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Quality Control of [ 3567-62-2 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

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Product Details of [ 3567-62-2 ]

CAS No. :	3567-62-2	MDL No. :	MFCD00088374
Formula :	C₈H₈Cl₂N₂O	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	219.07	Pubchem ID :	-
Synonyms :

Safety of [ 3567-62-2 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 3567-62-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 3567-62-2 ]

[ 3567-62-2 ] Synthesis Path-Downstream 1~24

1
[ 102-36-3 ]
[ 74-89-5 ]
[ 3567-62-2 ]
[ 100961-22-6 ]

Yield	Reaction Conditions	Operation in experiment
	With benzene

Reference： [1]Kaluszyner et al. [1957, vol. 7, p. 135]

2
[ 16240-18-9 ]
[ 3567-62-2 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrogenchloride

Reference： [1]Chupp,J.P.; Weiss,E.R. [Journal of Organic Chemistry, 1968, vol. 33, p. 2357 - 2361]

3
[ 3567-62-2 ]
[ 372-09-8 ]
[ 126381-34-8 ]

Yield	Reaction Conditions	Operation in experiment
46%	With acetic anhydride at 60℃; for 3h;

Reference： [1]Mueller, Thomas; Augustin, Manfred; Werchan, Hans-Georg [Zeitschrift fur Chemie, 1989, vol. 29, # 8, p. 281 - 283]

4
[ 3567-62-2 ]
[ 298-12-4 ]
[ 134124-32-6 ]
[ 38655-54-8 ]

Yield	Reaction Conditions	Operation in experiment
	In chloroform Heating;

Reference： [1]Onisko, Bruce; Chang, Lydia; Lewis, Sydell [Organic Mass Spectrometry, 1991, vol. 26, # 3, p. 125 - 131]

5
[ 102-36-3 ]
[ 74-89-5 ]
[ 3567-62-2 ]

Yield	Reaction Conditions	Operation in experiment
72%	In tetrahydrofuran at 20℃; for 2h;
	In tetrahydrofuran

Reference： [1]Tixier, Celine; Bogaerts, Philippe; Sancelme, Martine; Bonnemoy, Frederique; Twagilimana, Landoald; Cuer, Annie; Bohatier, Jacques; Veschambre, Henri [Pest Management Science, 2000, vol. 56, # 5, p. 455 - 462]
[2]Faure; Boule [Pesticide Science, 1997, vol. 51, # 4, p. 413 - 418]

6
[ 330-54-1 ]
[ 34637-13-3 ]
[ 3567-62-2 ]
[ 69342-26-3 ]
[ 76409-92-2 ]

Yield	Reaction Conditions	Operation in experiment
	With Fe(OH)⁽²⁺⁾ In water for 4h; Photolysis;

Reference： [1]Mazellier; Jirkovsky; Bolte [Pesticide Science, 1997, vol. 49, # 3, p. 259 - 267]

Yield	Reaction Conditions	Operation in experiment
	Bildung 1: O-Propionyl-N-methylcarbamoyl-N-(3-chlor-phenyl)-hydroxylamin, HCl;
	Bildung 2: O-Acetyl-N-methylcarbamoyl-N-(3-chlor-phenyl)-hydroxylamin, HCl;
	(yield)Bildung 1-2: 22percent;

	Ester (2), 1) Δ, 2) 3,4-Dichloranilin;
	Methylisocyanat, 3,4-Dichlor-anilin;
	aus Methylisocyanat, 3,4-Dichlor-anilin;

8
[ 3567-62-2 ]
[ 126381-37-1 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 46 percent / acetic anhydride / 3 h / 60 °C 2: 74 percent / 33 percent NaOH / 0.17 h / 80 °C

Reference： [1]Mueller, Thomas; Augustin, Manfred; Werchan, Hans-Georg [Zeitschrift fur Chemie, 1989, vol. 29, # 8, p. 281 - 283]

9
[ 3567-62-2 ]
[ 126381-40-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 46 percent / acetic anhydride / 3 h / 60 °C 2: 63 percent / NaNO₂ / H₂O / 0.17 h / 95 °C

Reference： [1]Mueller, Thomas; Augustin, Manfred; Werchan, Hans-Georg [Zeitschrift fur Chemie, 1989, vol. 29, # 8, p. 281 - 283]

10
[ 102-36-3 ]
[ 3567-62-2 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: toluene 2: aq. HCl

Reference： [1]Chupp,J.P.; Weiss,E.R. [Journal of Organic Chemistry, 1968, vol. 33, p. 2357 - 2361]

