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Chemical Structure| 35714-17-1 Chemical Structure| 35714-17-1

Structure of 35714-17-1

Chemical Structure| 35714-17-1

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Product Details of [ 35714-17-1 ]

CAS No. :35714-17-1
Formula : C15H14O2
M.W : 226.27
SMILES Code : O=C(OC)C1=CC=CC(CC2=CC=CC=C2)=C1

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Application In Synthesis of [ 35714-17-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 35714-17-1 ]

[ 35714-17-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 618-89-3 ]
  • [ 98-80-6 ]
  • [ 35714-17-1 ]
YieldReaction ConditionsOperation in experiment
72% With potassium phosphate;bis-triphenylphosphine-palladium(II) chloride; In water; N,N-dimethyl-formamide; at 80℃; for 1h; I. Methyl 3-benzylbenzoate; [00306] A solution of 3-bromomethylbenzoate (500 mg, 2.18 mmol), phenylboronic acid (290 mg, 2.40 mmol), PdCl2(PPh3)2 (46 mg, 0.07 mmol) and K3PO4 (1.16 g, 5.45 mmol) in DMF (10 mL) and water (2 mL) was heated at 8O0C for 1 hr and then cooled to room temperature and diluted with EtOAc. The reaction mixture was washed with water (3 times) and saturated NaCl, dried over Na2SO4 and filtered. The filtrate was concentrated under reduced pressure and the residue was purified by column chromatography on silica gel, eluting with 1 :19 EtOAc:hexanes to give a colorless oil (353 mg, 72%).
 

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