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Chemical Structure| 613-14-9 Chemical Structure| 613-14-9

Structure of 613-14-9

Chemical Structure| 613-14-9

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Product Details of [ 613-14-9 ]

CAS No. :613-14-9
Formula : C14H10O
M.W : 194.23
SMILES Code : OC1=CC=C2C=C3C=CC=CC3=CC2=C1
MDL No. :MFCD06653605
InChI Key :BQBWUVWMUXGILF-UHFFFAOYSA-N
Pubchem ID :99503

Safety of [ 613-14-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 613-14-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 613-14-9 ]

[ 613-14-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 605-32-3 ]
  • [ 613-14-9 ]
YieldReaction ConditionsOperation in experiment
93% With sodium tetrahydroborate; sodium carbonate; In isopropyl alcohol; for 0.333333h;Heating; NaBH4 (3.8 g, 100 mmol) was dissolved in 1M Na2CO3 (150 mL) in a large beaker (2 L), isopropanol (25 mL) was added and the resulting solution was heated to boiling point. Then solution of hydroxyanthraquinone 6 (2.5 g, 10 mmol) in 1M Na2CO3 (50 mL) was added portionwise with vigorous stirring and breaking the foam with a glass rod. The reaction mixture was heated at boiling point for 20 min, cooled to rt and acidified with 3M HCl. The product was filtered and washed thoroughly with water and finally dried in evacuated dessicator over KOH for 2 days to afford the product (2 g, 93%) in the form of yellow solid. The product was pure enough for the next step, no purification was needed.
 

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