Name: 36443-80-8|1-Benzyl-3-methyl-1H-imidazol-3-ium chloride|98%
Brand: Ambeed
SKU: A608563
Price: 7.0 USD
Availability: InStock
Rating: 90 (29 reviews)

1
[ 616-47-7 ]
[ 100-44-7 ]
[ 36443-80-8 ]

Yield	Reaction Conditions	Operation in experiment
99%	at 100℃; Microwave irradiation;
95%	In toluene for 72h; Heating;
95%	In acetonitrile for 48h; Inert atmosphere; Reflux;

95%	In toluene at -0.16 - 69.84℃; for 32.5h;
94%	In neat (no solvent) for 2h; Milling;
91%	Heating;
90%	In tetrahydrofuran for 24h; Schlenk technique; Reflux;
86%	With potassium carbonate In acetonitrile at 70℃; for 72h;
84%	In tetrahydrofuran Reflux;
78%	at 40 - 110℃; for 5h;	Benzyl chloride (0.4 mol) was dropped into methylimidazole (0.4 mol), stirred at 40 °C. The mixture was stirred for 5 h at 70-110 °C. The obtained crude 1-benzyl-3-methylimidazolium chloride, [Bzlmim]Cl, in the form of a light-orange viscous oil was dissolved in 70 cm3 acetonitrile and washed with diethyl ether (3 × 40 cm3), ethyl acetate (4 × 20 cm3), and again with diethyl ether (4 × 50 cm3), and finally with hexane (4 × 50 cm3). The product was left to stand over the hexane phase overnight to crystallize. The solid form was dried by nitrogen flow in a Schlenk apparatus to reach a constant weight. The product was obtained in the form of an off-white powder with 78% yield.
	at 80℃; for 72h;
	In acetonitrile at 24.84℃;
	In toluene
	In toluene
	at 150℃; for 0.5h; Microwave irradiation; Cooling; neat (no solvent);
	In toluene at 109.84℃; for 24h;
	In toluene for 24h; Reflux;
	In toluene for 24h; Reflux;
	In toluene
	In toluene for 24h; Reflux;
	In toluene at 80℃; for 24h;
	With sodium iodide In acetone at 20℃; for 12h; Schlenk technique;
	In chloroform at 20℃; for 5h;	13.1 (1) Synthesis of Intermediate (b) Example 13 Synthesis of Compound B-13 (1) Synthesis of Intermediate (b) In 100 g of chloroform, 30 g of benzyl chloride was dissolved, and to this, 20 g of 1-methylimidazole was added dropwise. The contents were stirred at room temperature. After 5 hours, the disappearance of the raw materials was confirmed by HPLC, and a 50% chloroform solution of Intermediate (b) was obtained.
	at 80℃; for 3h; Sealed tube;