11
[ 1189-71-5 ]
[ 3567-62-2 ]
[ 80653-08-3 ]

Yield	Reaction Conditions	Operation in experiment
	In 1,4-dioxane; ethyl acetate; Petroleum ether	1 EXAMPLE 1 EXAMPLE 1 65.7 parts of N-methyl-N'-(3',4'-dichlorophenyl)-urea are suspended in 300 parts of dioxane. 42.5 parts of chlorosulfonyl isocyanate are added, a little at a time, at room temperature. After the mixture has been stirred for 16 hours, insoluble matter is filtered off and the solution is concentrated; residual solvent is removed at 40°-60° C./0.01 mbar. 90 parts of ethyl acetate are added to the residue and when the mixture has crystallized 200 ml of petroleum ether are added. The product is filtered off and dried, giving 75 parts of 2H-4-methyl-6-(3',4'-dichlorophenyl)-3,4,5,6-tetrahydro-1,2,4,6-thiatriazine-3,5-dione-1,1-dioxide (active ingredient 1), melting point 180°-183° C.

Reference： [1]Current Patent Assignee: BASF SE - US4353732, 1982, A

12
1-(3,4-dichlorophenyl)-3-(1-hydroxy-2,2,2-trichloroethyl)-3-methyl urea [ No CAS ]
[ 3567-62-2 ]
[ 75-87-6 ]
[ 39803-91-3 ]

Yield	Reaction Conditions	Operation in experiment
	With sulfuric acid In diethyl ether	3 Preparation of 1-methyl-1-(1,2,2,2-tetrachloroethyl)-3-(3,4-dichlorophenyl) urea EXAMPLE 3 Preparation of 1-methyl-1-(1,2,2,2-tetrachloroethyl)-3-(3,4-dichlorophenyl) urea 1-(3,4-dichlorophenyl)-3-methyl urea (15.2 g, 0.07 mol) was combined with 15.0 g (0.1 mol) of chloral and 5 drops of concentrated sulfuric acid. The mixture was heated for an hour to effect reaction, then stripped under vacuum. To the crude 1-(3,4-dichlorophenyl)-3-(1-hydroxy-2,2,2-trichloroethyl)-3-methyl urea was added an excess of thionyl chloride and the mixture was heated gradually to a maximum of 65° C. Diethyl ether was added to the crude product, and the insoluble product was collected on a filter, washed twice with diethyl ether and dried. The 15.3 g of product, which melted at 132°-140° C., analyzed as follows: %Cl, calculated 55.2, found 46.0.

Reference： [1]Current Patent Assignee: CHEVRON CORP - US4007033, 1977, A

13
[ 75-76-3 ]
[ 3567-62-2 ]
[ 54892-17-0 ]

Yield	Reaction Conditions	Operation in experiment
	With pyridine; sulphur dichloride In dichloromethane	3 Example 3 Example 3 -- Preparation of N-chlorothio-N-methyl-N'-3,4-dichlorophenyl urea A 9.48-g (0.12 mol) sample of pyridine was added dropwise to a slurry of 21.9 (0.1 mol) N-methyl-N'-(3,4-dichlorophenyl) urea and 11.3 g (0.11 mol) sulfur dichloride in 100 ml methylene dichloride at 25°-30°C. After the completion of the addition, pyridine hydrochloride was filtered from the reaction mixture. The NMR spectrum of the reaction mixture showed a singlet at 3.5 ppm (relative to tetramethylsilane) for the N-methyl group of the N-chlorothio-N-methyl-N'-3,4-dichlorophenyl urea product.

Reference： [1]Current Patent Assignee: CHEVRON CORP - US3946062, 1976, A

14
[ 624-83-9 ]
[ 95-76-1 ]
[ 3567-62-2 ]

Yield	Reaction Conditions	Operation in experiment
	In di-isopropyl ether	4.A STEP A STEP A N-methyl-N'-(3,4-dichlorophenyl)-urea A mixture of 27.4 g of 3,4-dichloroaniline in 140 ml of isopropyl ether was added slowly to 9 g of methyl isocyanate in 100 ml of isopropyl ether and the mixture was refluxed for 2 hours and was then cooled to 0° C. The precipitate formed was recovered by vacuum filtration and was washed with isopropyl ether. The mother liquors were concentrated to obtain a second crop. The two combined crops weighing 19.5 g and melting at 156° C. were crystallized from ethyl acetate to obtain N-methyl-N'-(3,4-dichlorophenyl)-urea melting at 160° C., identical to the product described by Onley et al., J. Ass. Off. Anal. Chem., Vol. 52 (1969), p. 545. Analysis: C8 H8 Cl2 N2 O; molecular weight = 219.07; Calculated: %C, 43.86; %H, 3.68; %Cl, 32.37; %N, 12.79; Found: %C, 43.7; %H, 3.6; %Cl, 32.4; %N, 12.7.

