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Chemical Structure| 6926-45-0 Chemical Structure| 6926-45-0

Structure of 6926-45-0

Chemical Structure| 6926-45-0

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Product Details of [ 6926-45-0 ]

CAS No. :6926-45-0
Formula : C6H13N3
M.W : 127.19
SMILES Code : CCCCCCN=[N+]=[N-]
MDL No. :MFCD01723468

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Application In Synthesis of [ 6926-45-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 6926-45-0 ]

[ 6926-45-0 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 3839-35-8 ]
  • [ 6926-45-0 ]
  • 2
  • [ 6926-45-0 ]
  • [ 89635-82-5 ]
  • [ 1357845-49-8 ]
YieldReaction ConditionsOperation in experiment
73% With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In dimethyl sulfoxide; at 70℃; for 2h;Microwave irradiation; General procedure: Non-fluorous triazolyl triethyleneglycol ethers 27 and 28 were synthesized under modified Meldal-Sharpless conditions from 1-azidohexane and 1-azidooctane, respectively, by treatment in equimolar amounts with methoxy(triethyleneoxy)propyne (3.00 mmol), CuSO4·5H2O (0.15 mmol) and sodium ascorbate (0.30 mmol) in DMSO (1.0 cm3) under microwave irradiation at 70 C and 150 W power for 2 h, followed by chromatography on silica gel.Triazole 27 an oil (73% yield). 1H NMR (300 MHz; CDCl3) δ: 0.87 (t, 3H), 1.31 (m, 6H), 1.92 (m, 2H), 3.37 (s, 3H), 3.65 (m, 2H), 3.60-3.72 (m, 10H), 4.34 (t, 2H), 4.71 (s, 2H), 7.62 (s, 1H). ESI-MS found m/z: 352.2197 (15%), calcd for [M+Na]+m/z: 352.2214; found m/z: 331.2407 (18) calcd for [M+2H]+m/z: 331.2472; found m/z: 330.2378 (100) calcd for [M+H]+m/z: 330.2394.
 

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