Home Cart Sign in  
Chemical Structure| 69212-31-3 Chemical Structure| 69212-31-3

Structure of 69212-31-3

Chemical Structure| 69212-31-3

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 69212-31-3 ]

CAS No. :69212-31-3
Formula : C12H10N2O2S
M.W : 246.29
SMILES Code : O=[N+](C1=CC=CN=C1SCC2=CC=CC=C2)[O-]
MDL No. :MFCD00209547
InChI Key :CRGAGHBQCBIQPJ-UHFFFAOYSA-N
Pubchem ID :507300

Safety of [ 69212-31-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 69212-31-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 69212-31-3 ]

[ 69212-31-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 38240-29-8 ]
  • [ 100-39-0 ]
  • [ 69212-31-3 ]
YieldReaction ConditionsOperation in experiment
91% With potassium carbonate; In N,N-dimethyl-formamide; at 20℃; for 2.0h; Intermediate 6 2-(benzylthio)-3-nitropyridine [0133] <strong>[38240-29-8]3-nitropyridine-2-thiol</strong> (0.50 g, 3.2 mmol) in DMF (4 ml) was added benzyl bromide (0.38 ml, 3.2 mmol) and K2CO3 (0.89 g, 6.4 mmol). The mixture was stirred at room temperature for 2 hours, diluted with H2O, extracted with EtOAc. The organic layer was washed with brine, dried over Na2SO4, and concentrated in vacuo. The crude product was purified by recrystallization from MeOH and minimal amount of CH2Cl2 to yield the title compound (0.72 g, 91%). [0135] 1H NMR (CDCl3) delta: 8.72 (dd, J=4.5, 1.6 Hz, 1H), 8.49 (dd, J=8.2, 1.8 Hz, 1H), 7.43 (d, J=7.3 Hz, 2H), 7.20-7.34 (m, 4H), 4.48 (s, 2H).
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 69212-31-3 ]

Sulfides

Chemical Structure| 88753-54-2

A174774 [88753-54-2]

3-Nitro-2-(propylthio)pyridine

Similarity: 0.89

Chemical Structure| 22746-79-8

A620555 [22746-79-8]

2-(Methylthio)-3-nitropyridine

Similarity: 0.86

Chemical Structure| 107756-05-8

A789476 [107756-05-8]

2-(Ethylthio)-5-nitropyridine

Similarity: 0.84

Chemical Structure| 92741-41-8

A657223 [92741-41-8]

6-(Ethylthio)-5-nitropyridin-2-amine

Similarity: 0.83

Chemical Structure| 4262-11-7

A567802 [4262-11-7]

3-Nitro-2-(pyridin-2-ylthio)pyridine

Similarity: 0.82

Nitroes

Chemical Structure| 88753-54-2

A174774 [88753-54-2]

3-Nitro-2-(propylthio)pyridine

Similarity: 0.89

Chemical Structure| 22746-79-8

A620555 [22746-79-8]

2-(Methylthio)-3-nitropyridine

Similarity: 0.86

Chemical Structure| 107756-05-8

A789476 [107756-05-8]

2-(Ethylthio)-5-nitropyridine

Similarity: 0.84

Chemical Structure| 92741-41-8

A657223 [92741-41-8]

6-(Ethylthio)-5-nitropyridin-2-amine

Similarity: 0.83

Chemical Structure| 4262-11-7

A567802 [4262-11-7]

3-Nitro-2-(pyridin-2-ylthio)pyridine

Similarity: 0.82

Related Parent Nucleus of
[ 69212-31-3 ]

Pyridines

Chemical Structure| 88753-54-2

A174774 [88753-54-2]

3-Nitro-2-(propylthio)pyridine

Similarity: 0.89

Chemical Structure| 22746-79-8

A620555 [22746-79-8]

2-(Methylthio)-3-nitropyridine

Similarity: 0.86

Chemical Structure| 107756-05-8

A789476 [107756-05-8]

2-(Ethylthio)-5-nitropyridine

Similarity: 0.84

Chemical Structure| 92741-41-8

A657223 [92741-41-8]

6-(Ethylthio)-5-nitropyridin-2-amine

Similarity: 0.83

Chemical Structure| 4262-11-7

A567802 [4262-11-7]

3-Nitro-2-(pyridin-2-ylthio)pyridine

Similarity: 0.82