[ CAS No. 62281-07-6 ] {[proInfo.proName]}

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Quality Control of [ 62281-07-6 ]

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Product Details of [ 62281-07-6 ]

CAS No. :	62281-07-6	MDL No. :	MFCD26407439
Formula :	C₂₄H₅₁N	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	353.67	Pubchem ID :	-
Synonyms :

Safety of [ 62281-07-6 ]

Signal Word:	Danger	Class:	8
Precautionary Statements:	P501-P264-P280-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P405	UN#:	2735
Hazard Statements:	H314	Packing Group:	Ⅱ
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Application In Synthesis of [ 62281-07-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 62281-07-6 ]

[ 62281-07-6 ] Synthesis Path-Downstream 1~16

1
[ 62281-07-6 ]
[ 118129-60-5 ]
N,N-bis(2-decyl-1-tetradecyl)-1,7-dibromoperylene-3,4,9,10-tetracarboxylic acid bisimide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
81%	In water; butan-1-ol at 80℃; for 17h;
81%	In water; butan-1-ol at 80℃; for 17h; Inert atmosphere;	1 1,7-bisbromo-3,4,9,10-tetracarboxylic dianhydride (2.74 g, 4.98 mmol) in 200 ml BuOH/H2O (1:1) was sonicated for 10 min, 2-decyl-1-tetradecylamine (6.2 g, 17.53 mmol) was added, and the reaction mixture was heated at 80° C. for 17 h under nitrogen. 20 ml HCl was added and the mixture stirred at room temperature for 30 min. The mixture was extracted with chloroform, dried over MgSO4, and filtered. The solvent was removed and the residue purified by chromatography eluting with 1:1 CHCl3/Hexane, 4.9 g (81%) red solid was obtained. 1H NMR (500 MHz, CDCl3): δ (ppm): 9.43 (d, J=8.5 Hz, 2H), 8.87 (s, 2H), 8.64 (d, J=8.0 Hz, 2H), 4.11 (d, J=7.0 Hz, 4H), 1.98 (m, 2H), 1.5-1.1 (m, 80H), 0.84 (m, 12H). 13C NMR (125 MHz, CDCl3): δ(ppm): 163.2, 162.7, 138.1, 132.9, 132.7, 130.0, 129.2, 128.4, 126.9, 123.1, 122.7, 120.8, 44.8, 36.6, 31.9, 31.7, 31.6, 30.0, 29.68, 29.65, 29.3, 26.5, 22.7, 14.1. (12 aliphatic carbons not observed presumably due to overlapping resonances). MS (MALDI), m/z: calculated for C72H105Br2N2O4 (M+H), 1219.6536; found 1220.6513. Elemental analysis, calc. for C72H104Br2N2O4, C, 70.80; H, 8.58; N, 2.29; found C, 70.98; H, 8.59; N, 2.34.
	With acetic acid

Reference： [1]Zhan, Xiaowei; Tan, Zhan'ao; Domercq, Benoit; An, Zesheng; Zhang, Xuan; Barlow, Stephen; Li, Yongfang; Zhu, Daoben; Kippelen, Bernard; Marder, Seth R. [Journal of the American Chemical Society, 2007, vol. 129, # 23, p. 7246 - 7247]
[2]Current Patent Assignee: GEORGIA INSTITUTE OF TECHNOLOGY - US8039625, 2011, B2 Location in patent: Page/Page column 28
[3]Nakabayashi, Kazuhiro; Takeuchi, Yuhei; Mori, Hideharu [Bulletin of the Chemical Society of Japan, 2016, vol. 89, # 9, p. 1063 - 1068]

2
[ 62281-07-6 ]
[ 299962-88-2 ]
[ 1219501-16-2 ]

