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Chemical Structure| 403-46-3 Chemical Structure| 403-46-3

Structure of 403-46-3

Chemical Structure| 403-46-3

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Product Details of [ 403-46-3 ]

CAS No. :403-46-3
Formula : C8H10FN
M.W : 139.17
SMILES Code : CN(C)C1=CC=C(F)C=C1
MDL No. :MFCD00059471

Safety of [ 403-46-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 403-46-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 403-46-3 ]

[ 403-46-3 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 121-69-7 ]
  • [ 366-29-0 ]
  • [ 403-46-3 ]
  • [ 393-56-6 ]
  • [ 556-21-8 ]
  • [ 101-61-1 ]
  • [ 100-10-7 ]
YieldReaction ConditionsOperation in experiment
With N-fluorobis(benzenesulfon)imide; In chloroform; at 25℃; for 10.0h; General procedure: To a solution of amine (0.1mmol) in 3mL of CHCl3 the corresponding amount of NFSI in 2mL of the same solvent was added. The reaction mass was stirred at selected temperature during the time indicated in Table 1. The resulting solution was washed with water (2×15mL), dried over Na2SO4 and evaporated to dryness. The residue was analyzed either by GC/MS or separated by column chromatography.
  • 2
  • [ 121-69-7 ]
  • [ 366-29-0 ]
  • [ 403-46-3 ]
  • [ 393-56-6 ]
  • [ 698-01-1 ]
  • [ 556-21-8 ]
  • [ 101-61-1 ]
  • [ 100-10-7 ]
  • [ 98-09-9 ]
YieldReaction ConditionsOperation in experiment
6% With zirconium(IV) chloride; N-fluorobis(benzenesulfon)imide; In chloroform; for 5.0h;Reflux; General procedure: To a solution of amine (0.1mmol) in 3mL of CHCl3 the corresponding amount of NFSI in 2mL of the same solvent was added. The reaction mass was stirred at selected temperature during the time indicated in Table 1. The resulting solution was washed with water (2×15mL), dried over Na2SO4 and evaporated to dryness. The residue was analyzed either by GC/MS or separated by column chromatography.
 

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