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CAS No. : | 368-50-3 | MDL No. : | MFCD00047847 |
Formula : | C6H6FNO2S | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | PLSYVJDMJWGODG-UHFFFAOYSA-N |
M.W : | 175.18 | Pubchem ID : | 67780 |
Synonyms : |
|
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P260-P264-P270-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P405-P501 | UN#: | 3261 |
Hazard Statements: | H302-H332-H314 | Packing Group: | Ⅱ |
GHS Pictogram: |
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* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | Stage #1: 3-amino-benzenesulfonyl fluoride With hydrogenchloride; sodium nitrite In water at -10 - 20℃; for 0.333333h; Stage #2: With thionyl chloride; copper(l) chloride In water at -5℃; for 3h; | |
(i) (diazotization), (ii) SO3, Cu2Cl2, AcOH; Multistep reaction; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
(i) SOCl2, (ii) /BRN= 2641150/; Multistep reaction; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
(i) SOCl2, (ii) /BRN= 2641150/; Multistep reaction; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
39% | With triethylamine In acetonitrile at 60℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
39% | With triethylamine In acetonitrile at 60℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / NEt3 / acetonitrile / 6 h / 60 °C 2: acetonitrile / 3 h / Heating |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / NEt3 / acetonitrile / 6 h / 60 °C 2: acetonitrile / 3 h / Heating |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / NEt3 / acetonitrile / 6 h / 60 °C 2: acetonitrile / 1 h / Ambient temperature |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / NEt3 / acetonitrile / 6 h / 60 °C 2: 1) NEt3, 2) HOAc / 1) EtOH, r.t., 2 h, 2) EtOH, reflux, 3 h |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / NEt3 / acetonitrile / 6 h / 60 °C 2: 1) NEt3, 2) HOAc / 1) EtOH, r.t., 2 h, 2) EtOH, reflux, 3 h |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / NEt3 / acetonitrile / 6 h / 60 °C 2: 1) NEt3, 2) HOAc / 1) EtOH, r.t., 2 h, 2) EtOH, reflux, 3 h |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / triethylamine / acetonitrile / 6 h / 60 °C 2: acetonitrile / 3 h / Heating |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / triethylamine / acetonitrile / 6 h / 60 °C 2: acetonitrile / 1 h / Ambient temperature |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 39 percent / triethylamine / acetonitrile / 6 h / 60 °C 2: 1.) triethylamine, 2.) acetic acid / 1.) 2 h, 2.) reflux, 3 h |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 2: H2 / PtO2 |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
77% | In isopropyl alcohol at 110℃; Sealed tube; Microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
74% | In isopropyl alcohol at 110℃; Sealed tube; Microwave irradiation; | 4.1.4. General procedure for the preparation of the 4-anilino-2-phenylquinazoline derivatives 15-62 General procedure: The corresponding 4-chloroquinazoline derivative 8-14(1 mmol) was added to isopropanol (5 mL) with the correspondingsubstituted aniline derivative (1 mmol) and sealed in a microwavetube. The mixture was heated by 100 W microwave irradiation to110 °C for a period of 15-30 min to completion of the reaction,indicated by TLC. The formed precipitate was filtered, washed with10 mL isopropanol and dried in vacuo. If no precipitate is formed,the solvent was removed under reduced pressure and theremaining solid recrystallized from ethanol. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
81% | With hydrogenchloride; iron In ethanol; water at 90℃; for 4h; | |
79% | With 5%-palladium/activated carbon; hydrogen In methanol at 50℃; for 72h; Autoclave; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: potassium fluoride; triethylamine / water; dichloromethane / 4 h / 20 °C 2: hydrogen; 5%-palladium/activated carbon / methanol / 72 h / 50 °C / Autoclave |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: sodium nitrite; hydrogenchloride / water / 0.33 h / -10 - 20 °C 1.2: 3 h / -5 °C 2.1: pyridine / chloroform / 48 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
88% | In methanol; water at 45℃; for 24h; | 1 Example 1 Synthesis of compound of formula 4 (3-(2-chloro-5-methylpyrimidine-4-amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (1.80g, 10.3mmol), 2,4-dichloro-5-methylpyrimidine (2.00g, 1.2eq), methanol/water=1:1 (34mL) into the reaction flask , React at 45°C for 24 hours. A white solid precipitated out during the reaction, filtered with suction, the filter cake was washed with methanol/water=1:1, and dried to obtain a white solid with a yield of 88%. |
