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Chemical Structure| 70254-75-0 Chemical Structure| 70254-75-0

Structure of 70254-75-0

Chemical Structure| 70254-75-0

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Product Details of [ 70254-75-0 ]

CAS No. :70254-75-0
Formula : C8H10N2O2
M.W : 166.18
SMILES Code : O=[N+](C1=C(C)C=CC=C1NC)[O-]
MDL No. :MFCD29104028

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Application In Synthesis of [ 70254-75-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 70254-75-0 ]

[ 70254-75-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 70254-75-0 ]
  • [ 73902-64-4 ]
YieldReaction ConditionsOperation in experiment
82% With palladium 10% on activated carbon; hydrogen; at 20.0℃; To a solution of N,3-dimethyl-2-nitroaniline (160mg, 0.96mmol) in MeOH (lOmL), 10% Pd-C (160 mg) was added . The reaction mixture was stirred at rt under H2 balloon atmosphere for 2 h. TLC showed the reaction to be complete and filtered through a celite bed and washed with MeOH (5OmL). The filtrate was evaporated under vacuum to afford N1,3-dimethylbenzene-1,2-diamine as a red liquid. Yield:100mg (82%); 1H NMR (400 MHz; DMSO-d6): 6.70-6.81 (m, 1H), 6.58-6.66 (m, 2H), 2.87 (5, 3H), 2.21 (5, 3H); MS (ESl+) for CHNOS m/z 137.01 [M+H].
 

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