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Chemical Structure| 555-75-9 Chemical Structure| 555-75-9

Structure of 555-75-9

Chemical Structure| 555-75-9

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Product Details of [ 555-75-9 ]

CAS No. :555-75-9
Formula : C6H15AlO3
M.W : 162.16
SMILES Code : CC[O-].CC[O-].CC[O-].[Al+3]
MDL No. :MFCD00009658

Safety of [ 555-75-9 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314-H228
Precautionary Statements:P501-P260-P240-P210-P241-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P405
Class:4.1(8)
UN#:2925
Packing Group:

Application In Synthesis of [ 555-75-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 555-75-9 ]

[ 555-75-9 ] Synthesis Path-Downstream   1~2

  • 2
  • [ 555-75-9 ]
  • [ 151433-25-9 ]
  • [aluminum((1R,2R)-N,N′-bis(3,5-di-tert-butyl-salicylidene)cyclohexane-1,2-diamine)2O] [ No CAS ]
YieldReaction ConditionsOperation in experiment
63% In toluene; for 4h;Heating / reflux; AI(OEt)3 (0.28 g, 1.72 mmol) was added to dry toluene (60 mL) and stirred under reflux for 1 hour. The appropriate salen ligand (1.68 mmol) dissolved in dry toluene (40 mL) was then added and the reaction mixture was stirred under reflux for a further 3 hours before being allowed to cool to room temperature. The solution was dried (Na2SO4) and solvents were evaporated in vacuo to give a solid which was purified as specified below. The analysis data are set out below.Data for complex 1a: Yellow solid purified by washing with cold hexane. Yield 63%; <n="25"/>[α]D20 -548 (c= 0.11 , CHCI3); vmax(CH2CI2) 2953 m, 1626 m, and 1474 cm 1 m; δH(CDCI3) 8.35 (2H, s, CH=N), 8.15 (2H, s, CH=N), 7.52 (4H, d J 2.3 Hz, 4 x ArH), 7.07 (4H, d J 2.3 Hz, 4 x ArH), 3.9-3.7 (2H, br m, CHN), 3.2-3.0 (2H, br m, CHN), 2.7-1.8 (16H, m, 2 x (CHz)4), 1.50 (36H, s, 4 x (CH3)3), 1.29 (36H, s, 4 x (CHs)3); m/z (ESI) 1159.7 (MH+), 649.4, 623.4, 603.4, 569.3; Found (ESI) 1159.7106, C72Hi05N4O5AI2 (MH+) requires 1159.7716.
 

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