Name: 42858-60-6|3,5-Dioxocyclohexanecarboxylic acid|97%
Brand: Ambeed
SKU: A516296
Price: 12.0 USD
Availability: InStock
Rating: 90 (27 reviews)

1
[ 67-56-1 ]
[ 42858-60-6 ]
[ 95298-68-3 ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359
[2]Journal of the American Chemical Society,1959,vol. 81,p. 4278,4283
Organic Syntheses,1973,vol. Coll. Vol. V,p. 400
[3]Patent: US2020/190066,2020,A1 .Location in patent: Paragraph 0339-0340

2
[ 64-17-5 ]
[ 42858-60-6 ]
[ 63723-94-4 ]

Reference： [1]Journal of the American Chemical Society,1956,vol. 78,p. 4405,4410
[2]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5

3
[ 99-10-5 ]
[ 42858-60-6 ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359
[2]Chemische Berichte,1955,vol. 88,p. 316,327

4
[ 24941-58-0 ]
[ 42858-60-6 ]

Reference： [1]Australian Journal of Chemistry,1954,vol. 7,p. 256,259

5
[ 42858-60-6 ]
[ 142-04-1 ]
3-anilino-5-oxo-cyclohex-3-enecarboxylic acid [ No CAS ]

Reference： [1]Chemische Berichte,1955,vol. 88,p. 316,327

6
[ 42858-60-6 ]
[ 100-34-5 ]
3,5-dihydroxy-4-(<i>N</i>'-phenyl-hydrazino)-benzoic acid [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1959,vol. 81,p. 4278,4283
Organic Syntheses,1973,vol. Coll. Vol. V,p. 400

7
[ 42858-60-6 ]
[ 106-95-6 ]
[ 52935-95-2 ]

Reference： [1]Chemische Berichte,1957,vol. 90,p. 2928,2930

8
[ 42858-60-6 ]
[ 74-88-4 ]
[ 61040-89-9 ]

Reference： [1]Chemische Berichte,1957,vol. 90,p. 2928,2930

9
[ 42858-60-6 ]
[ 111-46-6 ]
[ 618-57-5 ]

Reference： [1]Chemische Berichte,1957,vol. 90,p. 2928,2930

10
[ 67-56-1 ]
[ 3866-79-3 ]
[ 42858-60-6 ]
[ 75836-86-1 ]

Reference： [1]Heterocycles,1980,vol. 14,p. 1301 - 1303

11
[ 67-56-1 ]
[ 42858-60-6 ]
[ 60891-25-0 ]

Reference： [1]Australian Journal of Chemistry,1994,vol. 47,p. 1727 - 1734

12
[ 78-83-1 ]
[ 42858-60-6 ]
[ 60891-20-5 ]

Reference： [1]Australian Journal of Chemistry,1994,vol. 47,p. 1727 - 1734

15
[ 42858-60-6 ]
[ 85925-67-3 ]
3-(4-carboxy-2-hydroxy-6-oxo-1-cyclohexen-1-yl)-5,7-dimethoxy-3H-isobenzofuran-1-one [ No CAS ]

Reference： [1]Tetrahedron,2007,vol. 63,p. 11781 - 11792

16
[ 16859-59-9 ]
[ 42858-60-6 ]
3-(4-carboxy-2-hydroxy-6-oxo-1-cyclohexen-1-yl)-3H-isobenzofuran-1-one [ No CAS ]

Reference： [1]Tetrahedron,2007,vol. 63,p. 11781 - 11792

17
[ 42858-60-6 ]
2-methylpropyl 5-(2-methylpropoxy)-7-oxo-1,2,3,4,7,7a-hexahydro-3aH-indene-3a-carboxylate [ No CAS ]

Reference： [1]Australian Journal of Chemistry,1994,vol. 47,p. 1727 - 1734

18
[ 42858-60-6 ]
[ 159015-69-7 ]

Reference： [1]Australian Journal of Chemistry,1994,vol. 47,p. 1727 - 1734

19
[ 42858-60-6 ]
cis-2-methylpropyl 6-methyl-3-(2-methylpropoxy)-5-oxocyclohex-3-ene-1-carboxylate [ No CAS ]

Reference： [1]Australian Journal of Chemistry,1994,vol. 47,p. 1727 - 1734

20
[ 42858-60-6 ]
trans-2-methylpropyl 6-methyl-3-(2-methylpropoxy)-5-oxocyclohex-3-ene-1-carboxylate [ No CAS ]

Reference： [1]Australian Journal of Chemistry,1994,vol. 47,p. 1727 - 1734

21
[ 42858-60-6 ]
[ 75836-87-2 ]

