Alternatived Products of [ 69698-09-5 ]
Product Details of [ 69698-09-5 ]
CAS No. : | 69698-09-5 |
MDL No. : | |
Formula : |
C9H12N2
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
148.21
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 69698-09-5 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 69698-09-5 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 69698-09-5 ]
- Downstream synthetic route of [ 69698-09-5 ]
- 1
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[ 123-75-1 ]
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[ 626-60-8 ]
-
[ 69698-09-5 ]
Yield | Reaction Conditions | Operation in experiment |
91% |
With sodium hydride; 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride; <i>tert</i>-butyl alcohol In tetrahydrofuran at 65℃; for 2.5h; |
|
90% |
With C48H56ClN3Pd; potassium <i>tert</i>-butylate In tetrahydrofuran at 70℃; for 24h; Schlenk technique; Inert atmosphere; |
|
89% |
With polymethylhydrosiloxane; sodium t-butanolate In 1,2-dimethoxyethane; toluene at 130℃; for 18h; |
|
72% |
With 1,4-diaza-bicyclo[2.2.2]octane; nickel(II) bromide dimethoxyethane; tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate In dimethyl sulfoxide at 80℃; for 0.5h; Flow reactor; Sealed tube; Schlenk technique; Inert atmosphere; Irradiation; |
|
10% |
at 100℃; for 96h; |
|
Reference:
[1]Gradel, Benot; Brenner, Eric; Schneider, Raphaël; Fort, Yves
[Tetrahedron Letters, 2001, vol. 42, # 33, p. 5689 - 5692]
[2]Deng, Qinyue; Zhang, Yang; Zhu, Haibo; Tu, Tao
[Chemistry - An Asian Journal, 2017, vol. 12, # 18, p. 2364 - 2368]
[3]Manolikakes, Georg; Gavryushin, Andrei; Knochel, Paul
[Journal of Organic Chemistry, 2008, vol. 73, # 4, p. 1429 - 1434]
[4]Park, Boyoung Y.; Pirnot, Michael T.; Buchwald, Stephen L.
[Journal of Organic Chemistry, 2020, vol. 85, # 5, p. 3234 - 3244]
[5]Hashimoto, Shiro; Otani, Shinichi; Okamoto, Tadashi; Matsumoto, Kiyoshi
[Heterocycles, 1988, vol. 27, # 2, p. 319 - 322]
- 2
-
[ 123-75-1 ]
-
[ 626-55-1 ]
-
[ 69698-09-5 ]
-
[ 2456-81-7 ]
- 3
-
[ 123-75-1 ]
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[ 7295-76-3 ]
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[ 69698-09-5 ]
Yield | Reaction Conditions | Operation in experiment |
90% |
With sodium hydride; lithium iodide In tetrahydrofuran at 0 - 60℃; for 4h; Inert atmosphere; Sealed tube; |
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