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Chemical Structure| 45096-22-8 Chemical Structure| 45096-22-8

Structure of 45096-22-8

Chemical Structure| 45096-22-8

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Product Details of [ 45096-22-8 ]

CAS No. :45096-22-8
Formula : C9H20O4
M.W : 192.25
SMILES Code : CC(OCC(OCC(O)C)C)CO
English Name :2-(2-(2-Hydroxypropoxy)propoxy)propan-1-ol
MDL No. :MFCD00014405

Safety of [ 45096-22-8 ]

Application In Synthesis of [ 45096-22-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 45096-22-8 ]

[ 45096-22-8 ] Synthesis Path-Downstream   1~2

YieldReaction ConditionsOperation in experiment
Stage #1: 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate; tripropylene glycol at 100℃; for 1h; Stage #2: at 80 - 150℃; for 12h; 7 EXAMPLE 7 A sample of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate of epoxide content 7.3 mol/kg (85.2 g) and tripropylene glycol (14.89) are heated at 100° C. under vacuum for 1 hour. The mixture is allowed to cool to 80° C. and then Amberlyst (TM) 15 ion exchange resin (30 g) added. This mixture is heated under vacuum at 150° C. for 12 hours by which time the epoxy value has fallen to 4.7 mol/kg. The reaction mixture is allowed to cool and the catalyst removed by filtration.
  • 2
  • [ 29911-28-2 ]
  • [ 45096-22-8 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With phosphorous (V) sulfide In n-heptane at 95 - 118℃; for 8.5h; 12 Example 12 Dithiophosphoric Acid Mixture, Lot RJT-569-56; A three neck round bottom flask was charged with 121.5 grams of phosphorous pentasulfide and 135.4 grams of heptane. This was attached to a scrubber to remove hydrogen sulfide gas. The flask was then flushed with nitrogen gas. To a second round bottom flask was added 226.5 grams of dipropylene glycol monobutyl ether and 95.3 grams of tripropylene glycol. The alcohol mixture was then added to the phosphorous pentasulfide over a period of two hours. The reaction mixture was then heated to 95° C. over a period of three and one half hours. The reaction was heated further, and heptane was removed by distillation. After the temperature reached 118° C., the reaction was heated for an additional three hours. An aspirator was attached to remove any remaining heptane. The final product was then filtered with diatomaceous earth.
 

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