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[ CAS No. 38002-87-8 ] {[proInfo.proName]}

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Chemical Structure| 38002-87-8
Chemical Structure| 38002-87-8
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Product Details of [ 38002-87-8 ]

CAS No. :38002-87-8 MDL No. :MFCD06751841
Formula : C11H12O2 Boiling Point : -
Linear Structure Formula :- InChI Key :JMLPELHBEYALIG-UHFFFAOYSA-N
M.W : 176.21 Pubchem ID :347848
Synonyms :

Calculated chemistry of [ 38002-87-8 ]      Expand+

Physicochemical Properties

Num. heavy atoms : 13
Num. arom. heavy atoms : 6
Fraction Csp3 : 0.18
Num. rotatable bonds : 4
Num. H-bond acceptors : 2.0
Num. H-bond donors : 0.0
Molar Refractivity : 52.27
TPSA : 26.3 Ų

Pharmacokinetics

GI absorption : High
BBB permeant : Yes
P-gp substrate : No
CYP1A2 inhibitor : Yes
CYP2C19 inhibitor : No
CYP2C9 inhibitor : No
CYP2D6 inhibitor : No
CYP3A4 inhibitor : No
Log Kp (skin permeation) : -5.25 cm/s

Lipophilicity

Log Po/w (iLOGP) : 2.36
Log Po/w (XLOGP3) : 2.99
Log Po/w (WLOGP) : 2.45
Log Po/w (MLOGP) : 1.95
Log Po/w (SILICOS-IT) : 2.87
Consensus Log Po/w : 2.52

Druglikeness

Lipinski : 0.0
Ghose : None
Veber : 0.0
Egan : 0.0
Muegge : 1.0
Bioavailability Score : 0.55

Water Solubility

Log S (ESOL) : -2.89
Solubility : 0.225 mg/ml ; 0.00128 mol/l
Class : Soluble
Log S (Ali) : -3.21
Solubility : 0.11 mg/ml ; 0.000622 mol/l
Class : Soluble
Log S (SILICOS-IT) : -3.32
Solubility : 0.0841 mg/ml ; 0.000478 mol/l
Class : Soluble

Medicinal Chemistry

PAINS : 0.0 alert
Brenk : 2.0 alert
Leadlikeness : 1.0
Synthetic accessibility : 1.66

Safety of [ 38002-87-8 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 38002-87-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 38002-87-8 ]

[ 38002-87-8 ] Synthesis Path-Downstream   1~50

  • 1
  • [ 769-42-6 ]
  • [ 38002-87-8 ]
  • 1,3-Dimethyl-5-[2-(2-methyl-allyloxy)-benzylidene]-pyrimidine-2,4,6-trione [ No CAS ]
YieldReaction ConditionsOperation in experiment
90% With ethylenediamine diacetic acid methylene dichloride or acetonitrile;
  • 2
  • [ 38002-87-8 ]
  • [ 38002-88-9 ]
YieldReaction ConditionsOperation in experiment
43% With aluminium trichloride In dichloromethane at -70 - 20℃; for 3h;
  • 3
  • [ 90-02-8 ]
  • [ 563-47-3 ]
  • [ 38002-87-8 ]
YieldReaction ConditionsOperation in experiment
90% With potassium carbonate; potassium iodide In N,N-dimethyl-formamide; acetone Heating;
82% With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 24h; Inert atmosphere;
With potassium carbonate; potassium iodide In acetone Heating; Yield given;
  • 4
  • [ 558-13-4 ]
  • [ 38002-87-8 ]
  • 1-(2,2-Dibromo-vinyl)-2-(2-methyl-allyloxy)-benzene [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triphenylphosphine In dichloromethane at 0℃; Yield given;
With triphenylphosphine In dichloromethane at 0 - 20℃; Inert atmosphere;
With triphenylphosphine In dichloromethane at 0 - 20℃;
  • 5
  • [ 1458-98-6 ]
  • [ 90-02-8 ]
  • [ 38002-87-8 ]
YieldReaction ConditionsOperation in experiment
99% With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 1h;
With potassium carbonate In acetone Heating; Yield given;
With potassium carbonate In acetonitrile at 60℃;
With potassium carbonate In N,N-dimethyl-formamide at 50℃; Inert atmosphere;
With potassium carbonate In N,N-dimethyl-formamide at 50℃;
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 6h;
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 12h;