Reference： [1]Heterocycles,1980,vol. 14,p. 1301 - 1303

22
[ 42858-60-6 ]
[ 75836-89-4 ]

Reference： [1]Heterocycles,1980,vol. 14,p. 1301 - 1303

23
[ 42858-60-6 ]
[ 75836-89-4 ]

Reference： [1]Heterocycles,1980,vol. 14,p. 1301 - 1303

24
[ 42858-60-6 ]
[ 539-80-0 ]

Reference： [1]Journal of the American Chemical Society,1956,vol. 78,p. 4405,4410

25
[ 42858-60-6 ]
[ 1901-34-4 ]

Reference： [1]Journal of the American Chemical Society,1956,vol. 78,p. 4405,4410

26
[ 42858-60-6 ]
[ 84011-70-1 ]

Reference： [1]Journal of the American Chemical Society,1956,vol. 78,p. 4405,4410
[2]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

27
[ 42858-60-6 ]
[ 103262-78-8 ]

Reference： [1]Journal of the American Chemical Society,1956,vol. 78,p. 4405,4410

28
[ 42858-60-6 ]
[ 106379-29-7 ]

Reference： [1]Journal of the American Chemical Society,1956,vol. 78,p. 4405,4410

29
[ 42858-60-6 ]
[ 1457-39-2 ]

Reference： [1]Chemische Berichte,1957,vol. 90,p. 2928,2930

30
[ 42858-60-6 ]
[ 102540-74-9 ]

Reference： [1]Chemische Berichte,1957,vol. 90,p. 2928,2930

31
dimethyl 3-(N,N-dimethylcarbamoyl)-5-oxocyclohex-⁽³⁾-enecarboxamide [ No CAS ]
[ 42858-60-6 ]
[ 79-44-7 ]
[ 95266-80-1 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrogenchloride; In tetrahydrofuran; ethyl acetate;	(a) With stirring, 18.4 ml of dimethylcarbamoyl chloride are added dropwise to a solution of 15.6 g of 3,5-cyclohexanedioncarboxylic acid and the mixture is then stirred for a further 12 hours at room temperature and for 2 hours at boiling temperature under reflux. The cooled reaction mixture is then taken up in 400 ml of ethyl acetate and the organic phase is washed with 4 times with brine, dried over magnesium sulfate and concentrated. The residue consists of 13.2 g of crude dimethyl 3-(N,N-dimethylcarbamoyl)-5-oxocyclohex-(3)-enecarboxamide. The crude residue is dissolved in 300 ml of tetrahydrofuran, 8 ml of concentrated hydrochloric acid are added and the solution is stirred for 2 hours at room temperature. The reaction mixture is then washed with brine, dried over magnesium sulfate and concentrated, affording 13.2 g of dimethyl 3,5-cyclohexandionecarboxamide as a resinous substance. Purification by chromatography with hexane/ether over a column of silica gel yields crystals with a melting point of 152-155 C. (compound 3.02).

Reference： [1]Patent: US4618360,1986,A

32
[ 42858-60-6 ]
[ 95266-78-7 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrogenchloride; sodium chloride; phosphoric acid; In tetrahydrofuran; 2-methyl-propan-1-ol; water; toluene;	(a) Isobutyl 3,5-cyclohexanedione-1-carboxylate A mixture of 50 g of <strong>[42858-60-6]3,5-cyclohexanedione-1-carboxylic acid</strong>, 150 ml of isobutanol, 30 g of 85% orthophosphoric acid and 400 ml of toluene is boiled overnight in a water separator. The solution is then concentrated in a rotovap. The residue is taken up in 200 ml of tetrahydrofuran, and the solution is boiled for 2 hours after addition of 100 ml of 1N hydrochloric acid. The cooled solution is extracted with ethyl acetate and the organic phase is separated, washed with a saturated solution of sodium chloride, dried and concentrated. The wax-like residue is recrystallized from ether/hexane and the crystalline product melts at 74-76 C.
	With hydrogenchloride; sodium chloride; phosphoric acid; In tetrahydrofuran; 2-methyl-propan-1-ol; water; toluene;	(a) Isobutyl 3,5-cyclohexanedionecarboxylate A mixture of 50 g of <strong>[42858-60-6]3,5-cyclohexanedione-1-carboxylic acid</strong>, 150 ml of isobutanol, 30 g of 85% orthophosphoric acid and 400 ml of toluene is boiled overnight in a water separator. The solution is then concentrated in a rotovap. The residue is taken up in 200 ml of tetrahydrofuran, and the solution is boiled for 2 hours after addition of 100 ml of 1N hydrochloric acid. The cooled solution is extracted with ethyl acetate and the organic phase is separated, washed with a saturated solution of sodium chloride, dried and concentrated. The wax-like residue is recrystallized from ether/hexane and the crystalline product melts at 74-76 C.

