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Chemical Structure| 6468-98-0 Chemical Structure| 6468-98-0

Structure of 6468-98-0

Chemical Structure| 6468-98-0

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Product Details of [ 6468-98-0 ]

CAS No. :6468-98-0
Formula : C15H10O3
M.W : 238.24
SMILES Code : O=C1C(C2=CC=C(O)C=C2)=CC3=C(O1)C=CC=C3

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Application In Synthesis of [ 6468-98-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 6468-98-0 ]

[ 6468-98-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 6468-98-0 ]
  • [ 83883-26-5 ]
  • C31H28O7 [ No CAS ]
YieldReaction ConditionsOperation in experiment
72.2% (0326) A 300 ml four-neck flask was charged with mesyl chloride (0.28 g, 0.002 mol) and THF (4.1 g), and the mixture was cooled to ?30° C. in a nitrogen atmosphere. A solution of TEA (0.24 g, 0.0024 mol) and 4-(6-acryloxy-hex-1-yloxy)benzoic acid (0.56 g, 0.002 mol) in THF (4.1 g) was added dropwise to the mixture and stirred at 0° C. for 2 hours. After a solution of TEA (0.24 g, 0.0024 mol) and DMAP (0.002 g) in THF (4.1 g) was further added to the mixture, intermediate 5 (0.48 g, 0.002 mol) obtained in step 2 was added to the mixture. The mixture was returned to room temperature and stirred overnight. The organic layer was extracted. After the solvent was removed by distillation, the residue was separated by silica gel column chromatography (eluent: chloroform). The separated product was crystallized from a chloroform/methanol system and dried under reduced pressure at room temperature to give 0.74 g of the desired product, compound B-169 (72.2percent yield).
 

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