  • 6
  • [ 1458-98-6 ]
  • [ 89-95-2 ]
  • [ 38002-87-8 ]
YieldReaction ConditionsOperation in experiment
78% With potassium carbonate In N,N-dimethyl-formamide at 20℃;
With potassium carbonate In acetone at 56℃; for 2h;
  • 7
  • [ 13200-60-7 ]
  • [ 38002-87-8 ]
  • (2RS,3aSR,9bRS)-2-ethoxycarbonyl-1,2,3,3a,4,9b-hexahydro-1,3a-dimethyl[1]benzopyrano[4,3-b]pyrrole [ No CAS ]
YieldReaction ConditionsOperation in experiment
98% In xylene at 130℃; for 0.5h; microwave irradiation;
  • 8
  • [ 38002-87-8 ]
  • [ 5804-85-3 ]
  • hydroxy-[2-(2-methyl-allyloxy)-phenyl]-acetonitrile [ No CAS ]
YieldReaction ConditionsOperation in experiment
In toluene at 0 - 25℃; for 1.5h;
  • 9
  • [ 38002-87-8 ]
  • [ 657401-94-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C
  • 10
  • [ 38002-87-8 ]
  • (1E,11Z)-2-Methoxy-11-methyl-9-oxa-tricyclo[12.3.1.03,8]octadeca-1,3(8),4,6,11-pentaene-17,18-dione [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C 5: 71 percent / PhCH=RuCl2(PCy3)(N,N'-Mes2-imidazolidin-2-yl) / CH2Cl2 / 17 h / 40 °C
  • 11
  • [ 38002-87-8 ]
  • (Z)-17-Methoxy-11-methyl-9-oxa-tricyclo[12.3.1.03,8]octadeca-1(17),3(8),4,6,11-pentaene-2,18-dione [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C 5: 68 percent / PhCH=RuCl2(PCy3)(N,N'-Mes2-imidazolidin-2-yl) / CH2Cl2 / 14 h / 40 °C
  • 12
  • [ 38002-87-8 ]
  • [ 657401-97-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C
  • 13
  • [ 38002-87-8 ]
  • [ 657402-02-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C
  • 14
  • [ 38002-87-8 ]
  • [ 657402-06-7 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C
  • 15
  • [ 38002-87-8 ]
  • 2-[1-Methoxy-1-[2-(2-methyl-allyloxy)-phenyl]-meth-(Z)-ylidene]-4-(3-methyl-but-2-enyl)-cyclohexane-1,3-dione [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C
  • 16
  • [ 38002-87-8 ]
  • (Z)-17-Methoxy-11-methyl-14-(3-methyl-but-2-enyl)-9-oxa-tricyclo[12.3.1.03,8]octadeca-1(17),3(8),4,6,11-pentaene-2,18-dione [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C 5: 88 percent / PhCH=RuCl2(PCy3)(N,N'-Mes2-imidazolidin-2-yl) / CH2Cl2 / 1.5 h / 40 °C
  • 17
  • [ 38002-87-8 ]
  • (1E,11Z)-2-Methoxy-11-methyl-14-(3-methyl-but-2-enyl)-9-oxa-tricyclo[12.3.1.03,8]octadeca-1,3(8),4,6,11-pentaene-17,18-dione [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C 5: 63 percent / PhCH=RuCl2(PCy3)(N,N'-Mes2-imidazolidin-2-yl) / CH2Cl2 / 3 h / 40 °C
  • 18
  • [ 38002-87-8 ]
  • [ 657401-98-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C
  • 19
  • [ 38002-87-8 ]
  • [ 657402-07-8 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C
  • 20
  • [ 38002-87-8 ]
  • [ 657402-03-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: toluene / 1.5 h / 0 - 25 °C 2: PCC / CH2Cl2 / 7 h / 40 °C 3: Et3N / tetrahydrofuran / 12 h / 25 °C 4: diethyl ether / 1 h / 0 °C
  • 21
  • [ 38002-87-8 ]
  • 2-Methyl-3-(2-methyl-allyl)-benzofuran [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: PPh3 / CH2Cl2 / 0 °C 2: BuLi / tetrahydrofuran / -78 - 20 °C 3: BuLi, H2O / tetrahydrofuran 4: 70 percent / Pd(PPh3)4 / acetonitrile; tetrahydrofuran / 6 h / 80 °C
  • 22
  • [ 38002-87-8 ]
  • ((3R,4R)-4-Amino-3-methyl-chroman-3-yl)-methanol [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 15 percent / CaCl2 / toluene / 36 h / Heating 2: 89 percent / H2 / 10percent Pd/C / acetic acid / 6 h
