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[ CAS No. 3753-18-2 ] {[proInfo.proName]}

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Chemical Structure| 3753-18-2
Chemical Structure| 3753-18-2
Structure of 3753-18-2 * Storage: {[proInfo.prStorage]}
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Product Details of [ 3753-18-2 ]

CAS No. :3753-18-2 MDL No. :MFCD03840532
Formula : C16H18O2 Boiling Point : -
Linear Structure Formula :- InChI Key :MODAACUAXYPNJH-UHFFFAOYSA-N
M.W : 242.31 Pubchem ID :1519430
Synonyms :

Safety of [ 3753-18-2 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P260-P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P362+P364-P405-P403+P233-P501 UN#:N/A
Hazard Statements:H315-H319-H335-H361-H373 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 3753-18-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3753-18-2 ]

[ 3753-18-2 ] Synthesis Path-Downstream   1~6

YieldReaction ConditionsOperation in experiment
Dichlorid II, KOH, MeOH;
  • 2
  • [ 3753-18-2 ]
  • [ 66-98-8 ]
YieldReaction ConditionsOperation in experiment
93.3 %Chromat. With sodium bromate; acetic acid at 90℃; for 1.5h; 11 In the same manner as in Example 3, the operation was conducted, except that 0.53 g (2 mmols) of bismethoxymethylbiphenyl was used in place of m-methoxybenzyl alcohol and also 0.2 g (1.35 mmols) of sodium bromate was used. With respect to the components in the reaction solution, 4,4'-bisformylbiphenyl was produced in an area ratio, as determined by gas chromatography, of 93.3% and 6.7% of bismethoxymethylbiphenyl as a raw material was remained. Example 3 (An embodiment of the invention described in the above embodiment [1]): Production of m-methoxybenzaldehyde In a 15 ml test tube type reaction vessel equipped with a magnetic stirrer and a reflux condenser, 0.55 g (4 mmols) of m-methoxybenzyl alcohol, 0.18 g (1.2 mmols) of sodium bromate and 2 ml (34.8 mmols) of acetic acid were charged, and then the resultant mixture was stirred at 90°C for 1.5 hours. Along with the progress of the reaction, a small amount of bromine was produced. After the completion of the reaction, bromine completely disappeared.
  • 3
  • [ 92-52-4 ]
  • [ 109-87-5 ]
  • [ 86130-05-4 ]
  • [ 3753-18-2 ]
YieldReaction ConditionsOperation in experiment
In cyclohexane at 120℃; for 4h; 36 Example 36; Example 27 was repeated using biphenyl as starting material The only mono- substituted isomer obtained was the 4-(methoxymethyl) biphenyl and the only desiredM EPO di-substituted isomer was the desired 4,4'-(dimethoxymethyl)biphenyl. The results are set out in Table 1 1.Table 11
YieldReaction ConditionsOperation in experiment
S.2 Synthesis of copolymer of 9,9-bis(hydroxyphenyl)fluorene and 4,4'-bis(methoxymethyl)biphenyl Synthesis Example 2 Synthesis of copolymer of 9,9-bis(hydroxyphenyl)fluorene and 4,4'-bis(methoxymethyl)biphenyl
  • 5
  • [ 1195-44-4 ]
  • [ 3753-18-2 ]
YieldReaction ConditionsOperation in experiment
With zinc In 1-methyl-pyrrolidin-2-one at 20 - 70℃; Inert atmosphere; 15 To a glass reaction container equipped with a cooling apparatus, 15.3 mg of nickel bromide, 19.2 mg of 5-trimethylsilyl-2,2'-bipyridine and 91.6 mg of zinc powder were added in an atmosphere of nitrogen at room temperature. To the obtained mixture, 109. 6 mg of 1-chloro-4-(methoxymethyl) benzene and 5 mL of N-methyl-2-pyrrolidone were added. The obtained mixture was reacted at 70°C for 2 hours to obtain a reaction mixture containing 4,4'-bis(methoxymethyl)biphenyl. The yield of 4,4'-bis(methoxymethyl)biphenyl was 67.8 mg.
With zinc In 1-methyl-pyrrolidin-2-one at 20 - 70℃; Inert atmosphere; 19 To a glass reaction container equipped with a cooling apparatus, 15.3 mg of nickel bromide, 25.2 mg of 5,5'-bis(trimethylsilyl)-2,2'-bipyridine and 91.6 mg of zinc powder were added under an atmosphere of nitrogen at room temperature. To the obtained mixture, 109.6 mg of 1-chloro-4-(methoxymethyl)benzene and 5 mL of N-methyl-2-pyrrolidone were added at room temperature. The obtained mixture was reacted at 70°C for 2 hours to obtain a reaction mixture containing 4,4'-bis(methoxymethyl)biphenyl. The yield of 4,4'-bis(methoxymethyl)biphenyl was 63.0 mg.
  • 6
  • diethyl 2-(cycloheptene-1-yl)-cyclobuten-1-yl phosphate [ No CAS ]
  • 4-(methoxymethyl)phenylzinc chloride lithium chloride [ No CAS ]
  • [ 3753-18-2 ]
  • 1-cycloheptenyl-2-[4-(methoxymethyl)phenyl]cyclobutene [ No CAS ]
YieldReaction ConditionsOperation in experiment
With aluminum (III) chloride; C36H28Cl2OP2Pd In tetrahydrofuran at 50℃; for 17h; Overall yield = 73 %; Overall yield = 0.451 g;
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