Home Cart Sign in  
Chemical Structure| 57653-14-2 Chemical Structure| 57653-14-2

Structure of 57653-14-2

Chemical Structure| 57653-14-2

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 57653-14-2 ]

CAS No. :57653-14-2
Formula : C12H14
M.W : 158.24
SMILES Code : CC(C(C1)=CC2=C1C=CC=C2)C
MDL No. :MFCD25460243

Safety of [ 57653-14-2 ]

Application In Synthesis of [ 57653-14-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 57653-14-2 ]

[ 57653-14-2 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 10485-09-3 ]
  • [ 920-39-8 ]
  • [ 57653-14-2 ]
YieldReaction ConditionsOperation in experiment
71.1% Under an argon atmosphere, a solution of zinc chloride g, 28.0 mmol) in tetrahydrofuran suspension (5 mL) was added with a solution of isopropyl magnesium bromide in tetrahydrofuran (0.78 M, 30.7 mL) at 0 C., and the resultant was stirred at the same temperature for 1 hour. Then a solution of tetrakistriphenyl phosphine palladium (800 mg, 0.70 mmol) and <strong>[10485-09-3]2-bromoindene</strong> (3.87 g, 20.0 mmol) in tetrahydrofuran (10 mL) was added thereto, and the resultant was further stirred at the same temperature for 16 hours. The reaction solution was added with a saturated aqueous solution of ammonium chloride, and extracted with diethyl ether. The organic layer was dried over anhydrous sodium sulfate, concentrated in vacuo, and the resultant residue was purified using silica-gel chromatography (hexane). 2-Isopropylindene (2.25 g, 71.1%) was obtained as a colorless oil.1H-NMR (400 MHz, CDCl3) δ; 1.22 (d, J=6.6 Hz, 6H), 2.77 (septet, J=6.6 Hz, 1H), 3.30 (s, 2H), 6.50 (s, 1H), 7.10-7.34 (m, 4H).
  • 2
  • [ 80041-89-0 ]
  • [ 256637-49-7 ]
  • [ 57653-14-2 ]
 

Historical Records