Yield	Reaction Conditions	Operation in experiment
19%	Stage #1: 2-decyl-1-tetradecylamine; 2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride With acetic acid Reflux; Stage #2: With phosphorus tribromide In toluene Reflux;
19%	Stage #1: 2-decyl-1-tetradecylamine; 2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride With acetic acid at 120℃; for 0.5 - 1h; Inert atmosphere; Stage #2: With phosphorus tribromide In toluene for 1h; Reflux;	Synthesis of N,N'-di(2-decyltetradecyl)-2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic acid diimide (22): TBNDA (3.3 g, 5.7 mmol) and 2-decyl-tetradecyl amine (6.5 g, 18.4 mmol) were added into acetic acid (50 mL) under nitrogen atmosphere, heated to 120°C. Heating was terminated when the reaction liquid turned clear and before the color got dark (the heating lasted for about 0.5∼1 hour). After cooled to room temperature, the reaction solution was poured into water (400 mL) and filtered. The resulting precipitate was washed with water (200 mL), and dried under vacuum to obtain a yellow solid. The yellow solid and phosphorus tribromide (2.0 mL, 21.1 mmol) were added into anhydrous toluene (120 mL) and heated to reflux for 1 hour. After cooled to room temperature, the reaction liquid was poured into water (400 mL) and extracted with toluene (200 mL × 3). The organic phases were combined and the solvent was evaporated under reduced pressure. The crude product was purified by silica gel chromatography column using dichloromethane/petroleum ether (1/2) as an eluent to give 1.35 g of a yellow solid (22), and the yield was 19% (calculated based on TBNDA as a starting material). MS (MALDI-TOF) m/z 1257.6 (M+); 1H-NMR (300 MHz, CDCl3) δ (ppm): 0.852-0.894 (m, 6H, -CH3), 1.287-1.409 (m, 8H, CH2), 1.235 (b, 40H, CH2), 1.970-2.005 (m, 1H, CH), 4.159-4.184 (d, J = 7.50 Hz, 2H, -CH2-N); 13C-NMR (100 MHz, CDCl3): δ 14.10, 22.67, 26.25, 29.33, 29.56, 29.64, 30.01, 31.50, 31.90, 36.50, 46.60, 125.75, 126.32, 135.23, 160.18 (CO).
19%	In acetic acid at 120℃; Inert atmosphere;	TBNDA (3.3 g, 5.7 mmol) and 2-decyl-tetradecyl amine (6.5 g, 18.4 mmol) were added into acetic acid (50 mL) under nitrogen atmosphere, heated to 120° C. Heating was terminated when the reaction liquid turned clear and before the color got dark (the heating lasted for about 0.51 hour). After cooled to room temperature, the reaction solution was poured into water (400 mL) and filtered. The resulting precipitate was washed with water (200 mL), and dried under vacuum to obtain a yellow solid. The yellow solid and phosphorus tribromide (2.0 mL, 21.1 mmol) were added into anhydrous toluene (120 mL) and heated to reflux for 1 hour. After cooled to room temperature, the reaction liquid was poured into water (400 mL) and extracted with toluene (200 mL×3). The organic phases were combined and the solvent was evaporated under reduced pressure. The crude product was purified by silica gel chromatography column using dichloromethane/petroleum ether (1/2) as an eluent to give 1.35 g of a yellow solid (22), and the yield was 19% (calculated based on TBNDA as a starting material).MS (MALDI-TOF) m/z 1257.6 (M+);1H-NMR (300 MHz, CDCl3) δ (ppm): 0.852-0.894 (m, 6H, -CH3), 1.287-1.409 (m, 8H, CH2), 1.235 (b, 40H, CH2), 1.970-2.005 (m, 1H, CH), 4.159-4.184 (d, J=7.50 Hz, 2H, -CH2-N);13C-NMR (100 MHz, CDCl3): δ 14.10, 22.67, 26.25, 29.33, 29.56, 29.64, 30.01, 31.50, 31.90, 36.50, 46.60, 125.75, 126.32, 135.23, 160.18 (CO).

Reference： [1]Gao, Xike; Di, Chong-An; Hu, Yunbin; Yang, Xiaodi; Fan, Hongyu; Zhang, Feng; Liu, Yunqi; Li, Hongxiang; Zhu, Daoben [Journal of the American Chemical Society, 2010, vol. 132, # 11, p. 3697 - 3699]
[2]Current Patent Assignee: Institute of Chemistry (in: CAS); CHINESE ACADEMY OF SCIENCES - EP2492271, 2012, A1 Location in patent: Page/Page column 10
[3]Current Patent Assignee: Institute of Chemistry (in: CAS); CHINESE ACADEMY OF SCIENCES - US2012/253045, 2012, A1 Location in patent: Page/Page column 8

3
[ 62281-07-6 ]
[ 113377-10-9 ]
[ 4885-93-2 ]
[ 299962-88-2 ]
[ 1351161-74-4 ]

Yield	Reaction Conditions	Operation in experiment
21%	Stage #1: 2-(2,4-dithia-1,5-disodapentan-3-ylidene)propanedinitrile; 2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride In N,N-dimethyl-formamide at 50℃; for 1h; Inert atmosphere; Stage #2: 2-decyl-1-tetradecylamine; N-(2-aminoethyl)tricosa-10,12-diynamide In N,N-dimethyl-formamide at 50℃; for 6h; Inert atmosphere;

