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Chemical Structure| 613-35-4 Chemical Structure| 613-35-4

Structure of 613-35-4

Chemical Structure| 613-35-4

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Product Details of [ 613-35-4 ]

CAS No. :613-35-4
Formula : C16H16N2O2
M.W : 268.31
SMILES Code : NC1=CC=C(C=C1)C2=CC=C(C=C2)N(C(C)=O)C(C)=O
MDL No. :MFCD00048194

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Application In Synthesis of [ 613-35-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 613-35-4 ]

[ 613-35-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 613-35-4 ]
  • [ 17024-12-3 ]
  • [ 690658-62-9 ]
YieldReaction ConditionsOperation in experiment
Mixed under argon flow were 100 g of N,N'-diacetyl-4,4'-benzidine (manufactured by Tokyo Kasei Kogyo Co., Ltd.), 337 g of <strong>[17024-12-3]9-iodophenanthrene</strong>, 204 g of anhydrous potassium carbonate (manufactured by Tokyo Kasei Kogyo Co., Ltd.), 4.7 g of copper powder (manufactured by Hiroshima Wako Co., Ltd.) and 750 ml of decalin, and they were reacted at 190C for 3 days. After cooling, 2 liter of toluene was added thereto to filter an insoluble matter. The matter filtered was dissolved in 4.5 liter of chloroform to filter off an insoluble matter, and then the filtrate was treated with activated carbon and concentrated under reduced pressure. Acetone 3 litter was added when the solution became slurry in the middle of concentration, and crystal deposited was filtered and dried. This was suspended in a mixture of 2 liter of ethylene glycol and 20 ml of water, and 110 g of a 85 % potassium hydroxide aqueous solution was added thereto, followed by carrying out reaction at 120C for 12 hours. After left cooling down to a room temperature, the reaction liquid was injected to 4 liter of water and treated with activated carbon, and then it was concentrated under reduced pressure. Acetone was added when the solution became slurry, and crystal deposited was filtered and dried to obtain 116 g of N,N'-bis(phenantho-9-yl)-4,4'-benzidine (A3).
 

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