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Chemical Structure| 6600-42-6 Chemical Structure| 6600-42-6

Structure of 6600-42-6

Chemical Structure| 6600-42-6

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Product Details of [ 6600-42-6 ]

CAS No. :6600-42-6
Formula : C12H18
M.W : 162.27
SMILES Code : C=CC12CC3CC(C2)CC(C3)C1
MDL No. :N/A

Safety of [ 6600-42-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H227
Precautionary Statements:P210-P264-P270-P280-P301+P312-P330-P370+P378-P403+P235-P501

Application In Synthesis of [ 6600-42-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 6600-42-6 ]

[ 6600-42-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 6600-42-6 ]
  • [ 66137-74-4 ]
  • C16H18F9IO3S [ No CAS ]
YieldReaction ConditionsOperation in experiment
88.3% To a 100 mL flask was charged vinyl admantane (5 g, 30.8 mmol), ICF2CF2OCF2CF2SO2F (16.41 g, 38.5 mmol), 12 mL of water and 24 mL of ACN. The mixture was stirred under nitrogen for 10 min. To the mixture was added a mixture of NaHC03 (1.59 g, 18.5 mmol) and a mixture of sodium bisulfite and sodium metabisulfite (2.15 g). The reaction temperature increased to 36C in 10 min. The temperature dropped to 26C in 20 min. The mixture was then heated to 40C and kept at the same temperature for 2 h. The mixture was cooled down to rt. Filtration and washing with DI water afforded 16.0 g (yield: 88.3%) of compound 1-1 under air drying. 1H NMR (300 MHz, CDCI3) d: 3.91 (dd, 1H), 2.95 (m, 1H), 2.65 (m, 1H), 1.95 (br s, 3H), 1.40-1.70 (m, 12H). 13C NMR (75 MHz, CDCI3) d: 40.2, 37.1, 36.9, 36.5, 36.2, 28.5.
 

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