Reference： [1]Hu, Yunbin; Qin, Yunke; Gao, Xike; Zhang, Fengjiao; Di, Chong-An; Zhao, Zheng; Li, Hongxiang; Zhu, Daoben [Organic Letters, 2012, vol. 14, # 1, p. 292 - 295]

4
[ 62281-07-6 ]
[ 1122-12-9 ]
[ 1301741-17-2 ]

Reference： [1]Macromolecules,2011,vol. 44,p. 4213 - 4221

5
[ 62281-07-6 ]
[ 83204-68-6 ]
[ 1088205-04-2 ]

Yield	Reaction Conditions	Operation in experiment
41.5%	With propionic acid at 140℃;
13.4%	In o-xylene; propionic acid at 140℃;

Reference： [1]Lin, Zuzhang; Liu, Xiaotong; Zhang, Weifeng; Wei, Congyuan; Huang, Jianyao; Chen, Zhihui; Wang, Liping; Yu, Gui [Journal of Polymer Science, Part A: Polymer Chemistry, 2017, vol. 55, # 21, p. 3627 - 3635]
[2]Location in patent: experimental part Zhou, Weiyi; Wen, Yugeng; Ma, Lanchao; Liu, Yunqi; Zhan, Xiaowei [Macromolecules, 2012, vol. 45, # 10, p. 4115 - 4121]

6
[ 732276-63-0 ]
[ 62281-07-6 ]

Reference： [1]Journal of Materials Chemistry A,2015,vol. 3,p. 6929 - 6934
[2]Angewandte Chemie - International Edition,2016,vol. 55,p. 12996 - 13000
Angew. Chem.,2016,vol. 128,p. 13190 - 13194
[3]Patent: WO2017/148864,2017,A1
[4]Journal of Materials Chemistry C,2022,vol. 10,p. 1698 - 1710

7
[ 62281-07-6 ]
[ 25121-83-9 ]
C₃₀H₅₃NS₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
15.5%	With potassium phosphate; copper(l) iodide; copper at 80℃; for 48h;	1 Preparation of compound 5a Compound 6a (5.00 g, 22.82 mmol, 1 equiv.), copper (0.07 g, 1.14 mmol, 5 mol%) copper(l)iodide (0.22 g, 1.14 mmol, 5 mol%), potassium phosphate tribasic (9.69g, 45.64 mmol, 2 equiv.)and 2-decyltetradecyl amine (12.11 g, 34.23 mmol, 1.5 equiv.) were heated with stirring in dimethyl aminoethanol (50 mL) at 80 °C for 48 hours. Upon cooling to room temperature, water and hexane were added. The aqueous layer was extracted several times with hexanes. The organic layers were combined, dried over MgSO4 and the solvent was removed by rotary evaporation. The crude product was passed through a small silica column using hexane as solvent to affordcompound 5a as brown oil (1.74 g, 3.54 mmol, 15.5 %). 1H NMR (400 MHz, CDCI3); 67.36 (dd, J= 5.3, 1.4 Hz, 1H), 6.05 (d, 1H, J= 2.1 Hz), 3.56 (s, 1H), 3.13 (d, J= 6.1 Hz, 2H), 1.29 (bm, 40H), 0.91 (m, 6H).
	With dipotassium hydrogenphosphate; copper(l) iodide; 3-aminobutan-2-ol; copper at 80℃;

Reference： [1]Current Patent Assignee: CLAP CO LTD - WO2016/5891, 2016, A1 Location in patent: Page/Page column 87; 88
[2]Meager, Iain; Nikolka, Mark; Schroeder, Bob C.; Nielsen, Christian B.; Planells, Miquel; Bronstein, Hugo; Rumer, Joseph W.; James, David Ian; Ashraf, Raja Shahid; Sadhanala, Aditya; Hayoz, Pascal; Flores, Jean-Charles; Sirringhaus, Henning; McCulloch, Iain [Advanced Functional Materials, 2014, vol. 24, # 45, p. 7109 - 7115]

8
[ 62281-07-6 ]
[ 6007-85-8 ]
5-(2-decyltetradecyl)-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
74%		Thieno[3,4-c]furan-1,3-dione (3.0 g, 0.0194 mol) anddecyltetradecan-1-amine (7.5 g, 0.021 mol) were addedinto toluene (300 mL) and refluxed for 24 h at 100 C. Andthen the solvent was removed, thionyl chloride (300 mL)was added, and the mixture was stirred for an additional4 h at 80 C. The mixture was then cooled down to roomtemperature, and the solvent was removed. Further purificationwas carried out by applying column chromatographyon silica gel using n-hexane:dichloromethane (1:1).Yield: 7.05 g (74%). 1H NMR (300 MHz, CDCl3: 7.81

