, 8H), 7.69 (m, 4H), 7.74(m, 8H), and 8.32 (dd, J = 10.1 Hz, 8H). 13C NMR(100 MHz, CDCl3, 298 K) d 42.4, 46.7, 123.9, 124.8,125.9, 126.7, 130.6, 130.8, 131.4, 131.6, 132.2, 133.1,133.7, 143.6, and 148.4. IR 3301 cm-1 (N-H), 1539 cm-1(N=O), 1359, 1166 cm-1 (SO2). Found: C, 61.64; H, 4.05;N, 6.81, Calcd for C82H60N8O16S43H2O: C, 61.72; H,4.17; N, 7.02. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
26% | With potassium carbonate; In N,N-dimethyl-formamide; at 20 - 90℃; | A solution of 4 (1.5 g, 2.6 mmol) and 9.10-bis(bromomethyl)anthracene (950 mg, 2.6 mmol) in dry DMF(250 ml) was added dropwise over 4 h to a suspension ofpotassium carbonate (1.8 g) in DMF (300 ml) at 90 C,resulting mixture was stirred for overnight at room temperature.The solvent was evaporated to dryness underreduced pressure. Distilled water (1000 ml) was added tothe residue. The resulting mixture was then stirred for 1 hat room temperature, insoluble materials were collected byfiltration. The residue was chromatographed on a columnof silica gel (SiO2) with chloroform as eluent. The productfraction was evaporated to dryness under reduced pressureto give a pale yellow solid (510 mg, 26 %): 1H NMR(400 MHz, CDCl3, 298 K) d 3.32 (s, 4 H), 5.84 (s, 8 H),6.28 (d, J = 8.0 Hz, 8H), 6.58 (d, J = 8.0 Hz, 8H), 7.53(m, 4H), 7.57 (dd, J = 10.1 Hz, 8H), 7.69 (m, 4H), 7.74(m, 8H), and 8.32 (dd, J = 10.1 Hz, 8H). 13C NMR(100 MHz, CDCl3, 298 K) d 42.4, 46.7, 123.9, 124.8,125.9, 126.7, 130.6, 130.8, 131.4, 131.6, 132.2, 133.1,133.7, 143.6, and 148.4. IR 3301 cm-1 (N-H), 1539 cm-1(N=O), 1359, 1166 cm-1 (SO2). Found: C, 61.64; H, 4.05;N, 6.81, Calcd for C82H60N8O16S43H2O: C, 61.72; H,4.17; N, 7.02. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68% | at 180℃; for 8h; | The 9,10-Bis(bromomethyl)anthracene (1.2 g, 3.3 mmol) was mixed with triethyl phosphate (10 mL). Resulting mixture was refluxed at 180C for 8 h in order to obtain the pure product. The solvent was then removed at vacuum and the residue product was purified by a column chromatography on silica gel using ethyl acetate/CH2Cl2 as the eluent. Yield: 1.05 g (68%). 1H NMR (300 MHz, CDCl3): delta 8.38 (m, 4H), delta 7.6 (m, 4H), 4.25 (d, 4H), 3.8 (m, 8H), 1.06 ppm (t, 12H). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In acetonitrile; for 48h;Reflux; | 3) Take <strong>[34373-96-1]9,10-dibromomethylanthracene</strong> (3.64g 10mmol) and compound 1-2 (4.23g, 10mmol) were dissolved in 750ml of acetonitrile, respectively, was dropped dropwise into 100ml acetonitrile under reflux, and the reaction was continued for 48h under reflux. Subsequently, NH4PF6 (16.3 g, 100 mmol) was added and the reaction was continued for 24 h. After completion of the reaction, the acetonitrile was removed by rotary evaporation and the residual solid was washed with water. The remaining solid was dissolved with acetonitrile and filtered through celite. The filtrate was spin-dried and recrystallized from acetonitrile/1,4-dioxane to give the product 1-4 ring as a yellow powder, ie (N2,N6-bis(6-(1H-imidazol-1-yl)pyridine-2-(N2,N6-dimethylpyridine-2,6-diamine)(9,10-dimethylhydrazine)dihexafluorophosphate, 5.1 g, 56% yield |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