Reference： [1]Current Patent Assignee: SANOFI - US4045209, 1977, A

15
[ 5813-48-9 ]
[ 60-29-7 ]
[ 3567-62-2 ]
[ 41881-54-3 ]

Yield	Reaction Conditions	Operation in experiment
	In pyridine	5 N-METHYL-METHYLTHIO-N'-(3,4-DICHLOROPHENYL)-UREA EXAMPLE 5 N-METHYL-METHYLTHIO-N'-(3,4-DICHLOROPHENYL)-UREA A mixture of 20 ml of methylsulfenyl chloride and 200ml of ethyl ether was added slowly while keeping the temperature below -30° C. to a solution of 40 g of N-methyl-N'-(3,4-dichlorophenyl)-urea in 500 ml of pyridine and the mixture was stirred for 1 hour at -30° C. After letting the temperature rise to 5° C., the mixture was stirred for 17 hours and the mixture was poured into a mixture of ice and water. The mixture was extracted with methylene chloride and the methylene chloride extract was washed with water and dried. The volatile fractions were removed by distillation under reduced pressure and the residue was crystallized from isopropyl ether to obtain 29.4 g of N-methyl-N-methylthio-N'-(3,4-dichlorophenyl)-urea melting at 93° C. A microanalytical sample was obtained by chromatography over silica gel and elution with a 9-1 benzene-ethyl acetate mixture. Analysis: C9 H10 Cl2 N2 OS; molecular weight = 265.16; Calculated: %C, 40.76; %H, 3.79; %Cl, 26.75; %N, 10.56; %S, 12.10; Found: %C, 40.6; %H, 3.8; %Cl, 26.8; %N, 10.5; %S, 12.0.

Reference： [1]Current Patent Assignee: SANOFI - US4045209, 1977, A

16
[ 19760-03-3 ]
[ 3567-62-2 ]
[ 629-19-6 ]
[ 41881-66-7 ]

Yield	Reaction Conditions	Operation in experiment
	With sulfuryl dichloride In pyridine; dichloromethane; Petroleum ether	17 N-PROPYLTHIO-N-METHYL-N'-(3,4-DICHLOROPHENYL)-UREA EXAMPLE 17 N-PROPYLTHIO-N-METHYL-N'-(3,4-DICHLOROPHENYL)-UREA 13,4 g of sulfuryl chloride were slowly added at -30° C. to a mixture of 106 ml of methylene chloride and 15 g of dipropyldisulfide, and after the temperature rose to -10°C., the mixture was stirred for 10 minutes at -10° C. to obtain a solution of propyl sulfenyl chloride. The solution was cooled to -30° C. and a solution of 22 g of N-methyl-N'-(3,4-dichlorophenyl)-urea in 140 ml of pyridine was added thereto. The mixture was stirred for 5 hours at -20° C., then for 17 hours at 0° C. The mixture was poured into a water-ice-hydrochloric acid-methylene chloride mixture, was stirred and decanted. The organic phase was washed with water, dried and concentrated to dryness under reduced pressure. The residue was chromatographed over silica gel and eluted with a 9-1 benzene-ethyl acetate mixture. The product was added to petroleum ether (b.p. = 65°-75° C.) and the precipitate formed was recovered by vacuum filtration and was washed and dried to obtain 14 g of N-methyl-N-propylthio-N'-(3,4-dichlorophenyl)-urea melting at 40° C. Analysis: C11 H14 Cl2 N2 OS; molecular weight = 293.22; Calculated: %C, 45.06; %H, 4.81; %Cl, 24.18; %N, 9.55; %S, 10.93; Found: %C, 45.4; %H, 5.0; %Cl, 23.9; %N, 9.8; %S, 11.2.

