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Chemical Structure| 35453-30-6 Chemical Structure| 35453-30-6

Structure of 35453-30-6

Chemical Structure| 35453-30-6

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Product Details of [ 35453-30-6 ]

CAS No. :35453-30-6
Formula : C8H4Br3NO4
M.W : 417.83
SMILES Code : O=C(O)C1=C(Br)C(N)=C(Br)C(C(O)=O)=C1Br
MDL No. :MFCD31802315

Safety of [ 35453-30-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 35453-30-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 35453-30-6 ]

[ 35453-30-6 ] Synthesis Path-Downstream   1~2

  • 1
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 143131-66-2 ]
  • [ 35453-30-6 ]
  • [ 7732-18-5 ]
  • 2C8H3Br3NO4(1-)*C12H12N6*Cd(2+)*4H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
66.28% at 20℃; for 5h; To a 2 mL of aqueous solution of H2ATBIP (0.042 g, 0.100 mmol) was added a 2 mL of aqueous solution of Cd(NO3)2·4H2O (0.0308 g, 0.100 mmol). Then, the above mixed solution was added into a 2 mL of aqueous solution of <strong>[143131-66-2]bbtz</strong> (0.024 g, 0.100 mmol). The resulting solution was filtered after about 5 h. The filtrate was allowed to stand at room temperature for about 3 days. White block crystals were formed in a 66.28% yield (based on H2ATBIP). Elemental analysis (%) calculated for C28H26Br6CdN8O12: C, 26.70; H, 2.07; N, 8.90%; Found: C, 26.51; H, 2.29; N, 8.81%. IR (KBr pellet, v, cm-1): 3460 (vs), 3110 (w), 1707 (m), 1589 (vs), 1407 (m), 1357 (m), 1267 (w), 1130 (m), 718 (w), 670 (m).
  • 2
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 143131-66-2 ]
  • [ 35453-30-6 ]
  • [ 7732-18-5 ]
  • 2C12H12N6*2C8H3Br3NO4(1-)*Cd(2+)*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
57.02% at 100℃; for 72h;Autoclave; A mixture of Cd(NO3)2·4H2O (0.0308 g, 0.100 mmol), H2ATBIP (0.042 g, 0.100 mmol), <strong>[143131-66-2]bbtz</strong> (0.024 g, 0.100 mmol) and H2O (6 mL) was sealed in a 25 mL Teflon reactor and heated at 100 C for about 3 days. After slowly cooling to ambient temperature at a rate of 10 C/h, white block crystals of 2 were collected in a 57.02% yield (based on H2ATBIP). Elemental analysis (%) calculated for C40H34Br6CdN14O10: C, 32.85; H, 2.34; N, 13.41%; Found: C, 32.68; H, 2.35; N, 13.44%. IR (KBr pellet, v, cm-1): 3467 (vs), 3110 (w), 1714 (m), 1590 (vs), 1399(m), 1350 (s), 1267 (m), 1130 (m), 1006 (w), 979 (w), 725 (w), 670 (m).
 

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