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[ CAS No. 64339-43-1 ] {[proInfo.proName]}

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Chemical Structure| 64339-43-1
Chemical Structure| 64339-43-1
Structure of 64339-43-1 * Storage: {[proInfo.prStorage]}
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Product Details of [ 64339-43-1 ]

CAS No. :64339-43-1 MDL No. :MFCD16251428
Formula : C6H5IO2 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 236.01 Pubchem ID :-
Synonyms :

Safety of [ 64339-43-1 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 64339-43-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 64339-43-1 ]

[ 64339-43-1 ] Synthesis Path-Downstream   1~7

  • 1
  • [ 62938-08-3 ]
  • [ 64339-43-1 ]
  • C36H49IO2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
93% With 18-crown-6 ether; potassium carbonate In acetone Heating;
  • 2
  • [ 64339-43-1 ]
  • [ 27208-80-6 ]
  • 3
  • [ 620-18-8 ]
  • [ 64339-43-1 ]
  • (E)-1-(3-hydroxyphenyl)-2-(3,5-dihydroxyphenyl)ethene [ No CAS ]
YieldReaction ConditionsOperation in experiment
47.1% With triethanolamine; palladium diacetate at 100℃; for 24h; Inert atmosphere; 5.1.2. General procedure for the Mizoroki-Heck reactions General procedure: A mixture of the styrene (3 mmol), the halogenated benzene (3 mmol), triethanolamine (3 mmol) and Pd(II) acetate (0.03 g) was stirred under argon at 100 °C for 24 h. The reaction was cooled to 25 °C, quenched by the addition of dil. aq. hydrochloric acid (2 N, 10 ml), and extracted with ether (3 × 100 ml). The organic phases were dried (Na2SO4), the solvents evaporated, and the crude product subjected to chromatography (silica gel, hexane/ethyl acetate mixtures).
With triethanolamine; palladium diacetate at 100℃; for 24h; Inert atmosphere;
  • 4
  • [ 64339-43-1 ]
  • [ 2628-17-3 ]
  • [ 501-36-0 ]
YieldReaction ConditionsOperation in experiment
41.4% With triethanolamine; palladium diacetate at 100℃; for 24h; Inert atmosphere; 5.1.2. General procedure for the Mizoroki-Heck reactions General procedure: A mixture of the styrene (3 mmol), the halogenated benzene (3 mmol), triethanolamine (3 mmol) and Pd(II) acetate (0.03 g) was stirred under argon at 100 °C for 24 h. The reaction was cooled to 25 °C, quenched by the addition of dil. aq. hydrochloric acid (2 N, 10 ml), and extracted with ether (3 × 100 ml). The organic phases were dried (Na2SO4), the solvents evaporated, and the crude product subjected to chromatography (silica gel, hexane/ethyl acetate mixtures).
41.4% With triethanolamine; palladium diacetate at 100℃; for 24h; Inert atmosphere; stereoselective reaction; 4.2. General procedure for the Mizoroki-Heck reactions General procedure: A mixture of the styrene (3 mmol), the halogenated benzene (3 mmol), triethanolamine (3 mmol) and Pd (II) acetate (0.03 g) was stirred under argon at 100 °C for 24 h. The reaction was cooled to 25 °C, quenched by the addition of dil. aq. hydrochloric acid (2 N, 10 ml), and extracted with ether (3 × 100 ml). The organic phases were dried (Na2SO4), the solvents evaporated, and the crude product was subjected to chromatography (silica gel, hexane/ethyl acetate mixtures).
With triethanolamine; palladium diacetate at 100℃; for 24h; Inert atmosphere;
  • 5
  • [ 7188-38-7 ]
  • [ 64339-43-1 ]
  • [ 19179-36-3 ]
YieldReaction ConditionsOperation in experiment
96% With copper (II) trifluoroacetate hydrate; palladium diacetate In dimethyl sulfoxide at 130℃; for 6h; Sealed tube; Inert atmosphere; 28 General procedure for the synthesis of aryl nitriles 1b-28b General procedure: Aryl iodide (0.7 mmol, 1 equiv), tert-butyl isocyanide (2.1 mmol, 237 μL, 3 equiv), Pd(OAc)2 (0.035 mmol, 8 mg, 5 mol %), Cu(TFA)2*xH2O (1.4 mmol, 405 mg, 2 equiv) and DMSO (2.5 mL) were added to a 15 mL sealed tube, and stirred at 130 °C for 4-12 h under nitrogen. After completion of the reaction indicated by TLC, the mixture was extracted with Et2O (510 mL). The combined organic phases was dried over Na2SO4, and concentrated under vacuum. Then the residue was purified by column chromatography on silica gel using petroleum ether (30-60 °C)/Et2O as eluant to provide the pure target product.
  • 6
  • [ 6318-56-5 ]
  • [ 64339-43-1 ]
  • 7
  • [ 64339-43-1 ]
  • [ 23031-25-6 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: ammonium acetate; tetrakis(triphenylphosphine) palladium(0) / acetonitrile / 80 °C / Inert atmosphere 2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / 1,4-dioxane; water / 100 °C / Inert atmosphere 3: potassium <i>tert</i>-butylate / toluene / 110 °C
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