88% | Stage #1: 2,6-dichloro-5-methylpyrimidine; 3-amino-benzenesulfonyl fluoride In methanol; water at 45℃; for 24h; Stage #2: In methanol; water at 15℃; for 0.5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; water at 45℃; for 24h; | 2 Example 2 Synthesis of compound of formula 4 (3-((2-chloropyrimidin-4-yl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), 2,4-dichloropyrimidine (35.8mg, 1.2eq), methanol/water=1:1 (0.66mL) to the reaction flask, and react at 45 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; water at 45℃; for 24h; | 3 Example 3 Synthesis of compound of formula 4 (3-((2-chloro-5-fluoropyrimidin-4-yl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), 2,4-dichloro-5-fluoropyrimidine (40.0mg, 1.2eq), methanol/water=1:1 (0.66mL) to the reaction flask , React at 45°C for 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; water at 45℃; for 24h; | 4 Example 4 Synthesis of compound of formula 4 (3-((2-chloro-5-nitropyrimidin-4-yl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), 2,4-dichloro-5-nitropyrimidine (46.6mg, 1.2eq), methanol/water=1:1 (0.66mL) to the reaction flask ), react at 45°C for 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; water at 45℃; for 24h; | 5 Example 5 Synthesis of compound of formula 4 (3-((2-chloro-5-trifluoromethylpyrimidin-4-yl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), 2,4-dichloro-5-trifluoromethylpyrimidine (52.1mg, 1.2eq) to the reaction flask, methanol/water=1:1 ( 0.66mL), react at 45°C for 24h. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; water at 45℃; for 24h; | 6 Example 6 Synthesis of compound of formula 4 (ethyl 2-chloro-4-((3-(fluorosulfonyl)phenyl)amino)pyrimidine-5-carboxylate) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), ethyl 2,4-dichloro-5-pyrimidinecarboxylate (53.0mg, 1.2eq), methanol/water=1:1 (0.66 mL), react at 45°C for 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; water at 45℃; for 24h; | 7 Example 7 Synthesis of compound of formula 4 (3-((6-chloro-5-cyano-4-methylpyridin-2-yl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), 3-cyano-4-methyl-2,6-dichloropyridine (44.9mg, 1.2eq) to the reaction flask, methanol/water=1 :1 (0.66 mL), react at 45°C for 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; water at 45℃; for 24h; | 8 Example 8 Synthesis of compound of formula 4 (3-((6-chloro-5-nitropyridin-3-yl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), 2,5-dichloro-3-nitropyridine (46.3mg, 1.2eq), methanol/water=1:1 (0.66mL) to the reaction flask ), react at 45°C for 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In water; isopropyl alcohol at 85℃; for 24h; | 9 Example 9 Synthesis of compound of formula 4 (3-((6-chloro-5-(trifluoromethyl)pyridin-2-yl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0mg, 0.2mmol), 2,6-dichloro-3-trifluoromethylpyridine (51.8mg, 1.2eq), isopropanol/water=1: 1 (0.66 mL), react at 85°C for 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In dimethyl sulfoxide at 85℃; for 24h; | 10 Example 10 Synthesis of compound of formula 4 (3-((2,3,5-trichloro-4,6-dicyanophenyl)amino)benzenesulfonyl fluoride) Add 3-aminobenzenesulfonyl fluoride (35.0 mg, 0.2 mmol), tetrachloro m-benzenedicyanide (63.8 mg, 1.2 eq), DMSO (1 mL) to the reaction flask, and react at 85°C for 24 hours. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1: methanol; water / 24 h / 45 °C 2: hydrogenchloride / water; isopropyl alcohol / 24 h / 70 °C 3: benzotriazol-1-ol; N-ethyl-N,N-diisopropylamine; 1,1,3,3-Tetramethyldisiloxane / dimethyl sulfoxide / 24 h / 25 °C | ||
Multi-step reaction with 4 steps 1.1: methanol; water / 24 h / 45 °C 1.2: 0.5 h / 15 °C 2.1: hydrogenchloride / isopropyl alcohol / 24 h / 70 °C 3.1: sodium hydroxide / water / 10 °C / pH 9 - 10 4.1: N-ethyl-N,N-diisopropylamine; 1,1,3,3-Tetramethyldisiloxane; benzotriazol-1-ol / dimethyl sulfoxide / 24 h / 25 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
88% | With potassium carbonate In N,N-dimethyl-formamide at 20℃; | 3-((3-nitrobenzyl)amino)benzenesulfonyl fluoride (18) A solution of 3-nitrobenzyl bromide (50 mg, 0.23 mmol) and 3-aminobenzene-1-sulfonyl fluoride (41 mg, 0.23 mmol) in 20 mL of DMF was treated with K2CO3 (35 mg, 0.25 mmol). The resulting mixture was stirred overnight at RT. After the reaction was completed, the reaction mixture was poured into ice water, aqueous phase was extracted with ethyl acetate. The combined organic phase was washed with brine twice, dried and concentrated. The resulting residue was purified by silica gel flash chromatography to give the compound as yellow oil (63 mg, 88%) MS (ESI): m/z 311.1 [M + H]+. |
Tags: 368-50-3 synthesis path| 368-50-3 SDS| 368-50-3 COA| 368-50-3 purity| 368-50-3 application| 368-50-3 NMR| 368-50-3 COA| 368-50-3 structure
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Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
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Prevention | |
Code | Phrase |
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P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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