Reference： [1]Patent: US4623382,1986,A
[2]Patent: US4693745,1987,A

33
[ 7664-93-9 ]
[ 42858-60-6 ]
[ 95298-68-3 ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; diethyl ether;	H.O.3. 3-methoxy-cyclohex-3-en-5-one-carboxylic acid 10 ml of concentrated sulphuric acid are added to a solution of 1560 g (10 moles) of <strong>[42858-60-6]cyclohexane-3,5-dione-carboxylic acid</strong> in 3 liters of methanol and the whole is left at from 20 to 25 C. for 3 hours while stirring. 3 liters of diethyl ether are then added and the precipitated product is filtered off with suction. 1508 g (88.7%) of the title compound of formula STR32 are isolated.

Reference： [1]Patent: US4872902,1989,A

34
[ 42858-60-6 ]
[ 1112977-84-0 ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359
[2]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359

35
[ 42858-60-6 ]
[ 1122710-49-9 ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359

36
[ 42858-60-6 ]
C₂₈H₄₆N₄O₈S [ No CAS ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359

37
[ 42858-60-6 ]
C₂₇H₄₄N₄O₈S [ No CAS ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359

38
[ 42858-60-6 ]
[ 1112977-83-9 ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 356 - 359

39
[ 42858-60-6 ]
[ 1625672-24-3 ]

Reference： [1]Patent: US2014/249129,2014,A1

40
[ 42858-60-6 ]
[ 1625669-47-7 ]

Reference： [1]Patent: US2014/249129,2014,A1

41
[ 42858-60-6 ]
[ 1625669-48-8 ]

Reference： [1]Patent: US2014/249129,2014,A1
[2]Patent: WO2014/135414,2014,A1

42
[ 42858-60-6 ]
[ 1625669-49-9 ]

Reference： [1]Patent: US2014/249129,2014,A1
[2]Patent: WO2014/135414,2014,A1

43
[ 42858-60-6 ]
[ 98-16-8 ]
[ 1625672-23-2 ]

Yield	Reaction Conditions	Operation in experiment
1.3 g	With ytterbium(III) triflate; In N,N-dimethyl-formamide; at 20.0℃;	5-Oxo-3-(3-(trifluoromethyl)phenylamino)cyclohex-3-enecarboxylic acid A mixture of <strong>[42858-60-6]3,5-dioxocyclohexanecarboxylic acid</strong> (1.00 g, 6.41 mmol), 3-(trifluoromethyl)aniline (880 muL, 1.14 g, 4.05 mmol), Ytterbium(III) trifluormethanesulfonate (20 mg, 32 mumol, 0.5 mol %) and N,N-dimethylformamide (3 mL) is stirred at room temperature over night. Water and aqueous sodium hydroxide are added and the mixture is washed with diethyl ether. The organic layer is discarded, and the aqueous layer is acidified with aqueous hydrogen chloride and extracted with diethyl ether. The organic layer is dried over Na2SO4 and concentrated under reduced pressure. Yield: 1.30 g; ESI mass spectrum [M+H]+=300, Retention time HPLC: 1.08 min (V001-006).
1.3 g	With ytterbium(III) triflate; In N,N-dimethyl-formamide; at 20.0℃;	A mixture of <strong>[42858-60-6]3,5-dioxocyclohexanecarboxylic acid</strong> (1.00 g, 6.41 mmol), 3-(trifluoro- methyl) aniline (880 mu, 1.14 g, 4.05 mmol), Ytterbium(III) trifluormethanesulfonate (20 mg, 32 muiotaetaomicron, 0.5 mol%) and N,N-dimethylformamide (3 mL) is stirred at room temperature over night. Water and aqueous sodium hydroxide are added and the mixture is washed with diethyl ether. The organic layer is discarded, and the aqueous layer is acidified with aqueous hydrogen chloride and extracted with diethyl ether. The organic layer is dried over Na2S04 and concentrated under reduced pressure. Yield: 1.30 g; ESI mass spectrum [M+H]+ = 300, Retention time HPLC: 1.08 min (V001 006).