Reference： [1]Erdmenger, Tina; Vitz, Juergen; Wiesbrock, Frank; Schubert, Ulrich S. [Journal of Materials Chemistry, 2008, vol. 18, # 43, p. 5267 - 5273]
[2]Brenna, Stefano; Posset, Tobias; Furrer, Julien; Bluemel, Janet [Chemistry - A European Journal, 2006, vol. 12, # 10, p. 2880 - 2888]
[3]Location in patent: experimental part Kilpelaeinen, Ilkka; Xie, Haibo; King, Alistair; Granstrom, Mari; Heikkinen, Sami; Argyropoulos, Dimitris S. [Journal of Agricultural and Food Chemistry, 2007, vol. 55, # 22, p. 9142 - 9148]
[4]Location in patent: experimental part Srivastava, Rajendra [Catalysis Letters, 2010, vol. 139, # 1-2, p. 17 - 25]
[5]Beillard, Audrey; Golliard, Ethan; Gillet, Valentin; Bantreil, Xavier; Métro, Thomas-Xavier; Martinez, Jean; Lamaty, Frédéric [Chemistry - A European Journal, 2015, vol. 21, # 49, p. 17614 - 17617]
[6]Location in patent: experimental part Zhuravlev; Verolainen; Voronchikhina [Russian Journal of Applied Chemistry, 2011, vol. 84, # 7, p. 1158 - 1164]
[7]Tang, Xiaodong; Qi, Chaorong; He, Haitao; Jiang, Huanfeng; Ren, Yanwei; Yuan, Gaoqing [Advanced Synthesis and Catalysis, 2013, vol. 355, # 10, p. 2019 - 2028]
[8]Rehm, Tobias; Rothemund, Matthias; Muenzner, Julienne K.; Noor, Awal; Kempe, Rhett; Schobert, Rainer [Dalton Transactions, 2016, vol. 45, # 39, p. 15390 - 15398]
[9]Lima, Heather M.; Lovely, Carl J. [Organic Letters, 2011, vol. 13, # 21, p. 5736 - 5739]
[10]Ochȩdzan-Siodłak, Wioletta; Dziubek, Katarzyna; Siodłak, Dawid [Journal of Molecular Liquids, 2013, vol. 177, p. 85 - 93]
[11]Day, Graeme; Glaser, Rainer; Shimomura, Noriyuki; Takamuku, Atsushi; Ichikawa, Kazuhiko [Chemistry - A European Journal, 2000, vol. 6, # 6, p. 1078 - 1086]
[12]Letaief, Sadok; Detellier, Christian [Journal of Materials Chemistry, 2007, vol. 17, # 15, p. 1476 - 1484]
[13]Location in patent: experimental part Bini, Riccardo; Chiappe, Cinzia; Pomelli, Christian Silvio; Parisi, Benedetta [Journal of Organic Chemistry, 2009, vol. 74, # 22, p. 8522 - 8530]
[14]Location in patent: scheme or table Kore, Rajkumar; Srivastava, Rajendra [Journal of Molecular Catalysis A: Chemical, 2011, vol. 345, # 1-2, p. 117 - 126]
[15]Location in patent: scheme or table Li, Xinzhong; Lin, Qi; Ma, Liang [Ultrasonics Sonochemistry, 2010, vol. 17, # 5, p. 752 - 755] Location in patent: scheme or table Kore, Rajkumar; Srivastava, Rajendra [Catalysis Communications, 2011, vol. 12, # 15, p. 1420 - 1424]
[16]Location in patent: experimental part Ceron, Miguel A.; Guzman-Lucero, Diego J.; Palomeque, Jorge F.; Martinez-Palou, Rafael [Combinatorial Chemistry and High Throughput Screening, 2012, vol. 15, # 5, p. 427 - 432]
[17]Location in patent: scheme or table Kore, Rajkumar; Srivastava, Rajendra [Tetrahedron Letters, 2012, vol. 53, # 26, p. 3245 - 3249]
[18]Location in patent: scheme or table Kore, Rajkumar; Kumar, T.J. Dhilip; Srivastava, Rajendra [Journal of Molecular Catalysis A: Chemical, 2012, vol. 360, p. 61 - 70]
[19]Kore, Rajkumar; Tumma, Mahesh; Srivastava, Rajendra [Catalysis Today, 2012, vol. 198, # 1, p. 189 - 196]
[20]Ravindran, Anaswara; Kore, Rajkumar; Srivastava, Rajendra [Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2013, vol. 52, # 1, p. 129 - 135]
[21]Kore, Rajkumar; Srivastava, Rajendra [Journal of Molecular Catalysis A: Chemical, 2013, vol. 376, p. 90 - 97]
[22]Wang, Jinquan; Sng, Waihong; Yi, Guangshun; Zhang, Yugen [Chemical Communications, 2015, vol. 51, # 60, p. 12076 - 12079]
[23]Banerjee, Mainak; Karri, Ramesh; Rawat, Kuber Singh; Muthuvel, Karthick; Pathak, Biswarup; Roy, Gouriprasanna [Angewandte Chemie - International Edition, 2015, vol. 54, # 32, p. 9323 - 9327][Angew. Chem., 2015, vol. 127, p. 9455 - 9459,5]
[24]Current Patent Assignee: SANYO CHEMICAL INDUSTRIES LTD; EVONIK INDUSTRIES AG - US2016/9737, 2016, A1 Location in patent: Paragraph 0109
[25]Pellerite, Mark J.; Kaplun, Marina M.; Webb, Robert J. [Journal of Organic Chemistry, 2019, vol. 84, # 23, p. 15486 - 15497]

2
[ 1934-75-4 ]
[ 36443-80-8 ]
1-benzyl-3-methylimidazolium dicyanoamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
93%	In water at 20℃; for 12h; Inert atmosphere;

Reference： [1]Location in patent: experimental part Kilpelaeinen, Ilkka; Xie, Haibo; King, Alistair; Granstrom, Mari; Heikkinen, Sami; Argyropoulos, Dimitris S. [Journal of Agricultural and Food Chemistry, 2007, vol. 55, # 22, p. 9142 - 9148]

3
[ 12107-56-1 ]
[ 918824-07-4 ]
[ 36443-80-8 ]
[Pd(1-(methyl)-3-(benzyl)imidazol-2-ylidene)2Cl₂] [ No CAS ]