Home Cart Sign in  
Chemical Structure| 389806-32-0 Chemical Structure| 389806-32-0

Structure of 389806-32-0

Chemical Structure| 389806-32-0

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 389806-32-0 ]

CAS No. :389806-32-0
Formula : C10H6BrI
M.W : 332.96
SMILES Code : BrC1=CC2=CC=C(I)C=C2C=C1
MDL No. :MFCD17012551
InChI Key :VYMNCOOEVDIPTL-UHFFFAOYSA-N
Pubchem ID :53485696

Safety of [ 389806-32-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H315-H318-H335-H411
Precautionary Statements:P261-P264-P271-P273-P280-P302+P352-P304+P340-P305+P351+P338-P310-P312-P321-P332+P313-P362-P391-P403+P233-P405-P501
Class:9
UN#:3077
Packing Group:

Application In Synthesis of [ 389806-32-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 389806-32-0 ]

[ 389806-32-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 7499-66-3 ]
  • [ 389806-32-0 ]
YieldReaction ConditionsOperation in experiment
51.1% To a 500 mL round bottom containing a stir bar was added borontrifluoride diethyletherate (14.5 mL, 115 mmol) and the flask was cooled to -30 °C. Compound CXI-1 (6.0 g, 27.3 mmol) dissolved in THF (75 mL) was added dropwise. 90percent tert-butylnitrite (12 mL, 100 mmol) was dissolved in THF (75 mL) and added dropwise. The reaction was allowed to warm to -5 °C at which time 100 mL of diethyl ether was added and the mixture was allowed to stir at -5 °C for 10 min until a pale solid precipitated. The solid was filtered and washed with ether to afford a pale solid which was then added in one portion to a 500 mL round bottom containing a stir bar, potassium iodide (6.4 g, 38.7 mmol), iodine (4.92 g, 19.4 mmol), and acetonitrile (100 mL). The reaction was allowed to stir at room temperature for 15 mins. 150 mL of a saturated aqueous solution of sodium thiosulfate was added as well as 150 mL of DCM. The mixture was allowed to stir for 5 mins, the layers were separated, the organics were dried using anhydrous MgS04, and the solvent was removed in vacuo. The residue was purified by column (PE) to give compounf CXI-2 (4.6 g, yield 51.1percent).
 

Historical Records

Technical Information

Categories