  • 23
  • [ 38002-87-8 ]
  • ((3S,4S)-4-Amino-3-methyl-chroman-3-yl)-methanol [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 32 percent / CaCl2 / toluene / 36 h / Heating 2: 88 percent / H2 / 10percent Pd/C / acetic acid / 6 h
  • 24
  • [ 38002-87-8 ]
  • [ 4303-29-1 ]
  • (5aRS,11bRS)-3,5a,6,11b-tetrahydro-5a-methyl-2H,5H-[1]benzopyrano[4',3':4,5]thiopyrano[2,3-d][1,3]thiazol-2-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
71% With triethylamine In acetic acid at 20℃; for 12h;
  • 25
  • [ 38002-87-8 ]
  • [ 162971-77-9 ]
YieldReaction ConditionsOperation in experiment
25% With tin(IV) chloride In dichloromethane at 40℃; for 1h;
at 180℃;
  • 26
  • [ 16567-18-3 ]
  • [ 38002-87-8 ]
  • C20H19NO2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
55% Stage #1: 8-bromoquinoline With n-butyllithium In tetrahydrofuran; hexane at -78℃; Inert atmosphere; Stage #2: O-methallylsalicylaldehyde In tetrahydrofuran; hexane at -78 - 20℃; for 2.5h; Inert atmosphere;
  • 29
  • [ 38002-87-8 ]
  • [ 124-40-3 ]
  • [ 1314018-12-6 ]
YieldReaction ConditionsOperation in experiment
In water at 50℃; for 5h; Inert atmosphere; Preparation of aromatic N,N-acetals 11 General procedure: To the aqueous solution of 40% dimethylamine (12.0 mL, 108.0 mmol) was added aldehyde (24.4 mmol) in one portion at 50 °C. The reaction mixture was stirred for 5 h at 50 °C. After cooling to room temperature, the mixture was saturated with potassium carbonate, and then the upper layer was separated with the aid of ether (50 mL). After drying over potassium carbonate and evaporating, the pure N,N-acetal 1 was obtained using Kugelrohr distillation.
  • 30
  • [ 38002-87-8 ]
  • [ 23534-97-6 ]
  • [ 1314234-78-0 ]
YieldReaction ConditionsOperation in experiment
90% Stage #1: 1,1,3‐tribromo‐2,2‐dimethylcyclopropane With n-butyllithium In hexanes; diethyl ether at -78 - -10℃; for 1h; Stage #2: O-methallylsalicylaldehyde In hexanes; diethyl ether at -50 - -10℃; for 0.25h; Stage #3: With ammonium chloride In hexanes; diethyl ether; water Saturated solution;
  • 31
  • [ 38002-87-8 ]
  • [ 3355-28-0 ]
  • [ 1332626-74-0 ]
YieldReaction ConditionsOperation in experiment
50% With indium; water; indole-2,3-dione; ammonium chloride In tetrahydrofuran at 0℃;
  • 32
  • [ 38002-87-8 ]
  • [ 173019-84-6 ]
  • [ 1332626-80-8 ]
YieldReaction ConditionsOperation in experiment
45% With indium; water; indole-2,3-dione; ammonium chloride In tetrahydrofuran at 0℃;
  • 33
  • [ 38002-87-8 ]
  • [ 173019-85-7 ]
  • [ 1332626-79-5 ]
YieldReaction ConditionsOperation in experiment
46% With indium; water; indole-2,3-dione; ammonium chloride In tetrahydrofuran at 0℃;
  • 34
  • [ 38002-87-8 ]
  • [ 1794-48-5 ]
  • [ 1332626-75-1 ]
YieldReaction ConditionsOperation in experiment
55% With indium; water; indole-2,3-dione; ammonium chloride In tetrahydrofuran at 0℃;
55% With indium; ammonium chloride In tetrahydrofuran; water at 0℃;
  • 35
  • [ 38002-87-8 ]
  • 2-ethynyl-(2-methyl-2-propenyloxy)benzene [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: triphenylphosphine / dichloromethane / 0 - 20 °C 2: methyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere
  • 36
  • [ 38002-87-8 ]
  • [ 2926-30-9 ]
