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Chemical Structure| 358376-08-6 Chemical Structure| 358376-08-6

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Chemical Structure| 358376-08-6

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Product Details of [ 358376-08-6 ]

CAS No. :358376-08-6
Formula : C14H29BO2
M.W : 240.19
SMILES Code : CC1(C)C(C)(C)OB(C(C)CCCCCC)O1

Safety of [ 358376-08-6 ]

Application In Synthesis of [ 358376-08-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 358376-08-6 ]

[ 358376-08-6 ] Synthesis Path-Downstream   1~6

  • 1
  • [ 14850-23-8 ]
  • [ 25015-63-8 ]
  • [ 358376-08-6 ]
  • [ 177949-99-4 ]
  • [ 66217-56-9 ]
  • [ 1203488-26-9 ]
References: [1]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[2]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[3]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[4]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[5]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[6]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[7]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[8]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[9]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[10]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[11]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[12]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[13]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[14]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[15]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[16]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[17]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[18]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[19]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[20]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[21]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
[22]Journal of the American Chemical Society,2010,vol. 132,p. 131 - 137.
  • 2
  • 2,2'-(ethane-1,1-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) [ No CAS ]
  • [ 3839-35-8 ]
  • [ 358376-08-6 ]
  • 3
  • [ 14850-23-8 ]
  • [ 25015-63-8 ]
  • [ 358376-08-6 ]
  • [ 66217-56-9 ]
  • 4
  • [ 111-66-0 ]
  • [ 73183-34-3 ]
  • [ 358376-08-6 ]
  • [ 66217-56-9 ]
YieldReaction ConditionsOperation in experiment
General procedure: An oven-dried vial was charged with Cu(OTf)2 (0.015 mmol), Lp7 (0.03 mmol), t-BuONa (0.03 mmol) and bis(pinacolato)diboron (0.36 mmol). After being sealed with a septum, the vial was connected to an argon-vacuum line and was evacuated and backfilled with argon (x 3). CH3CN (2 mL) and methanol (0.9 mmol) were added and the mixture was stirred for 30 min. Then, Alkene (0.3 mmol) was added and the mixture got a dark brown color and was stirred at 50 oC for 3h. After 3h, ethyl acetate and water were added and the organic layer were separated. The aqueous phase was extracted with ethyl acetate(x 3) and the combined organic layers were dried over Na2SO4 and concentrated. The crude product was purified by silica gel column chromatography.
  • 6
  • [ 111-66-0 ]
  • [ 73183-34-3 ]
  • [ 358376-08-6 ]
  • [ 66217-56-9 ]
  • [ 1240790-15-1 ]
 

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