Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
{[ item.p_purity ]} | {[ item.pr_size ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]} | {[ item.pr_usastock ]} | Inquiry - | {[ item.pr_chinastock ]} | Inquiry - |
* Storage: {[proInfo.prStorage]}
CAS No. : | 503859-61-8 | MDL No. : | MFCD09842766 |
Formula : | - | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | GASXLROKFOTRGN-UHFFFAOYSA-N |
M.W : | - | Pubchem ID : | 71310422 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P501-P261-P270-P271-P264-P280-P362+P364-P301+P312+P330-P302+P352+P312-P304+P340+P312 | UN#: | |
Hazard Statements: | H302+H312+H332 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In dichloromethane; at 40.0℃; for 1.0h;Schlenk technique; Inert atmosphere; | General procedure: The corresponding ligand (0.074mmol) was dissolved in CH2Cl2 (5mL) and [Ir(μ-Cl)(cod)]2 (25.0mg, 0.037mmol) was added. The reaction mixture was refluxed at 40C for 1h. After 5min at room temperature, NaBArF (77.2mg, 0.080mmol) and water (5mL) were added and the reaction mixture was stirred vigorously for 30min at room temperature. The phases were separated and the aqueous phase was extracted twice with CH2Cl2. The combined organic phases were dried with MgSO4. Evaporation of the solvent gave a brown-orange solid, which was purified by flash chromatography on neutral silica (dichloromethane/petroleum ether (1:1) as eluent) to produce the corresponding complex as an orange solid. |