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Chemical Structure| 606129-90-2 Chemical Structure| 606129-90-2

Structure of 606129-90-2

Chemical Structure| 606129-90-2

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Product Details of [ 606129-90-2 ]

CAS No. :606129-90-2
Formula : C36H23N3
M.W : 497.59
SMILES Code : N1(C2=CC3=C(C=C2)NC4=C3C=C(N5C6=C(C7=C5C=CC=C7)C=CC=C6)C=C4)C8=C(C9=C1C=CC=C9)C=CC=C8
MDL No. :MFCD29472452
InChI Key :OGDZAJUZGODBKX-UHFFFAOYSA-N
Pubchem ID :12103890

Safety of [ 606129-90-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 606129-90-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 606129-90-2 ]

[ 606129-90-2 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 3029-64-9 ]
  • [ 606129-90-2 ]
  • C113H66N12 [ No CAS ]
YieldReaction ConditionsOperation in experiment
50.2% 8.79 g (35 mmol) of isopropyl carbazole was added to a 250 ml three-necked flask, and 100 ml of N,N-dimethylformamide was added as a reaction solvent in an ice bath.Stir on a magnetic stirrer for 10 min. 0.72 g (30 mmol) of NaH was added portionwise to the reaction flask and stirring was continued for 1 h.4.97 g (10 mmol) of <strong>[3029-64-9]2,4,6-trichloro-5-cyanopyrimidine</strong> was dissolved in 40 ml of N,N-dimethylformamide solution, and added dropwise to the reaction system. After the addition, at room temperature The reaction was carried out for 24 h. After the reaction was completed, the reaction solution was poured into 200 ml of 10percent diluted hydrochloric acid, and the mixture was filtered under reduced pressure, washed with water and dried, and the crude product was obtained from petroleum ether and dichloromethane (PE: DCM=10: 1) Pass the column for the mobile phase. Obtained 7.98 g of a white solid powder in a yield of50.2percent.
  • 2
  • [ 100189-84-2 ]
  • [ 606129-90-2 ]
  • C44H30BrN3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
75.9% With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 100℃; for 24h;Inert atmosphere; 1) Under a nitrogen atmosphere, add 500 mol of Intermediate II-1, 0.3 mol of raw material IV-2, 0.15 mol of sodium tert-butoxide, 1 × 10-4 mol of Pd2 (dba) 3 and 1 × 10-4 mol of tri-tert-butyl phosphorus, then 150 mL of toluene was added to dissolve it, heated to 100 C, refluxed for 24 h, and the reaction was observed by TLC until the reaction was completed. It was left to cool to room temperature, filtered, and the filtrate was rotary distilled to no fractions. The obtained substance was purified through a silica gel column to obtain intermediate A-2, with a purity of 99.3% and a yield of 75.9%.
 

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