Alternatived Products of [ 60718-97-0 ]
Product Details of [ 60718-97-0 ]
| CAS No. : | 60718-97-0 |
MDL No. : | |
| Formula : |
C14H10O2S
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Boiling Point : |
- |
| Linear Structure Formula : | - |
InChI Key : | - |
| M.W : |
242.29
|
Pubchem ID : | - |
| Synonyms : |
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Safety of [ 60718-97-0 ]
| Signal Word: | |
Class: | |
| Precautionary Statements: | |
UN#: | |
| Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 60718-97-0 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 60718-97-0 ]
- 1
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[ 908094-01-9 ]
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[ 2786-08-5 ]
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[ 60718-97-0 ]
| Yield | Reaction Conditions | Operation in experiment |
|
With diethyl ether |
|
- 2
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[ 67-56-1 ]
-
[ 23985-81-1 ]
-
[ 60718-97-0 ]
| Yield | Reaction Conditions | Operation in experiment |
|
With iodine; potassium carbonate at 23℃; for 6h; |
1; 3 Example 1: Synthesis of Carboxylate Represented by Formula (I-1)
2.50 Parts of a compound represented by formula (I-1-a), 6.10 parts of potassium carbonate, 8.22 parts of iodine and 12.50 parts of methanol were mixed, followed by stirring at 23° C. for 6 hours. To the mixture thus obtained, 30 parts of an aqueous saturated sodium hydrogen sulfate solution and 60 parts of chloroform were added, followed by stirring at 23° C. for 30 minutes and further isolation through separation to obtain an organic layer. To the organic layer thus obtained, 30 parts of ion-exchanged water was added, followed by stirring at 23° C. for 30 minutes and further isolation through separation to obtain an organic layer. This water washing operation was performed five times. The organic layer thus obtained was concentrated and then the concentrated mixture was isolated from a column (silica gel 60N (spherical, neutral) 100-210 μm; manufactured by Kanto Chemical Co., Inc., developing solvent: n-heptane/ethyl acetate=1/1) to obtain 1.84 parts of a salt represented by formula (I-1-b). |
|
Stage #1: methanol; bisbenzo[b,d]thiophene-4-carbaldehyde With iodine; potassium carbonate at 23℃; for 6h;
Stage #2: With sodium hydrogencarbonate In chloroform at 23℃; for 0.5h; |
1; 3 Example 1: Synthesis of Carboxylate Represented by Formula (I-1)
2.50 parts of compound represented by formula (I-1-a), 6.10 parts of potassium carbonate, 8.22 parts of iodine and 12.50 parts of methanol were mixed and stirred at 23 ° C. for 6 hours. To the obtained mixture, 30 parts of a saturated aqueous sodium hydrogensulfate solution and 60 parts of chloroform were added, and the mixture was stirred at 23 ° C. for 30 minutes and separated to obtain an organic layer. To the obtained organic layer, 30 parts of ion-exchanged water was added, and the mixture was stirred at 23 ° C. for 30 minutes and separated to obtain an organic layer. This washing operation was performed 5 times. The obtained organic layer is concentrated, and the concentrated mixture is prepared using a column (silica gel 60N (spherical, neutral) 100-210 μm; manufactured by Kanto Chemical Co., Inc., developing solvent: n-heptane / ethyl acetate = 1/1). By fractionation, 1.84 parts of the compound represented by the formula (I-1-b) was obtained. 0.78 parts of the compound represented by the formula (I-1-b), |
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