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Chemical Structure| 3807-38-3 Chemical Structure| 3807-38-3

Structure of 3807-38-3

Chemical Structure| 3807-38-3

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Product Details of [ 3807-38-3 ]

CAS No. :3807-38-3
Formula : C8H6S3
M.W : 198.33
SMILES Code : C1(SC2=CSC=C2)=CSC=C1

Safety of [ 3807-38-3 ]

Application In Synthesis of [ 3807-38-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3807-38-3 ]

[ 3807-38-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 3807-38-3 ]
  • [ 34907-53-4 ]
  • C17H15BS3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
48% Weigh the compound 3,3 'bis-thiophene sulfide (2.238,11.221111111,1,069191 ¥)250ml eggplant bottle, N2 protection conditions, add 70ml of dry ether to fully dissolve. The mixture was stirred at -3 C30 min, slowly adding n-butyllithium (2.5 M in hexane, 23.56 mmol, 2 lOequiv) in the reaction system,At the same temperature for 1 hour. The reaction was heated to 40 C for 1 hour and then cooled to room temperature.Dimethyl borate (2.35 mg, 12.24 mmol, 1. lOequiv) was stirred overnight at room temperature and the mixture was quenched with water,Ethyl acetate was extracted three times, the organic phase was combined, dried over anhydrous magnesium sulfate, filtered, the solvent was rotated with a rotary evaporator,The mobile phase consisted of petroleum ether (PE) and the crude product was purified by silica gel column chromatography to give the product as a white solid.(1.76 g, yield = 48%).
 

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