Reference： [1]Patent: US2014/249129,2014,A1 .Location in patent: Paragraph 0395-0396
[2]Patent: WO2014/135414,2014,A1 .Location in patent: Page/Page column 83

44
[ 42858-60-6 ]
[ 130256-40-5 ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

45
[ 42858-60-6 ]
C₂₉H₄₄INO₅ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

46
[ 42858-60-6 ]
C₂₉H₄₂INO₅ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5

47
[ 42858-60-6 ]
C₂₉H₄₁NO₅ [ No CAS ]
C₂₉H₄₁NO₅ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

48
[ 42858-60-6 ]
C₂₈H₃₉NO₄ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

49
[ 42858-60-6 ]
C₂₈H₃₉NO₅ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

50
[ 42858-60-6 ]
C₁₆H₂₃NO₂ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[14]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[15]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[16]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[17]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[18]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[19]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[20]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[21]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[22]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[23]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[24]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[25]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[26]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

51
[ 42858-60-6 ]
C₁₆H₂₂BrNO₂ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5

52
[ 42858-60-6 ]
C₂₃H₂₉NO₂ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5

53
[ 42858-60-6 ]
13-epi-13β,16-epoxydihydrofawcettimine [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
    Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
    Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[3]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
    Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[14]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[15]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[16]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[17]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[18]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[19]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[20]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[21]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[22]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[23]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[24]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[25]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[26]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[27]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[28]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[29]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[30]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[31]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[32]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[33]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[34]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[35]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[36]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[37]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[38]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[39]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

54
[ 42858-60-6 ]
C₂₁H₃₃NO₅ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

55
[ 42858-60-6 ]
C₁₆H₂₃NO₂ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5

56
[ 42858-60-6 ]
5-epi-huperzine Q [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5

57
[ 42858-60-6 ]
C₁₅H₁₉NO₂ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[14]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[15]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[16]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[17]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[18]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[19]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[20]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[21]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[22]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[23]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[24]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[25]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[26]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

58
[ 42858-60-6 ]
C₂₂H₃₃NO₆ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

59
[ 42858-60-6 ]
C₁₇H₂₃NO₃ [ No CAS ]
lycogladine H [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

60
[ 42858-60-6 ]
C₂₁H₃₁NO₅ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

61
[ 42858-60-6 ]
[ 155751-23-8 ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 1011 - 1015
Angew. Chem.,2014,vol. 127,p. 1025 - 1029,5
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

62
[ 42858-60-6 ]
C₁₇H₂₄N₂O₆S [ No CAS ]
C₂₄H₃₀N₂O₉S [ No CAS ]

Reference： [1]Chemical Science,2016,vol. 7,p. 400 - 415

63
[ 42858-60-6 ]
[ 190657-27-3 ]
C₂₀H₂₈N₂O₄ [ No CAS ]

Reference： [1]Patent: US2016/22642,2016,A1 .Location in patent: Sheet 6

64
[ 42858-60-6 ]
C₁₆H₂₆O₄ [ No CAS ]
C₂₃H₃₂O₇ [ No CAS ]

Reference： [1]Patent: US2016/22642,2016,A1 .Location in patent: Sheet 6

65
[ 42858-60-6 ]
C₁₆H₂₇NO₃ [ No CAS ]
C₂₃H₃₃NO₆ [ No CAS ]

Reference： [1]Patent: US2016/22642,2016,A1 .Location in patent: Sheet 7

66
[ 42858-60-6 ]
C₁₄H₂₅NO₂ [ No CAS ]
C₂₁H₃₁NO₅ [ No CAS ]

Reference： [1]Patent: US2016/22642,2016,A1 .Location in patent: Sheet 8

67
[ 42858-60-6 ]
C₂₆H₃₉NO₈ [ No CAS ]
C₂₈H₃₇NO₉ [ No CAS ]

Reference： [1]Patent: US2016/22642,2016,A1 .Location in patent: Sheet 11

68
2-(2-aminoethoxy)ethyl 2-(adamantan-1-yl)acetate [ No CAS ]
[ 42858-60-6 ]
C₂₃H₃₃NO₆ [ No CAS ]

Reference： [1]Patent: US2016/22642,2016,A1 .Location in patent: Sheet 7

69
[ 23702-88-7 ]
[ 42858-60-6 ]
C₁₃H₂₁NO₅ [ No CAS ]

