Alternatived Products of [ 575456-77-8 ]
Product Details of [ 575456-77-8 ]
CAS No. : | 575456-77-8 |
MDL No. : | N/A |
Formula : |
-
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | AXSCZKAJIQMFGF-UHFFFAOYSA-J |
M.W : |
-
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Pubchem ID : | 73162355 |
Synonyms : |
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Safety of [ 575456-77-8 ]
Application In Synthesis of [ 575456-77-8 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 575456-77-8 ]
- 1
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[ CAS Unavailable ]
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[ 310874-13-6 ]
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[ 575456-77-8 ]
Yield | Reaction Conditions | Operation in experiment |
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In chlorobenzene under N2; Rh complex, ligand (9.6 equiv.) and chlorobenzene heated underreflux for 24 h in Soxlet apparatus fitted with thimble contg. dried Na 2CO3 and sand; solvent evapd.; purified by flash chromy. (basic alumina, MeOH); |
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16 g |
In chlorobenzene at 130 - 135℃; for 3h; |
2
Take a 250mL three-necked flask, and add chlorobenzene (150mL) in sequence under stirring.Compound 2-2 (14.1 g, 45.2 mmol) and dipolyrhodium acetate (5 g, 11.3 mmol); heated to 130 ° C-135 ° C, and reacted at reflux for 3 hours;The three-necked flask is equipped with a vacuum distillation device, and the solvent is distilled while stirring the reaction until it does not drip;Add n-hexane (60 mL), beat, filter, and dry the solid to obtain 16 g of Rh2 {(s) -nttl} 4. |
- 2
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[ 575456-77-8 ]
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[ CAS Unavailable ]
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[ CAS Unavailable ]
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[ CAS Unavailable ]
Yield | Reaction Conditions | Operation in experiment |
100% |
In dichloromethane at 20℃; for 0.5h; |
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- 3
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[ 1122-58-3 ]
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[ 575456-77-8 ]
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[ CAS Unavailable ]
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[ CAS Unavailable ]
Yield | Reaction Conditions | Operation in experiment |
100% |
In dichloromethane at 20℃; for 0.5h; |
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- 4
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[ CAS Unavailable ]
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[ 310874-13-6 ]
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[ 575456-77-8 ]
Yield | Reaction Conditions | Operation in experiment |
48% |
With lithium carbonate In ethanol at 20℃; for 6.5h; Inert atmosphere; Heating; |
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