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Chemical Structure| 4920-84-7 Chemical Structure| 4920-84-7

Structure of 4920-84-7

Chemical Structure| 4920-84-7

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Product Details of [ 4920-84-7 ]

CAS No. :4920-84-7
Formula : C8H9NO4
M.W : 183.16
SMILES Code : COC1=CC(OC)=C(C=C1)[N+]([O-])=O
MDL No. :MFCD00024210
InChI Key :XXWIYOBCHKCWNT-UHFFFAOYSA-N
Pubchem ID :78633

Safety of [ 4920-84-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H332-H335
Precautionary Statements:P261-P280-P305+P351+P338

Application In Synthesis of [ 4920-84-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 4920-84-7 ]

[ 4920-84-7 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 151-10-0 ]
  • [ 16147-07-2 ]
  • [ 4920-84-7 ]
  • [ 6665-97-0 ]
  • 2
  • [ 151-10-0 ]
  • [ 4920-84-7 ]
  • [ 6665-97-0 ]
YieldReaction ConditionsOperation in experiment
With bismuth (III) nitrate pentahydrate; for 1.5h;Schlenk technique; Ionic liquid; Inert atmosphere; Heating; General procedure: The ionic liquid (3.5-4.0 mL) was charged into an oven-dried Schlenk tube under a nitrogen atmosphere and Bi(NO3)3·5H2O (1.5 mmol) was added. The respective aromatic compound (1 mmol) was then introduced into the Schlenk tube under a nitrogen atmosphere. The reaction mixture was magnetically stirred, initially at rt for about 10 min followed by stirring in a pre-heated oil bath at 80-85 C, until completion (as monitored by GC-MS). Once the reaction was over, the contents were cooled to rt and extracted with EtOAc-Hexane (2:3 vol/vol), until the final extraction did not show a spot corresponding to the starting material or to the product. The combined organic extracts were washed with 10% NaHCO3 solution, dried with MgSO4, and concentrated to give the crude product. Isomer distributions were determined by GC-MS, and/or by 1H NMR.
 

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