Reference： [1]Journal of Nanoscience and Nanotechnology,2017,vol. 17,p. 5662 - 5668
[2]RSC Advances,2015,vol. 5,p. 55619 - 55624

9
[ 62281-07-6 ]
[ 293738-03-1 ]
5-bromo-N-(2-decyltetradecyl)-2-iodobenzene [ No CAS ]

Reference： [1]RSC Advances,2016,vol. 6,p. 16437 - 16447

10
[ 62281-07-6 ]
[ 1015423-45-6 ]
1,3-dibromo-5-(2-decyltetradecyl)-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2016,vol. 55,p. 12996 - 13000
Angew. Chem.,2016,vol. 128,p. 13190 - 13194

11
[ 58670-89-6 ]
[ 62281-07-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: N-Bromosuccinimide; triphenylphosphine / dichloromethane / 12 h / 20 °C / Inert atmosphere 2: N,N-dimethyl-formamide / 18 h / 90 °C / Inert atmosphere 3: hydrazine hydrate / methanol / 12 h / 95 °C / Inert atmosphere
	Multi-step reaction with 3 steps 1.1: pyridine / 0.5 h / 0 °C 1.2: 2 h 2.1: N,N-dimethyl-formamide / 16 h / 90 °C / Inert atmosphere 3.1: hydrazine / methanol / 12 h / 95 °C / Inert atmosphere
	Multi-step reaction with 3 steps 1.1: triphenylphosphine / dichloromethane / 0.08 h / 0 °C / Inert atmosphere 1.2: 16 h 2.1: N,N-dimethyl-formamide / 16 h / Reflux 3.1: hydrazine hydrate / water; methanol / 16 h / Reflux

Multi-step reaction with 3 steps 1: triphenylphosphine; bromine / dichloromethane / 0 - 20 °C / Inert atmosphere 2: N,N-dimethyl-formamide / 90 °C / Inert atmosphere 3: hydrazine hydrate / methanol / 45 h / 95 °C

Reference： [1]Liu, Shengjian; Kan, Zhipeng; Thomas, Simil; Cruciani, Federico; Brédas, Jean-Luc; Beaujuge, Pierre M. [Angewandte Chemie - International Edition, 2016, vol. 55, # 42, p. 12996 - 13000][Angew. Chem., 2016, vol. 128, p. 13190 - 13194]
[2]Lee, Ji Eun; Kim, Yebyeol; Ha, Jong-Jin; An, Tae Kyu; Kim, Yun-Hi [Journal of Nanoscience and Nanotechnology, 2017, vol. 17, # 8, p. 5662 - 5668]
[3]Current Patent Assignee: CLAP CO LTD - WO2017/148864, 2017, A1
[4]Adel, Rana; Alonso-Navarro, Matías J.; Campoy-Quiles, Mariano; De La Peña, Alejandro; Gala, Elena; Gutierrez-Fernandez, Edgar; Harbuzaru, Alexandra; Martín, Jaime; Martinez-Ferrero, Eugenia; Ortiz, Rocío Ponce; Ramos, M. Mar; Segura, José L.; Stella, Marco [Journal of Materials Chemistry C, 2022, vol. 10, # 5, p. 1698 - 1710]

12
[ 62281-07-6 ]
[ 6007-85-8 ]
1,3-dibromo-5-(2-decyltetradecyl)-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
89.98%		2 mmol of <strong>[6007-85-8]3,4-thiophenedicarboxylic anhydride</strong> and 2.6 mmol of 2-decyl-1-tetradecylamine were added to a refluxing reactor equipped with a stirrer, 15 mL of toluene solvent was added, pass nitrogen protection, at 120 C under the conditions, Reflux 24h; The reaction was cooled to room temperature, And 16 mmol of dibromo sulfoxide was added under stirring at 0 C, Then 18 mmol of anhydrous pyridine was added, This mixture was stirred at room temperature for 5 hours, Heated to 120 C reflux reaction for 24h, the end of the reaction, the reaction cooled to room temperature, And then the product slowly dumped in a beaker containing ice, stirring constantly, The organic layer was collected by extraction with dichloromethane, and the organic layer was dried over anhydrous magnesium sulfate, filtered, evaporated, and subjected to column chromatography, rotary distillation, suction filtration and vacuum drying to obtain a compound of the formula of product yield was 89.98%.