81% | A solution of each of compounds 1 (10 mmol) and KOH(1.14 g, 20 mmol) in ethanol (10 ml) was stirred at room temperaturefor 10 min. The solvent was removed in vacuo and theremaining solvent was triturated with dry ether, collected anddried. It was then used in the next steps without furtherpurification. Synthesis of 7,7′-((anthracene-9,10-diylbis(methylene))bis-(oxy))bis(4-methyl-2H-chromen-2-one) (BisCA) (3) A solution of each of the potassium salt of 1 (20 mmol) and<strong>[34373-96-1]9,10-bis(bromomethyl)anthracene</strong> (2) (10 mmol) in DMF(20 ml) was heated under reflux for 5 min during which timeKBr was precipitated. The solvent was then removed in vacuo and the remaining material was washed with water (50 ml)and crystallized from DMF to give compound 3 as orangecrystals.; yield: 81%; mp 242 C; IR: υ max 1714 (C=O)cm-1, 1H NMR (DMSO) δ 2.39 (s, 6H, CH3), 5.41 (s, 4H,OCH2), 6.20-7.92 (m, 10H, ArHs, Coumarin H) ppm. MS:m/z 554 (M+); Anal. for C36H26O6 (554.17), Calcd: C, 77.97;H, 4.73. Found: C, 77.70; H, 5.10 |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
60% | General procedure: Anthracene (5g, 28mmol) was dissolved in 25mL of glacial acetic acid and 100mL of hydrobromic acid. 1,3,5-trioxane (5g, 56mmol) and TTA (0.2g) were added and stirred at 75C under reflux with a condenser sealed with an argon balloon for 24h. The mixture was then cooled, filtered and washed with water. The crude was dried and dissolved with toluene in a 70C bath, and then recrystallized in an ice bath. Three more washes with hot ethanol at 60C were needed to remove the remaining anthracene. A green-yellow solid of 9,10-bis(bromomethyl)anthracene 2 was obtained [31] (1.3g, yield 60%). 1H NMR (400MHz, CDCl3): δppm 8.4 (dd, J =6.9Hz, J =3.2Hz, 4H), 7.7 (dd, J =6.9Hz, J =3.2Hz, 4H), 5.53 (s, 4H); 13C NMR (100MHz, CDCl3): δppm 130.2, 129.6, 126.7, 124.4, 26.6. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | 2-azido-1-ethanol (1.196 g, 13.73 mmol) and NaH (0.549 g, 13.73mmol) was added in THF (50 mL) under inert atmosphere and obtainedsuspension was refluxed for 30 min. After, 910-bis(bromomethyl)anthracene (2.000 g, 5.490 mmol) which dissolved in THF (50 mL)was added dropwise to suspension and reaction mixture was refluxed for24 h. The reaction was followed by TLC (silica gel used as stationary and5 n-hexane: 1 ethylacetate (v/v) used as an eluent). After reactionfinished, G4 filter was used for filtration of reaction mixture and theorganic solvent of mixture was removed with using rotary evaporatorunder reduced pressure. Crude product was purified by column chromatography(silica gel used as stationary and 5 n-hexane: 1 ethylacetate(v/v) used as an eluent) and N3-L was obtained as light yellow solid(1.650 g, 80 %, m.p. 92 C). 1H NMR (ppm, 298 K, DMSO-d6); 8.50 (dd, J= 6.9, 3.1 Hz, 2 H), 7.61 (dd, J = 6.9, 3.1 Hz, 2 H), 5.53 (s, 2 H), 3.86 (t, J= 4.8, 2 H), 3.47 (t, J = 4.8, 2 H). 13C NMR (ppm, 298 K, DMSO-d6);130.25, 130.01, 125.80, 124.10, 68.76, 64.30, 50.10. FT-IR (ATR, cm 1); 3094 3024 (CH), 2981- 2860 (CH), 2086.6 (NNN), 1850 1650(CC), 1350 1250 (CH). [M+H]-- ----- -- --- -----+: 377.272m/z (calc. [M+H]+: 377.420). |
Tags: 34373-96-1 synthesis path| 34373-96-1 SDS| 34373-96-1 COA| 34373-96-1 purity| 34373-96-1 application| 34373-96-1 NMR| 34373-96-1 COA| 34373-96-1 structure
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P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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