Reference： [1]Current Patent Assignee: SANOFI - US4045209, 1977, A

17
N-chloromercaptomorpholine [ No CAS ]
[ 3567-62-2 ]
[ 41881-53-2 ]

Yield	Reaction Conditions	Operation in experiment
	With triethylamine In tetrahydrofuran	4.B STEP B STEP B N-methyl-N-morpholinothio-N'-(3,4-dichlorophenyl) urea 43.8 g of N-methyl-N'-(3,4-dichlorophenyl)-urea and 21.1 g of triethylamine were added to 440 ml of tetrahydrofuran and the mixture was stirred until dissolution occurred. A solution of 36 g of N-chloro-mercaptomorpholine in 60 ml of tetrahydrofuran was added in 5 minutes to the said solution and the mixture was stirred for 4 hours at room temperature. The precipitate formed was removed by filtration and the filtrate was concentrated to dryness under reduced pressure. The residue was crystallized from ethyl acetate to obtain 42.5 g of N-methyl-N-morpholinothio-N'-(3,4-dichlorophenyl)-urea melting at 142° C. Analysis: C12 H15 Cl2 N3 O2 S; molecular weight = 336.246; Calculated: %C, 42.86; %H, 4.50; %Cl, 21.09; %N, 12.50; %S, 9.54; Found: %C, 42.8; %H, 4.8; %Cl, 21.0; %N, 12.4; %S, 9.6.

Reference： [1]Current Patent Assignee: SANOFI - US4045209, 1977, A

18
[ 110-81-6 ]
[ 3567-62-2 ]
[ 41881-55-4 ]

Yield	Reaction Conditions	Operation in experiment
	With sulfuryl dichloride In pyridine; dichloromethane	6 N-METHYL-N-ETHYLTHIO-N'-(3,4-DICHLOROPHENYL)-UREA EXAMPLE 6 N-METHYL-N-ETHYLTHIO-N'-(3,4-DICHLOROPHENYL)-UREA A solution of 67 g of sulfuryl chloride in 100 ml of methylene chloride was added dropwise to a solution of 61 g of diethyldisulfide in 600 ml of methylene chloride cooled to -40° C. and after the temperature was raised to -5° C., the mixture was stirred for 5 minutes. The mixture was cooled to -40° C. and a solution of 57 g of N-methyl-N'-(3,4-dichlorophenyl)-urea in 460 ml of pyridine was added dropwise thereto. The mixture was stirred at -40° C. for 1 hour and for another hour at -20° C. The mixture was poured into an ice-water mixture and the pH was adjusted to 3.5 by addition of concentrated hydrochloric acid. The organic phase was decanted and the aqueous phase was extracted with methylene chloride. The combined organic phases were washed with water, dried and evaporated to dryness under reduced pressure. The residue was crystallized from isopropyl ether and subjected to chromatography over silica gel. Elution with a 7-3 benzene-ethyl acetate mixture gave 22 g of N-methyl-N-ethylthio-N'-(3,4-dichlorophenyl)-urea melting at 71° C. Analysis: C10 H12 Cl2 N2 OS; molecular weight = 279.16; Calculated: %C, 43.02; %H, 4.34; %Cl, 25.41; %N, 10.04; %S, 11.48; Found: %C, 43.2; %H, 4.4; %Cl, 25.2; %N, 10.1; %S, 11.1.

Reference： [1]Current Patent Assignee: SANOFI - US4045209, 1977, A

19
[ 420-12-2 ]
[ 3567-62-2 ]
[ 62351-01-3 ]

Yield	Reaction Conditions	Operation in experiment
	With chlorosulphuric acid In pyridine; dichloromethane	2 N-(2-chloroethylthio)-N-methyl-N'-(3,4-dichlorophenyl)-urea EXAMPLE 2 N-(2-chloroethylthio)-N-methyl-N'-(3,4-dichlorophenyl)-urea 27 g of chlorosulfuric acid were slowly added at 0° C to a mixture of 12 g of ethylene sulfide and 200 ml of methylene chloride and the mixture was stirred at 0° C for 10 minutes and was then cooled to -20° C. A mixture of 32.6 g of N-methyl-N'-(3,4-dichlorophenyl)-urea in 210 ml of pyridine was added to the reaction mixture after which the temperature returned to 0° C. The mixture was stirred at 0° C for 10 minutes and was then poured into a mixture of ice, water, hydrochloric acid and methylene chloride. The mixture was stirred for 30 minutes and the decanted organic phase was washed, dried, filtered and concentrated to dryness under reduced pressure. The residue was chromatographed over silica gel and the product was eluted witn 9-1 benzene-ethyl acetate mixture and was crystallized from isopropyl ether to obtain 10 g of N-(2-chloroethylthio)-N-methyl-N'-(3,4-dichlorophenyl)-urea melting at 62° C. Analysis: C10 H11 Cl3 N2 OS Calculated: %C 38.29; %H 3.54; %N 8.93; %Cl 33.92; %S 10.22; Found: %C 38.3; %H 3.6; %N 8.7; %Cl 33.8; %S 10.0

