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Chemical Structure| 67851-11-0 Chemical Structure| 67851-11-0

Structure of 67851-11-0

Chemical Structure| 67851-11-0

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Product Details of [ 67851-11-0 ]

CAS No. :67851-11-0
Formula : C14H11F3O2
M.W : 268.23
SMILES Code : OC(C1=CC=CC(OC2=CC=CC=C2)=C1)C(F)(F)F
MDL No. :MFCD00729043

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Application In Synthesis of [ 67851-11-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 67851-11-0 ]

[ 67851-11-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 51631-50-6 ]
  • [ 67851-11-0 ]
  • α-trifluoromethyl-3-phenoxybenzyl 2-(4-chlorophenyl)-3-methylbutanoate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With pyridine; In toluene; EXAMPLE V PREPARATION OF α-TRIFLUOROMETHYL-3-PHENOXYBENZYL 2-(4-CHLOROPHENYL)-3-METHYLBUTANOATE This compound was prepared in the manner of Example II, using 5.3 g of 2-(4-chlorophenyl)-3-methylbutanoyl chloride, whose preparation is described in Agr. Biol. Chem., 38, 881 (1974), together with J. Kagaku To Seibutsu, 14, 427 (1976), 4.6 g of α-trifluoromethyl-3-phenoxybenzyl alcohol, and 1.5 g of pyridine in 50 ml of toluene. Volatiles were removed from the crude reaction product at 100 C./0.02 mm through a short path Kugelrohr distillation system to give as a residue 7.8 g of α-trifluoromethyl-3-phenoxybenzyl 2-(4-chlorophenyl)-3-methylbutanoate. The ir spectrum was consistent with the assigned structure. Analysis: Calc'd for C25 H22 ClF3 O3: C, 64.87; H, 4.79; L Cl, 7.66. Found: C, 65.07; H, 4.91; Cl, 8.20. nmrδppm (CDCl3): 0.60-1.10 (m, 6H), 2.10-2.60 (m, 1H), 3.30 (d, 1H), 5.90-6.30 (q, 1H), 6.90-7.40 (m, 13H).
 

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