Reference： [1]Patent: US2016/22642,2016,A1 .Location in patent: Sheet 9

70
[ 42858-60-6 ]
disodium 4-amino-5-sulfonaphthalene-2,7-disulfonate [ No CAS ]
C₁₇H₁₃NO₁₂S₃^(2-)*2Na⁽¹⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		Weigh 156mg<strong>[42858-60-6]3,5-dicarbonylcyclohexanecarboxylic acid</strong> (156.14, 1 eq)And 178 mgN, N'-carbonyldiimidazole CDI (162.14, 1.1 eq),50 C for 5 minutes in a mortar,TLC thin layer chromatography to monitor the complete reaction of cyanoacetic acid,Again into the mortar called 384mgAmino-1,3,6-naphthalenesulfonic acid disodium salt hydrate (427.3, 0.9 eq),10.4 mg imidazole hydrochloride (104, 0.1 eq) and 100 muL water, milled for 10 minutes and monitored by TLC TLCDisodium 8-amino-1,3,6-naphthalenesulfonate completely reacted.Water (10 mL) and ethyl acetate (3 x 15 mL) were added and the mixture was separated and the aqueous layer was lyophilized at -60 C to give product I-4 as a yellow solid

Reference： [1]Patent: CN107235866,2017,A .Location in patent: Paragraph 0060; 0061; 0062

71
[ 42858-60-6 ]
C₂₉H₄₂INO₅ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

72
[ 42858-60-6 ]
C₂₉H₄₅NO₆ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

73
[ 42858-60-6 ]
C₂₉H₄₄ClNO₈S [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

74
[ 42858-60-6 ]
C₂₉H₄₂ClNO₈S [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

75
[ 42858-60-6 ]
C₂₉H₄₁NO₅ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

76
[ 42858-60-6 ]
C₂₉H₄₃NO₅ [ No CAS ]
C₂₉H₄₃NO₅ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

77
[ 42858-60-6 ]
C₂₈H₄₁NO₆ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

78
[ 42858-60-6 ]
C₂₈H₄₃NO₆ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

79
[ 42858-60-6 ]
C₂₈H₄₃NO₆ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

80
[ 42858-60-6 ]
C₂₈H₃₉NO₆ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

81
[ 42858-60-6 ]
C₁₆H₂₃NO₂ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

82
[ 42858-60-6 ]
5-epi-huperzine Q [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

83
[ 42858-60-6 ]
C₁₆H₂₂BrNO₂ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[13]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[14]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[15]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[16]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[17]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[18]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[19]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[20]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[21]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[22]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[23]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[24]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

84
[ 42858-60-6 ]
C₂₁H₂₉NO₅ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

85
[ 42858-60-6 ]
C₁₆H₂₁NO₃ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

86
[ 42858-60-6 ]
(-)-4-epi-lycopladine D [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

87
[ 42858-60-6 ]
C₂₁H₃₁NO₅ [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[2]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[3]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[4]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[5]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[6]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[7]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[8]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[9]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[10]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[11]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567
[12]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

88
[ 42858-60-6 ]
C₄₅H₆₃NO₆Si [ No CAS ]

Reference： [1]Chemistry - An Asian Journal,2017,vol. 12,p. 1557 - 1567

Purity	Size	Price	VIP Price	USA Stock *0-1 Day	Global Stock *5-7 Days	Quantity
{[ item.p_purity ]}	{[ item.pr_size ]}	{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]}	{[ getRatePrice(item.pr_usd, 1,1) ]}	Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]}	{[ item.pr_usastock ]}	Inquiry -	{[ item.pr_chinastock ]}	Inquiry -

CAS No. :	42858-60-6	MDL No. :	MFCD09836162
Formula :	C₇H₈O₄	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	MCGPFJGIBKPQGO-UHFFFAOYSA-N
M.W :	156.14	Pubchem ID :	14371458
Synonyms :

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 42858-60-6 ] {[proInfo.proName]}

Quality Control of [ 42858-60-6 ]

Related Doc. of [ 42858-60-6 ]

Product Details of [ 42858-60-6 ]

Safety of [ 42858-60-6 ]

Application In Synthesis of [ 42858-60-6 ]

[ 42858-60-6 ] Synthesis Path-Downstream 1~88

Related Functional Groups of
[ 42858-60-6 ]

Aliphatic Cyclic Hydrocarbons

Ketones

Carboxylic Acids

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

[ CAS No. 42858-60-6 ] {[proInfo.proName]}

Quality Control of [ 42858-60-6 ]

Related Doc. of [ 42858-60-6 ]

Product Details of [ 42858-60-6 ]

Safety of [ 42858-60-6 ]

Application In Synthesis of [ 42858-60-6 ]

[ 42858-60-6 ] Synthesis Path-Downstream 1~88

Related Functional Groups of [ 42858-60-6 ]

Aliphatic Cyclic Hydrocarbons

Ketones

Carboxylic Acids

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 42858-60-6 ]