Reference： [1]Current Patent Assignee: SANOFI - US4043796, 1977, A

20
[ 14925-97-4 ]
[ 629-45-8 ]
[ 3567-62-2 ]
[ 41881-68-9 ]

Yield	Reaction Conditions	Operation in experiment
	With sulfuryl dichloride In pyridine; dichloromethane	19 N-METHYL-N-n-BUTYLTHIO-N'-(3,4-DICHLOROPHENYL)-UREA EXAMPLE 19 N-METHYL-N-n-BUTYLTHIO-N'-(3,4-DICHLOROPHENYL)-UREA 26.8 g of sulfuryl chloride were slowly added at -30° C. to 35.6 g of dibutyl disulfide and 212 ml of methylene chloride and after raising the temperature to -10° C., the mixture was stirred for 10 minutes at -10° C. to obtain a solution of n-butyl sulfenyl chloride. A solution of 44 g of N-methyl-N'-(3,4-dichlorophenyl)-urea in 280 ml of pyridine was added slowly to the said solution at -30° C. and the mixture was stirred at -20° C. for 5 hours, then at 0° C. for 17 hours and poured into a methylene chloride-water-ice-hydrochloric acid mixture. The mixture was stirred and decanted and the organic phase was washed with water, dried and concentrated to dryness under reduced pressure. The residue was crystallized from methanol to obtain 22.1 g of N-methyl-N-n-butylthio-N'-(3,4-dichlorophenyl)-urea melting at 47° C. Analysis: C12 H16 Cl2 N2 OS; molecular weight = 307.25; Calculated: %C, 46.91; %H, 5.25; %Cl, 23.08; %N, 9.12; %S, 10.44; Found: %C, 47.1; %H, 5.5; %Cl, 23.0 %N, 8.7; %S, 10.7.

Reference： [1]Current Patent Assignee: SANOFI - US4045209, 1977, A

21
[ 3567-62-2 ]
[ 144386-19-6 ]
[ 41881-56-5 ]

Yield	Reaction Conditions	Operation in experiment
	With potassium carbonate In water; dimethyl sulfoxide	7 N-METHYL-N-(2-THIAPROPYL)-N'-(3,4-DICHLOROPHENYL)-UREA EXAMPLE 7 N-METHYL-N-(2-THIAPROPYL)-N'-(3,4-DICHLOROPHENYL)-UREA 11 g of N-methyl-N'-(3,4-dichlorophenyl)-urea, 60 g of potassium carbonate and 50 ml of dimethylsulfur chloride were added at 10° C. to 150 ml of dimethylsulfoxide and the mixture was allowed to stand until exothermic generation of heat ceased. The reaction mixture was added to water and was extracted with ether. The ether solution was washed with water, dried and concentrated to dryness by distillation under reduced pressure. The residue was crystallized from isopropyl ether and then ethyl acetate to obtain 7.7 g of N-methyl-N-(2-thiapropyl)-N'-(3,4-dichlorophenyl)-urea melting at 103° C.

Reference： [1]Current Patent Assignee: SANOFI - US4045209, 1977, A

22
[ 3567-62-2 ]
[ 1380583-40-3 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: carbon tetrabromide; triethylamine; triphenylphosphine / dichloromethane / 0 °C 2: copper(l) chloride / benzene / Reflux

Reference： [1]Han, Minsoo; Hahn, Hoh-Gyu [Bulletin of the Korean Chemical Society, 2012, vol. 33, # 4, p. 1371 - 1374]

23
[ 3567-62-2 ]
[ 1380583-56-1 ]

Yield	Reaction Conditions	Operation in experiment
	With carbon tetrabromide; triethylamine; triphenylphosphine In dichloromethane at 0℃;

Reference： [1]Location in patent: scheme or table Han, Minsoo; Hahn, Hoh-Gyu [Bulletin of the Korean Chemical Society, 2012, vol. 33, # 4, p. 1371 - 1374]

24
[ 3567-62-2 ]
N-methyl-N-(2-chlorocycloheptylthio)-N'-(3,4-dichlorophenyl)-urea [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: pyridine; sulphur dichloride / dichloromethane

Reference： [1]Current Patent Assignee: CHEVRON CORP - US3946062, 1976, A

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P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 3567-62-2 ] {[proInfo.proName]}

Quality Control of [ 3567-62-2 ]

Related Doc. of [ 3567-62-2 ]

Product Details of [ 3567-62-2 ]

Safety of [ 3567-62-2 ]

Application In Synthesis of [ 3567-62-2 ]

[ 3567-62-2 ] Synthesis Path-Downstream 1~24

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry