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CAS No. : | 75449-26-2 | MDL No. : | MFCD00137932 |
Formula : | C10H10N4 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | LSSHHQCMLSBUMT-UHFFFAOYSA-N |
M.W : | 186.21 | Pubchem ID : | 3577122 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362 | UN#: | |
Hazard Statements: | H315-H319 | Packing Group: | |
GHS Pictogram: |
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* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | In ethanol 1) 4 h, room temperature, 2) 1 h, reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
30% | With isopentyl nitrite In benzene for 12h; Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
62% | With triethylamine In diethyl ether for 2h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | In toluene at 80℃; for 0.5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
73% | With triethylamine In diethyl ether for 2h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
87% | In toluene at 80℃; for 2h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | With triethylamine In diethyl ether for 2h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68% | With triethylamine In diethyl ether for 2h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
72% | With triethylamine In diethyl ether for 3h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
38% | With triethylamine In dichloromethane for 4h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | In dichloromethane at 30 - 40℃; for 4h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | In tetrahydrofuran for 18h; Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
58% | With TEA In diethyl ether for 4h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
66% | With TEA In diethyl ether for 16h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
74% | With TEA In tetrahydrofuran for 16h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
77% | In ethanol for 1h; Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
87% | In ethanol for 1h; Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
90% | In ethanol for 3h; Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
96% | In ethanol for 2h; Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
100% | With palladium 10% on activated carbon; hydrogen In ethanol at 25℃; for 16h; | |
95% | With palladium 10% on activated carbon; hydrogen In ethanol at 20℃; for 8h; | |
95% | With palladium 10% on activated carbon; hydrogen In ethanol at 20℃; for 8h; |
95% | With palladium 10% on activated carbon; hydrogen In ethanol at 20℃; | |
95% | With hydrogen; palladium In ethanol at 20℃; | |
88% | With hydrogenchloride; tin In water at 120℃; for 1.5h; Cooling; Inert atmosphere; | 10.b To a solution of 700 ml of hydrochloric acid (37%) in 800 ml of ice water are added 72 g (0.292 mol) of 3,3'-dinitro-2,2'-bipyridine and 249.0 g (2.029 mol) of Sn powder (exothermic, wait until cooled down). The green suspension is slowly heated to 120°C under nitrogen. After 1.5 hours TLC (CH2CI2) analysis showes that all starting material has been consumed. The reaction mixture is cooled to room temperature and filtered. The residue is suspended in 1000 ml of water : ethyl acetate 1 :1 , then 400 ml of NaOH (2N) are added (pH = 10). To the thick green-yellow mixture are added 250 ml of ethyl acetate, then the mixture is stirred for 30 minutes. After filtration (slow) the filtrate is stored during the weekend and shows after that time a nice phase separation. The phases are separated and the water phase is extracted 3 times with 250 ml of ethyl acetate each. The organic phase is washed with 250 ml of a puffer solution of pH 7 and 250 ml of brine, dried over Na2S04, filtered and evaporated to yield 51.7 g (88 %) of yellow crystals of 3,3'-diamino-2,2'- bipyridine. (0552) 1H NMR (400 MHz, CDCb): δ 7.98 (dxd,Ji=3.6Hz,J2=2.0Hz,2H); 7.06-7.01 (m,4H); 6.28 ( |
86% | With hydrogenchloride; tin(ll) chloride In water for 0.5h; Heating; | |
47% | With hydrogenchloride; tin(ll) chloride In ethanol Ambient temperature; | |
With hydrogenchloride; tin(ll) chloride In water for 0.5h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
78% | With triethylamine In dichloromethane at 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
95.2% | With hydrogenchloride In water for 0.5h; Heating; | |
