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Chemical Structure| 502693-09-6 Chemical Structure| 502693-09-6

Structure of 502693-09-6

Chemical Structure| 502693-09-6

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Product Details of [ 502693-09-6 ]

CAS No. :502693-09-6
Formula : C42H51N6O4RuS2
M.W : 869.09
SMILES Code : S=C=[N-][Ru+2]12([N]3=CC=C(C([O-])=O)C=C3C4=CC(C([O-])=O)=CC=[N]14)([N]5=CC=C(CCCCCCCCC)C=C5C6=CC(CCCCCCCCC)=CC=[N]26)[N-]=C=S.[H+]
MDL No. :MFCD12546029

Safety of [ 502693-09-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301-H319-H351
Precautionary Statements:P280-P305+P351+P338
Class:6.1
UN#:2811
Packing Group:

Application In Synthesis of [ 502693-09-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 502693-09-6 ]

[ 502693-09-6 ] Synthesis Path-Downstream   1~5

  • 1
  • ruthenium(III) chloride trihydrate [ No CAS ]
  • [ 6813-38-3 ]
  • ammonium thiocyanate [ No CAS ]
  • [ 142646-58-0 ]
  • [ 502693-09-6 ]
YieldReaction ConditionsOperation in experiment
61% 0.851 g of ruthenium (III) chloride hydrate and 40 ml ofN-methylpyrrolidone were added to the first reactor and (4,4'-dinonyl-2,2'bipyridine)was added thereto while stirring and the mixture was stirred for 0.5 hour. In the second reactor, ligand 2(2,2'-bipyridine-4,4'-dicarboxylicacid) and 60 ml of N-methylpyrrolidone were placed and maintained at 140 to 150 C. The mixed solution of the first reactor was added to the secondreactor, stirring was continued for 1.5 hours while maintaining the temperatureat 140 to 150 C, and ammonium thiocyanate 5.16 g was added and stirred for 1hour and then the reactor was cooled. The reaction mixture was poured into distilled water toprecipitate a solid. The solid was dissolved in 40 ml of methanol and NaOH wereused to maintain the pH of 10 to 11. After purification by column usingSephadex resin, the solution was adjusted to pH 4.8 with nitric acid to give togive the desired compound as a solid.
  • 2
  • [ 52462-29-0 ]
  • [ 6813-38-3 ]
  • ammonium thiocyanate [ No CAS ]
  • [ 142646-58-0 ]
  • [ 502693-09-6 ]
YieldReaction ConditionsOperation in experiment
28% General procedure: 0.851 g of ruthenium (III) chloride hydrate and 40 ml of N-methylpyrrolidone were added to the first reactor(4,4'-dinonyl-2,2'bipyridine) was added thereto while stirring and the mixture was stirred for 0.5 hour. In the second reactor, ligand 2(2,2'-bipyridine-4,4'-dicarboxylic acid) and 60 ml of N-methylpyrrolidone were placed and maintained at 140 to 150 C. The mixed solution of the first reactor was added to the second reactor,Stirring was continued for 1.5 hours while maintaining the temperature at 140 to 150 C, and ammonium thiocyanate5.16 g was added and stirred for 1 hour and then the reactor was cooled. The reaction mixture was poured into distilled water to precipitate a solid. The solid was dissolved in methanol40 ml and NaOH were used to maintain the pH of 10 to 11, After purification by column using Sephadex resin,the solution was adjusted to pH 4.8 with nitric acid to give a solid to give the desired compound. Instead of ruthenium (III) chloride hydrate, [RuCl2 (p-cymene)] 2 Except that the complex compound was used, a heteroleptic ruthenium complex dye was synthesized in the same manner.
  • 3
  • [ 502693-09-6 ]
  • [ 505-86-2 ]
  • C42H52N6O4RuS2*C19H42N(1+)*HO(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
100% 30 mL of ethanol and 50 mg of <strong>[502693-09-6]Z907</strong> were stirred for 0.5 hour. 0.5 mL of trimethylhexadecylammonium hydroxide was added and the pH was 13 and continued stirring for 0.5 hour until complete dissolution.0.1 M HNO was added with stirring3Adjust the pH to 4.3.After precipitation of a large amount of precipitate, filtration and drying were carried out to obtain 50 mg of a black solid in a yield of 100%.
  • 4
  • [ 502693-09-6 ]
  • [ 26214-05-1 ]
  • C42H52N6O4RuS2*C11H26N(1+)*HO(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
100% 30 mL of ethanol and 50 mg of <strong>[502693-09-6]Z907</strong> were stirred for 0.5 hour, 0.5 mL of trimethyloctyl ammonium hydroxide was added and the pH was 13 and continued stirring for 0.5 hour until complete dissolution.0.1 M HNO was added with stirring3Adjust the pH to 4.3.A large amount of precipitate was precipitated, filtered, and dried to obtain 50 mg of a black solid in 100% yield.
  • 5
  • [ 502693-09-6 ]
  • [ 14898-63-6 ]
  • C42H52N6O4RuS2*C15H34N(1+)*HO(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
100% 30 mL of ethanol and 50 mg of <strong>[502693-09-6]Z907</strong> were stirred for 0.5 hour, 0.5 mL of trimethyldodecylammonium hydroxide was added and the pH was 13 and continued stirring for 0.5 hour until complete dissolution.0.1 M HNO was added with stirring3Adjust the pH to 4.3.After precipitation of a large amount of precipitate, filtration and drying were carried out to obtain 50 mg of a black solid in a yield of 100%.
 

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