Reference： [1]Patent: CN104402901,2016,B .Location in patent: Paragraph 0048; 0050; 0052

13
[ 62281-07-6 ]
[ 1542-34-3 ]
[ 4885-93-2 ]
[ 299962-88-2 ]
C₅₂H₅₁F₂IN₆O₄S₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
10%		Under ambient conditions, a solution of 3 (500 mg, 0.86 mmol) and sodium 1,1-dicyanoethene-2,2-dithiolate (480 mg, 2.57 mmol) in DMF (25 mL) was stirred at 55 C for 1 hour. Then 2-decyltetradecylamine (394 mg, 1.11 mmol) and 3,5-difluoroiodoaniline[2] (371 mg, 1.46 mmol) were added to the reaction mixture. The resulting purple black solution was stirred at 55 C for 12 hours, and water (200 mL) was added to quench the reaction. The product was extracted with CH2Cl2 (3 × 50 mL), and the combined organic solution was washed with water, brine, and dried over anhydrous MgSO4. After removing the solvent under reduced pressure, the crude product was purified by silica gel column chromatography with CH2Cl2 as eluent. Compound 1 was obtained as a purple red solid (yield: 10 %).

Reference： [1]Chinese Chemical Letters,2018,vol. 29,p. 423 - 428

14
[ 62281-07-6 ]
[ 372-39-4 ]
[ 4885-93-2 ]
[ 299962-88-2 ]
C₅₂H₅₂F₂N₆O₄S₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
10%	Stage #1: 2-(2,4-dithia-1,5-disodapentan-3-ylidene)propanedinitrile; 2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride In N,N-dimethyl-formamide at 55℃; for 1h; Stage #2: 2-decyl-1-tetradecylamine; 3,5-difluoroaniline In N,N-dimethyl-formamide at 55℃; for 12h;	2,2-[2-(3,5-difluoro-4-iodo)phenyl-8-(2-decyltetradecyl)-1,2,3,7,8,9-hexahydro-1,3,7,9-tetraoxo[1,3]benzodithiolo[4,5,6,7-lmn][1,3]dithiolo[4,5-f][3,8]phenanthroline-5,11-diylidine]bis(malononitrile) (1). General procedure: Under ambient conditions, a solution of 3 (500 mg, 0.86 mmol) and sodium 1,1-dicyanoethene-2,2-dithiolate (480 mg, 2.57 mmol) in DMF (25 mL) was stirred at 55 °C for 1 hour. Then 2-decyltetradecylamine (394 mg, 1.11 mmol) and 3,5-difluoroiodoaniline[2] (371 mg, 1.46 mmol) were added to the reaction mixture. The resulting purple black solution was stirred at 55 °C for 12 hours, and water (200 mL) was added to quench the reaction. The product was extracted with CH2Cl2 (3 × 50 mL), and the combined organic solution was washed with water, brine, and dried over anhydrous MgSO4. After removing the solvent under reduced pressure, the crude product was purified by silica gel column chromatography with CH2Cl2 as eluent. Compound 1 was obtained as a purple red solid (yield: 10 %).

Reference： [1]Li, Jing; Hu, Yong-Hui; Ge, Cong-Wu; Gong, He-Gui; Gao, Xi-Ke [Chinese Chemical Letters, 2018, vol. 29, # 3, p. 423 - 428]

15
[ 62281-07-6 ]
[ 86-90-8 ]
5-bromo-2-(2-decyltetradecyl)isoindoline-1,3-dione [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
78%	In acetic acid; at 120℃; for 8h;	General procedure: To a mixture of <strong>[86-90-8]4-bromo-phthalic anhydride</strong> (1.5 g, 6.61 mmol) and2-butyl-octylamine (1.41 g, 7.60 mmol), 10 mL of acetic acid was addedas a solvent and stirred at 120 C for 8 h. When the reaction was determinedto be complete, the reaction was cooled to room temperature,and then extracted with chloroform and water. The organic layer wasdried with anhydrous Na2SO4 and concentrated by vacuum evaporationto obtain colourless oil. The crude product was purified by silica gelchromatography using a mixture of hexane and DCM as eluent to obtainproduct as colourless oil (2.0 g, 75%).

Reference： [1]Organic electronics,2018,vol. 62,p. 12 - 20

16
[ 62281-07-6 ]
[ 19725-82-7 ]
7-bromo-2-(2-decyltetradecyl)isoquinolinedione [ No CAS ]

Reference： [1]Macromolecules,2019,vol. 52,p. 8238 - 8247

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P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 62281-07-6 ] {[proInfo.proName]}

Quality Control of [ 62281-07-6 ]

Related Doc. of [ 62281-07-6 ]

Product Details of [ 62281-07-6 ]

Safety of [ 62281-07-6 ]

Application In Synthesis of [ 62281-07-6 ]

[ 62281-07-6 ] Synthesis Path-Downstream 1~16

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry