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Chemical Structure| 614-69-7 Chemical Structure| 614-69-7

Structure of 614-69-7

Chemical Structure| 614-69-7

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Product Details of [ 614-69-7 ]

CAS No. :614-69-7
Formula : C8H7NS
M.W : 149.21
SMILES Code : CC1=CC=CC=C1N=C=S
MDL No. :MFCD00004802
InChI Key :JYKYYPPZLPVIBY-UHFFFAOYSA-N
Pubchem ID :69195

Safety of [ 614-69-7 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301-H311-H315-H319-H331-H335
Precautionary Statements:P233-P260-P261-P264-P270-P271-P280-P301+P310-P302+P352-P304-P304+P340-P305+P351+P338-P311-P312-P321-P322-P330-P332+P313-P337+P313-P340-P361-P362-P363-P403-P403+P233-P405-P501
Class:6.1
UN#:2810
Packing Group:

Application In Synthesis of [ 614-69-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 614-69-7 ]

[ 614-69-7 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 30065-27-1 ]
  • [ 614-69-7 ]
  • [ 62638-89-5 ]
  • 2
  • [ 828-81-9 ]
  • [ 614-69-7 ]
  • 1-[5-(2-chloro-phenyl)-[1,3,4]thiadiazol-2-yl]-3-<i>o</i>-tolyl-thiourea [ No CAS ]
  • 3
  • [ 120-35-4 ]
  • [ 614-69-7 ]
  • 4-Methoxy-N-phenyl-3-(3-o-tolyl-thioureido)-benzamide [ No CAS ]
YieldReaction ConditionsOperation in experiment
In ethyl acetate; Example 98 4-Methoxy-N-phenyl-3-(3-o-tolyl-thioureido)-benzamide A mixture of 3-amino-4-methoxy-N-phenyl-benzamide (0.972 g, 4.00 mmol), 2-methylphenyl isothiocyanate (0.55 mL, 4.11 mmol, and ethyl acetate 20 mL) was allowed to stand at room temperature. After 4 days, the reaction was heated to 80 C. for 3 hours then allowed to stand at room temperature for an additional 5 days. Filtration afforded the product (0.804 g); m.p. 172-174 C. Calculated for C22H21N3O2S: C, 67.50; H, 5.41; N, 10.73. Found: C, 66.96; H, 5.47; N, 10.56.
  • 4
  • [ 63746-12-3 ]
  • [ 614-69-7 ]
  • C17H14N2O3S [ No CAS ]
YieldReaction ConditionsOperation in experiment
90% With pyridine; at 100℃; Add 6.7 g of <strong>[63746-12-3]dimethyl 4-aminoisophthalate</strong> to a 100 mL double-neck flask, add 30 mL of pyridine and 6 g of o-methylphenylthioisocyanate and react at 100 C. overnight. Add 40 mL of water after the reaction, stir for 30 min, separate out a large amount of white solid, perform suction filtration and wash the solid with diethyl ether. Dry the solid to obtain a pure product. The output is 9.45 g and the yield is 90%; mp 227-229 C. 1H NMR (600 MHz, DMSO-D6): delta 13.38 (s, 1H), 8.47 (s, 1H), 8.30 (d, J=9.0 Hz, 1H), 7.53 (d, J=9.0 Hz, 1H), 7.36-7.28 (m, 3H), 7.23 (d, J=7.2 Hz, 1H), 3.89 (s, 3H), 2.06 (s, 3H).
 

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