Alternatived Products of [ 532-18-3 ]
Product Details of [ 532-18-3 ]
CAS No. : | 532-18-3 |
MDL No. : | MFCD03093264 |
Formula : |
C20H15N
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | SBMXAWJSNIAHFR-UHFFFAOYSA-N |
M.W : |
269.34
|
Pubchem ID : | 68283 |
Synonyms : |
|
Application In Synthesis of [ 532-18-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 532-18-3 ]
- 1
-
[ 532-02-5 ]

-
[ 91-59-8 ]

-
[ 532-18-3 ]
- 2
-
[ 3141-24-0 ]

-
[ 532-18-3 ]

-
[ 865-48-5 ]

-
[ 1300028-64-1 ]
Yield | Reaction Conditions | Operation in experiment |
68% |
With triphenylphosphine;tris-(dibenzylideneacetone)dipalladium(0); In toluene; |
(11) Synthesis of 3-Bromo-N2,N2,N5,N5-tetra(naphthalen-2-yl)thiophene-2,5-diamine 23.7 g of a product (yield: 68%) was obtained in the same manner as described in the synthesis method of 2-1 except that <strong>[3141-24-0]2,3,5-tribromothiophene</strong> (16.04 g, 50 mmol), dinaphthalen-2-ylamine (26.94 g, 100 mmol), Pd2(dba)3 (2.75 g, 3 mmol), PPh3 (2.62 g, 10 mmol), NaOt-Bu (28.83 g, 300 mmol), and toluene (525 mL) were used. |
- 3
-
[ 608-21-9 ]

-
[ 532-18-3 ]

-
C26H17Br2N
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
60% |
With bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; XPhos; In toluene; at 80℃; for 3h;Inert atmosphere; |
1,2,3-tribrorobenzene (3.15g, 10.0mmol) and bis(naphthalen-2-yl)amine (2.69g, 10.0mmol), t-BuONa (1.92g, 20.0mmol), toluene (45mL) Was put in. Nitrogen was blown, and Pd2(dba)3 (0.183g, 0.200mmol) and Xphos (0.19g, 0.400mmol) were added, followed by stirring at 80 C. for 5 hours, and then cooled to room temperature. After adding dichloromethane and purified water, the layers were separated. An organic layer was obtained, dried over MgSO4, and filtered. After the filtrate was concentrated, compound 5-1 (3.42g, 68%) was obtained by column chromatography (dichloromethane/heptane). |