Alternatived Products of [ 3753-18-2 ]
Product Details of [ 3753-18-2 ]
CAS No. : | 3753-18-2 |
MDL No. : | MFCD03840532 |
Formula : |
C16H18O2
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | MODAACUAXYPNJH-UHFFFAOYSA-N |
M.W : |
242.31
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Pubchem ID : | 1519430 |
Synonyms : |
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Application In Synthesis of [ 3753-18-2 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 3753-18-2 ]
Yield | Reaction Conditions | Operation in experiment |
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Dichlorid II, KOH, MeOH; |
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- 2
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[ 3753-18-2 ]
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[ 66-98-8 ]
Yield | Reaction Conditions | Operation in experiment |
93.3 %Chromat. |
With sodium bromate; acetic acid at 90℃; for 1.5h; |
11
In the same manner as in Example 3, the operation was conducted, except that 0.53 g (2 mmols) of bismethoxymethylbiphenyl was used in place of m-methoxybenzyl alcohol and also 0.2 g (1.35 mmols) of sodium bromate was used. With respect to the components in the reaction solution, 4,4'-bisformylbiphenyl was produced in an area ratio, as determined by gas chromatography, of 93.3% and 6.7% of bismethoxymethylbiphenyl as a raw material was remained. Example 3 (An embodiment of the invention described in the above embodiment [1]): Production of m-methoxybenzaldehyde In a 15 ml test tube type reaction vessel equipped with a magnetic stirrer and a reflux condenser, 0.55 g (4 mmols) of m-methoxybenzyl alcohol, 0.18 g (1.2 mmols) of sodium bromate and 2 ml (34.8 mmols) of acetic acid were charged, and then the resultant mixture was stirred at 90°C for 1.5 hours. Along with the progress of the reaction, a small amount of bromine was produced. After the completion of the reaction, bromine completely disappeared. |
- 3
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[ 92-52-4 ]
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[ 109-87-5 ]
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[ 86130-05-4 ]
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[ 3753-18-2 ]
Yield | Reaction Conditions | Operation in experiment |
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In cyclohexane at 120℃; for 4h; |
36
Example 36; Example 27 was repeated using biphenyl as starting material The only mono- substituted isomer obtained was the 4-(methoxymethyl) biphenyl and the only desiredM EPO di-substituted isomer was the desired 4,4'-(dimethoxymethyl)biphenyl. The results are set out in Table 1 1.Table 11 |
Yield | Reaction Conditions | Operation in experiment |
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S.2 Synthesis of copolymer of 9,9-bis(hydroxyphenyl)fluorene and 4,4'-bis(methoxymethyl)biphenyl
Synthesis Example 2 Synthesis of copolymer of 9,9-bis(hydroxyphenyl)fluorene and 4,4'-bis(methoxymethyl)biphenyl |
- 5
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[ 1195-44-4 ]
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[ 3753-18-2 ]
Yield | Reaction Conditions | Operation in experiment |
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With zinc In 1-methyl-pyrrolidin-2-one at 20 - 70℃; Inert atmosphere; |
15
To a glass reaction container equipped with a cooling apparatus, 15.3 mg of nickel bromide, 19.2 mg of 5-trimethylsilyl-2,2'-bipyridine and 91.6 mg of zinc powder were added in an atmosphere of nitrogen at room temperature. To the obtained mixture, 109. 6 mg of 1-chloro-4-(methoxymethyl) benzene and 5 mL of N-methyl-2-pyrrolidone were added. The obtained mixture was reacted at 70°C for 2 hours to obtain a reaction mixture containing 4,4'-bis(methoxymethyl)biphenyl. The yield of 4,4'-bis(methoxymethyl)biphenyl was 67.8 mg. |
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With zinc In 1-methyl-pyrrolidin-2-one at 20 - 70℃; Inert atmosphere; |
19
To a glass reaction container equipped with a cooling apparatus, 15.3 mg of nickel bromide, 25.2 mg of 5,5'-bis(trimethylsilyl)-2,2'-bipyridine and 91.6 mg of zinc powder were added under an atmosphere of nitrogen at room temperature. To the obtained mixture, 109.6 mg of 1-chloro-4-(methoxymethyl)benzene and 5 mL of N-methyl-2-pyrrolidone were added at room temperature. The obtained mixture was reacted at 70°C for 2 hours to obtain a reaction mixture containing 4,4'-bis(methoxymethyl)biphenyl. The yield of 4,4'-bis(methoxymethyl)biphenyl was 63.0 mg. |
- 6
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diethyl 2-(cycloheptene-1-yl)-cyclobuten-1-yl phosphate
[ No CAS ]
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4-(methoxymethyl)phenylzinc chloride lithium chloride
[ No CAS ]
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[ 3753-18-2 ]
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1-cycloheptenyl-2-[4-(methoxymethyl)phenyl]cyclobutene
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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With aluminum (III) chloride; C36H28Cl2OP2Pd In tetrahydrofuran at 50℃; for 17h; Overall yield = 73 %; Overall yield = 0.451 g; |
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