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Chemical Structure| 64584-92-5 Chemical Structure| 64584-92-5

Structure of 64584-92-5

Chemical Structure| 64584-92-5

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Product Details of [ 64584-92-5 ]

CAS No. :64584-92-5
Formula : C5H10O
M.W : 86.13
SMILES Code : C[C@@H](O)CC=C
MDL No. :MFCD03701536
InChI Key :ZHZCYWWNFQUZOR-RXMQYKEDSA-N
Pubchem ID :6999724

Safety of [ 64584-92-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225
Precautionary Statements:P501-P240-P210-P233-P243-P241-P242-P280-P370+P378-P303+P361+P353-P403+P235
Class:3
UN#:1987
Packing Group:

Application In Synthesis of [ 64584-92-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 64584-92-5 ]

[ 64584-92-5 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 64584-92-5 ]
  • [ 17924-92-4 ]
  • 2
  • [ 64584-92-5 ]
  • [ 13659-23-9 ]
  • [ 1567219-26-4 ]
YieldReaction ConditionsOperation in experiment
92% With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 20h; To a solution of <strong>[13659-23-9]2-bromo-5-chlorophenol</strong> (0.40 g, 1.93 mmol, 1 equiv), (R)-pent-4-en-2-ol (0.397 mL, 3.86 mmol, 2 equiv), and PPh3 (1.01 g, 3.86 mmol, 2 equiv) in THF (6.4 mL) wasadded DEAD (0.61 mL, 3.86 mmol, 2 equiv). After stirring 20 h, reaction diluted with ether and washed with 1 N NaOH. The ether layer was dried (MgSO4) and concentrated in vacuo. The crude product was purified by flash column chromatography (0-10% EtOAc in hexane) to provide the product as a colorless oil (0.49 g, 92%). 1H NMR (400 MHz, CDC13) oe 7.45 (d, J= 8.3 Hz, 1H), 6.89 (d, J=2.3 Hz, 1H), 6.83 (dd, J= 8.5, 2.3 Hz, 1H), 5.90 (ddt, J= 17.1, 10.1, 7.2 Hz, 1H),5.21 - 5.11 (m, 2H), 4.49 - 4.39 (m, 1H), 2.60 - 2.50 (m, 1H), 2.48 - 2.38 (m, 1H),1.37 (d, J= 6.3 Hz, 3H).
 

Historical Records

Similar Product of
[ 64584-92-5 ]

Chemical Structure| 55563-79-6

A742183 [55563-79-6]

(S)-Pent-4-en-2-ol

Reason: Optical isomers