  • 3-methyl-3-(2,2,2-trifluoroethyl)chroman-4-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
30% With dipotassium peroxodisulfate In water; dimethyl sulfoxide at 100℃; for 24h; Schlenk technique; Sealed tube; chemoselective reaction;
With dipotassium peroxodisulfate In water; acetonitrile at 70℃; for 8h; Schlenk technique; Sealed tube; Example 1 General procedure: Add 1 mmol of allyl salicylaldehyde in a clean and dry 20 mL Schlenk pressure-resistant reaction tube.1.5 mmol of sodium trifluoromethylsulfinate, 3 mmol of potassium persulfate,Further, 1.5 mL of acetonitrile and 2.5 mL of water were added as a solvent, and the reaction tube was sealed and placed in an oil bath at 70 ° C to heat the reaction for 8 hours.After the reaction was completed, ethyl acetate was added to extract the reaction mixture, and the organic phase was dried by a rotary evaporator.The residue obtained was treated with petroleum ether and ethyl acetate as eluents.The title product was obtained as a colorless oily liquid, eluted from silica gel column, yield 62%.
  • 37
  • [ 1458-98-6 ]
  • [ 88284-48-4 ]
  • [ 38002-87-8 ]
YieldReaction ConditionsOperation in experiment
74% With cesium fluoride In N,N-dimethyl-formamide at 20℃; for 1h;
  • 38
  • [ 38002-87-8 ]
  • [ 622-30-0 ]
  • (E)-N-benzyl-1-(2-((2-methylallyl)oxy)phenyl)methanimine oxide [ No CAS ]
YieldReaction ConditionsOperation in experiment
In 1,2-dichloro-ethane at 20℃; for 2h;
  • 39
  • [ 38002-87-8 ]
  • (cis)-1-benzyl-3a-methyl-1,3a,4,9b-tetrahydro-3H-chromeno[4,3-c]isoxazole [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 1,2-dichloro-ethane / 2 h / 20 °C 2: tris(2,2'-bipyridyl)ruthenium dichloride / acetonitrile / 24 h / 20 °C / Inert atmosphere; Irradiation
  • 40
  • [ 38002-87-8 ]
  • [ 874-60-2 ]
  • 3-methyl-3-(2-oxo-2-(p-tolyl)ethyl)chroman-4-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In acetonitrile at 20℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation; Green chemistry;
  • 41
  • [ 38002-87-8 ]
  • [ 403-43-0 ]
  • 3-(2-(4-fluorophenyl)-2-oxoethyl)-3-methylchroman-4-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
72% With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In acetonitrile at 20℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation; Green chemistry;
  • 42
  • [ 38002-87-8 ]
  • [ 122-01-0 ]
  • 3-(2-(4-chlorophenyl)-2-oxoethyl)-3-methylchroman-4-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
58% With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In acetonitrile at 20℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation; Green chemistry;
  • 43
  • [ 38002-87-8 ]
  • [ 98-88-4 ]
  • 3-methyl-3-(2-oxo-2-phenylethyl)chroman-4-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In acetonitrile at 20℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation; Green chemistry;
  • 44
  • [ 38002-87-8 ]
  • [ 685-87-0 ]
  • diethyl 2-((3-methyl-4-oxochroman-3-yl)methyl)malonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
57% With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In dimethyl sulfoxide at -78℃; for 30h; Schlenk technique; Inert atmosphere; Irradiation;
  • 45
  • [ 536-57-2 ]
  • [ 38002-87-8 ]
  • 3-methyl-3-(p-tosylmethyl)chroman-4-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
62% With ammonium peroxydisulfate In water; dimethyl sulfoxide at 20℃; for 12h; Irradiation;
