Alternatived Products of [ 62769-24-8 ]
Product Details of [ 62769-24-8 ]
CAS No. : | 62769-24-8 |
MDL No. : | MFCD09038959 |
Formula : |
C48H36ClMnN4O4
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | OIOAQBHDVVOKIK-UHFFFAOYSA-L |
M.W : |
823.21
|
Pubchem ID : | 156592363 |
Synonyms : |
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Application In Synthesis of [ 62769-24-8 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 62769-24-8 ]
- Downstream synthetic route of [ 62769-24-8 ]
- 1
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[ 101565-35-9 ]
-
[ 62769-24-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With NaCl In dichloromethane; water a soln. of Mn-compd. in CH2Cl2 was treated with a dil. aq. soln. of NaCl; the procedure was repeated, followed by a final wash with distd. water; the org.layer was collected, dried over anhyd. Na2SO4, then reduced to 5 ml under reduced pressure;; crystn. by slow addn. of heptane; purity was confirmed by visible spectroscopy and cyclic voltammetric behavior;; |
|
- 2
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hydroxo(tetrakis(p-methoxyphenyl)porphinato)manganese(III)
[ No CAS ]
-
[ 62769-24-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With hydrogenchloride In dichloromethane stirred with 1 M aq. HCl; heptane was added, vac.-dried at 100°C; |
|
- 3
-
[ 62769-24-8 ]
-
[ 139312-22-4 ]
Yield | Reaction Conditions | Operation in experiment |
|
With tetrahydrofuran; silver tetrafluoroborate In tetrahydrofuran byproducts: AgCl; excess of AgBF4; inert atmosphere; UV; |
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- 4
-
[ 62769-24-8 ]
-
[ 10102-43-9 ]
-
nitrolsylmanganese(II) meso-tetra(p-methoxyphenyl)porphyrin
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
65% |
With sodium tetrahydroborate In methanol byproducts: H2; Mn-compd. addn. to NaBH4 in round-bottom flask, purging N2 for 20 min, solvent addn., stirring (N2) until H2 ceased, NO bubbling into soln. for 20 min, pptn.; ppt. filtration under N2; |
|
- 5
-
[ 110-89-4 ]
-
[ 62769-24-8 ]
-
[ 10102-43-9 ]
-
[ 673459-85-3 ]
Yield | Reaction Conditions | Operation in experiment |
81% |
In dichloromethane charging of Schlenk flask with (C20H8N4(p-MeOC6H4)4)MnCl, CH2Cl2 and piperidine; bubbling of NO gas through soln. for 20 min; bubbling of N2 for5 min; addn. of methanol; concn. in vac., pptn., discarding of supernatant soln.; drying in vac.; |
|
- 6
-
[ 62769-24-8 ]
-
[ 107-15-3 ]
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C2H8N2*C48H36N4O4(2-)*Cl(1-)*Mn(3+)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
75% |
In ethanol for 24h; Reflux; |
|
- 7
-
[ 22112-78-3 ]
-
[ 62769-24-8 ]
Yield | Reaction Conditions | Operation in experiment |
91% |
With [Mn(III)(acac)2Cl]; acetic anhydride; acetic acid for 4h; Reflux; |
|
- 8
-
manganese(II) chloride tetrahydrate
[ No CAS ]
-
[ 22112-78-3 ]
-
[ 62769-24-8 ]
Yield | Reaction Conditions | Operation in experiment |
97.5% |
In N,N-dimethyl-formamide for 0.5h; Reflux; |
|
Reference:
[1]Wang, Lanzhi; She, Yuanbin; Zhong, Rugang; Ji, Hongbing; Zhang, Yanhui; Song, Xufeng
[Organic Process Research and Development, 2006, vol. 10, # 4, p. 757 - 761]