Home Cart Sign in  
Chemical Structure| 60418-14-6 Chemical Structure| 60418-14-6

Structure of 60418-14-6

Chemical Structure| 60418-14-6

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 60418-14-6 ]

CAS No. :60418-14-6
Formula : C14H11N3O2
M.W : 253.26
SMILES Code : O=[N+](C1=CC=CC=C1C2=NC3=CC=CC=C3N2C)[O-]

Safety of [ 60418-14-6 ]

Application In Synthesis of [ 60418-14-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 60418-14-6 ]

[ 60418-14-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 2622-63-1 ]
  • [ 60418-14-6 ]
YieldReaction ConditionsOperation in experiment
42% With dipotassium peroxodisulfate; silver(I) nitrite; oxygen; palladium diacetate; at 130℃; for 42h;Sealed tube; General procedure: Compound 1 or 3 (0.5 mmol), Pd(OAc)2 (11.2 mg, 0.05mmol), AgNO2 (230.8 mg, 1.5 mmol), K2S2O8 (270.3 mg, 1.0 mmol) and anhydrous TCP (2 mL) were sequentially added to a 25 mL Schlenk-flask equipped with a high-vacuum PTFE valve-to-glass seal. Then the flask was sealed and stirred at 130 °C under O2 for 42 h. Upon completion, the resulting mixture was diluted with CH2Cl2 (10 mL) and then treated with 10mL of saturated Na2S aqueous solution. After filtered through a pad of Celite, the organic and aqueous layers were separated, and the aqueous layer was extracted with CH2Cl2 (2×10 mL). The combined organic layers were dried over Na2SO4 and filtered. After evaporation of the solvent under vacuum, the residue was purified by column chromatography on silica gel (100?200 mesh) using hexane-EtOAc as eluent (10:1, v/v) to give desired product 2 or 4.
 

Historical Records

Technical Information

Categories