  • 46
  • [ 7677-24-9 ]
  • [ 38002-87-8 ]
  • [ 104416-52-6 ]
YieldReaction ConditionsOperation in experiment
63% With tert.-butylhydroperoxide; 4,4'-dibromo-2,2'-bipyridine; copper(l) chloride In acetonitrile at 80℃; for 24h; Inert atmosphere; Schlenk technique; Green chemistry; 1.1 General procedure for synthesis of compounds 3 General procedure: In a dried Schlenk tube, CuCl (0.01 mmol, 2.5 mol%) and 4,4'-dibromo-2,2'-bipyridine L5 (0.015 mmol, 3.5 mol %) were dissolved in acetonitrile (2 mL) under a nitrogen atmosphere, and the mixture was stirred at rt for 30 min. Then substrate 1 (0.2 mmol, 1.0 equiv), TMSCN 2 (1 mmol, 5.0 equiv) and TBHP (0.4 mmol, 2 equiv, 70% in water) were sequentially added. The reaction mixture was stirred at 80 oC for 24 h. Upon completion of the reaction, the solvent was concentrated under vacuum. The crude residue was purified by flash column chromatography on silica gel to give the product.
  • 47
  • [ 38002-87-8 ]
  • 3-methyl-5-phenyl-3-(tosylmethyl)-2,3-dihydrobenzo[b]oxepine [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: tetrahydrofuran / 3 h / 0 - 20 °C 2: Jones reagent / diethyl ether / 1.5 h / 0 - 20 °C 3: n-butyllithium / tetrahydrofuran; hexane / 12 h / 0 °C 4: disodium hydrogenphosphate; tert.-butylhydroperoxide / nitromethane / 24 h / 100 °C / Inert atmosphere; Sealed tube
  • 48
  • [ 38002-87-8 ]
  • (2-((2-methylallyl)oxy)phenyl)(phenyl)methanone [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: tetrahydrofuran / 3 h / 0 - 20 °C 2: Jones reagent / diethyl ether / 1.5 h / 0 - 20 °C
  • 49
  • [ 38002-87-8 ]
  • 1-((2-methylallyl)oxy)-2-(1-phenylvinyl)benzene [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: tetrahydrofuran / 3 h / 0 - 20 °C 2: Jones reagent / diethyl ether / 1.5 h / 0 - 20 °C 3: n-butyllithium / tetrahydrofuran; hexane / 12 h / 0 °C
  • 50
  • [ 38002-87-8 ]
  • 3-(((4-(trifluoromethyl)benzoyl)oxy)imino)butan-2-one [ No CAS ]
  • 3-methyl-3-(2-oxopropyl)chroman-4-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
67% With 2,6-dimethylpyridine; tris(2-phenylpyridinato-N,C2′)iridium(III) In acetone at 80℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation;
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2,4-Bis(allyloxy)benzaldehyde

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Chemical Structure| 71186-58-8

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2-(Allyloxy)-4-methoxybenzaldehyde

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Ethers

Chemical Structure| 1708169-96-3

[ 1708169-96-3 ]

2,4-Dimethyl-6-((2-methylallyl)oxy)benzaldehyde

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Chemical Structure| 28752-82-1

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2-(Allyloxy)benzaldehyde

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Chemical Structure| 110124-13-5

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3-Methoxy-2-((2-methylallyl)oxy)benzaldehyde

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Chemical Structure| 96601-10-4

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2,4-Bis(allyloxy)benzaldehyde

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2-(Allyloxy)-4-methoxybenzaldehyde

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