Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 464174-87-6 Chemical Structure| 464174-87-6

Structure of 464174-87-6

Chemical Structure| 464174-87-6

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 464174-87-6 ]

CAS No. :464174-87-6
Formula : C18H18BF4N3O
M.W : 379.16
SMILES Code : F[B-](F)(F)F.[N+]12=CN(C3=CC=CC=C3)N=C1COC[C@@H]2CC4=CC=CC=C4
MDL No. :MFCD28167845
InChI Key :ABHXPJSMRQQAIG-LMOVPXPDSA-N
Pubchem ID :53469168

Safety of [ 464174-87-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P280-P305+P351+P338-P310
Class:8
UN#:1759
Packing Group:

Application In Synthesis of [ 464174-87-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 464174-87-6 ]

[ 464174-87-6 ] Synthesis Path-Downstream   1~5

  • 4
  • [ 101250-48-0 ]
  • [ 122-51-0 ]
  • [ 100-63-0 ]
  • [ 464174-87-6 ]
YieldReaction ConditionsOperation in experiment
29% To a solution of lactam (400 mg, 2.09 mmol) in CH2Cl2 (12 mL) was added trimethyloxonium tetrafluoroborate (337 mg, 2.28 mmol) and the mixture was stirred for 16 h. To the mixture was then added phenylhydrazine (0.206 mL, 2.09 mmol) and the mixture was stirred for 20 h. The mixture was then concentrated in vacuo and redissolved in MeOH (1.5 mL) and triethyl orthoformate (4.5 mL). The mixture was heated at reflux (110 C) for 16 h then cooled to ambient temperature, whereby the product had precipitated.† The product was collected by filtration and washed with cold (-78 C) EtOAc (5 mL) to afford the title product 47 as a pale peach solid (230 mg, 29%); mp 190-195 C; inlMMLBox (c 0.8, MeOH); δH (400 MHz, DMSO-d6) 10.91 (1H, s, NCHN), 7.90-7.88 (2H, m, PhH), 7.76-7.71 (2H, m, PhH), 7.71-7.65 (1H, m, PhH-4), 7.43-7.40 (2H, m, NPhH-2), 7.36-7.32 (3H, m, NPhH), 5.23 (1H, ABd, J 16.2, OCHAHB), 5.15 (1H, ABd, J 16.2, OCHAHB), 4.85 (1H, app dq, J 9.7, 5.9, BnCH), 4.01-3.93 (2H, m, OCH2CHBn), 3.50 (1H, ABX, JAB 13.6, JAX 5.9, PhCHAHB) and 3.18 (1H, ABX, JBA 13.6, JBX 9.7, PhCHAHB); δC (100 MHz, DMSO-d6) 149.9 (NCHN), 135.1 (NC), 134.9 (NArC-1), 134.9 (CH2PhC-1), 130.8 (ArCH-4), 130.4 (ArCH), 129.5 (ArCH), 129.0 (ArCH), 127.5 (ArCH), 120.7 (ArCH), 65.1 (OCH2), 61.5 (OCH2), 56.3 (NCH) and 37.5 (Ph-CH2); m/z MS (ESI+) 292 (100, [M-BF4]+); HRMS (ESI+) inlMMLBox ([M-BF4]+) requires 292.1444, found 292.1443 (-0.4 ppm); IR νmax (KBr)/cm-1 3337, 3141, 3060 (Ar C-H), 3026, 2987, 2969, 1585 (CN), 1536, 1497 (Ar CC), 1469, 1118 (C-O) and 1054 (br).
  • 5
  • [ 12112-67-3 ]
  • [ 464174-87-6 ]
  • C26H29ClIrN3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
53% With triethylamine; In toluene; at 25.0℃; for 34h;Inert atmosphere; General procedure: Argon under the protection,In a dry 250 ml three-necked bottle,[Ir (cod) Xld] 2 (336 mg, 0.5 mmol) was added,Such as compounds represented by formula and bases,Organic solvents,Stirring reaction,The crude product was isolated by column chromatography (ethyl acetate / petroleum ether: 1: 5).The specific reaction conditions for the compounds Va-Vc and the compound Vf are shown in Table 5.The compound Vd-Ve,Preparation Methods and Conditions for Compound Vg Referring to Example 5 and Table 5,among them,The molar ratio in Table 5 refers to the molar ratio of [Ir (cod) Xld] 2: compound : base.
 

Historical Records

Categories