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Chemical Structure| 39061-59-1 Chemical Structure| 39061-59-1

Structure of 39061-59-1

Chemical Structure| 39061-59-1

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Product Details of [ 39061-59-1 ]

CAS No. :39061-59-1
Formula : C6H9ClO3
M.W : 164.59
SMILES Code : O=C(OC(C)(C)C)C(Cl)=O
MDL No. :MFCD03788742

Safety of [ 39061-59-1 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H331-H314
Precautionary Statements:P260-P264-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P403+P233-P405-P501
Class:8(6.1)
UN#:2922
Packing Group:

Application In Synthesis of [ 39061-59-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 39061-59-1 ]

[ 39061-59-1 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 39061-59-1 ]
  • [ 35661-51-9 ]
  • [ 947528-35-0 ]
YieldReaction ConditionsOperation in experiment
62% With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 20℃; for 0.25h; To a mixture of Fmoc-hydrazine (0.100 mg, 0.39 mmol), DIPEA (0.08 mL, 0.43 mmol) and methylenechloride (10 mL) was added t-Bu-oxalylchloride (0.06 mL, 0.39) slowly with stirring and ice-bath cooling under argon. The reaction mixture was stirred further at room temperature for 15 mins. The reaction mixture was then washed with 1N HCL (5 mL), followed by 10percent NaHCO3 (5 mL) and brine (5 mL), dried (Na2SO4) and concentrated to give 140 mg of crude compound which was purified by column chromatography to give 94 mg (62percent) of pure product as white solid; mp. 79-80°C. Rf = 0.45 (2:1 Pentane/EtOAc) 1H NMR (200 MHz, CDCl3) delta (ppm) 8.94 (br s, 1H), 7.75 (d, J = 7.42 Hz, 2H), 7.58 (d, J = 7.24 Hz, 2H), 7.26-7.43 (m, 5H), 4.44 (d, J = 7.22 Hz, 2H), 4.23 (t, J = 7.14 Hz, 1H), 1.57 (m, 12H). 13C NMR (200 MHz, CDCl3) delta(ppm) 157.78, 156.38, 155.51, 143.33, 141.25, 127.84, 127.16, 125.1, 120.01, 85.69, 68.3, 46.79, 27.70.
  • 2
  • [ 78-69-3 ]
  • [ 39061-59-1 ]
  • tert-butyl (3,7-dimethyloctan-3-yl) oxalate [ No CAS ]
 

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