1.7 g | With hydrogenchloride In water for 1h; Reflux; Inert atmosphere; Schlenk technique; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
48% | With triethylamine In dichloromethane at 20℃; for 4h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4 A molecular sieve In toluene | ||
In toluene for 120h; Reflux; Dean-Stark; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1: 76.6 percent / activated copper bronze / dimethylformamide / 4 h / 110 °C 2: 95.2 percent / HCl / H2O / 0.5 h / Heating | ||
Multi-step reaction with 3 steps 1: 48 h / Inert atmosphere; Schlenk technique 2: copper / N,N-dimethyl-formamide / 3 h / 130 °C / Inert atmosphere; Schlenk technique 3: hydrogenchloride / water / 1 h / Reflux; Inert atmosphere; Schlenk technique |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 76.6 percent / activated copper bronze / dimethylformamide / 4 h / 110 °C 2: 95.2 percent / HCl / H2O / 0.5 h / Heating | ||
Multi-step reaction with 2 steps 1: copper / N,N-dimethyl-formamide / 3 h / 130 °C / Inert atmosphere; Schlenk technique 2: hydrogenchloride / water / 1 h / Reflux; Inert atmosphere; Schlenk technique |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 83 percent / copper / dimethylformamide / 2 h / 150 °C 2: 47 percent / SnCl2*2H2O, conc. HCl / ethanol / Ambient temperature | ||
Multi-step reaction with 2 steps 1: copper / N,N-dimethyl-formamide / 0.75 h / 150 °C / Inert atmosphere 2: palladium 10% on activated carbon; hydrogen / ethanol / 8 h / 20 °C / 760.05 Torr | ||
Multi-step reaction with 2 steps 1: copper / N,N-dimethyl-formamide / 110 °C / Inert atmosphere 2: tin(ll) chloride; hydrogenchloride / water / 0.5 h / Inert atmosphere |
Multi-step reaction with 2 steps 1: copper / N,N-dimethyl-formamide / 2 h / 150 °C / Inert atmosphere 2: palladium 10% on activated carbon; hydrogen / ethanol / 16 h / 25 °C / 775.74 Torr |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1: 70 percent / tetrahydrofuran / 18 h / Heating 2: 83 percent / TEA / tetrahydrofuran / 18 h / Ambient temperature 3: 99 percent / TFA / CH2Cl2 / 18 h / Ambient temperature |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 70 percent / tetrahydrofuran / 18 h / Heating 2: 83 percent / TEA / tetrahydrofuran / 18 h / Ambient temperature |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 4 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 1) NaH (80percent) / 1) DMF, 120-130 deg C, 30 min, 2) DMF, 100 deg C, 30 min 3: 99 percent / KOH, TBAB / dimethylsulfoxide / 3 h / 100 °C 4: 97 percent / 10percent HCl / 4 h / Heating | ||
Multi-step reaction with 3 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 75 percent / KOH, TBAB / dimethylsulfoxide / 100 - 110 °C 3: 97 percent / 10percent HCl / 4 h / Heating | ||
Multi-step reaction with 4 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 26 percent / KOH, TBAB / dimethylsulfoxide / 10 h / 100 - 110 °C 3: 25 percent / KOH, TBAB / dimethylsulfoxide / 2 h / 100 - 110 °C 4: 97 percent / 10percent HCl / 4 h / Heating |
Multi-step reaction with 4 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 75 percent / acetic acid / 1 h / Heating 3: 25 percent / KOH, TBAB / dimethylsulfoxide / 2 h / 100 - 110 °C 4: 97 percent / 10percent HCl / 4 h / Heating |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 1) NaH (80percent) / 1) DMF, 120-130 deg C, 30 min, 2) DMF, 100 deg C, 30 min 3: 99 percent / KOH, TBAB / dimethylsulfoxide / 3 h / 100 °C | ||
Multi-step reaction with 2 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 75 percent / KOH, TBAB / dimethylsulfoxide / 100 - 110 °C | ||
Multi-step reaction with 3 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 26 percent / KOH, TBAB / dimethylsulfoxide / 10 h / 100 - 110 °C 3: 25 percent / KOH, TBAB / dimethylsulfoxide / 2 h / 100 - 110 °C |
Multi-step reaction with 3 steps 1: 85 percent / ethanol / 1) 4 h, room temperature, 2) 1 h, reflux 2: 75 percent / acetic acid / 1 h / Heating 3: 25 percent / KOH, TBAB / dimethylsulfoxide / 2 h / 100 - 110 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | In acetonitrile 1 equiv. of N-base and Cu-compd. were stirred in MeCN overnight; ppt. was filtered off, dried and recrystd. from water, elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
93% | In acetonitrile 1. equiv. of N-base and Cu-compd. were stirred in MeCN overnight; ppt. was filtered off, dried and recrystd. from aq. EtOH, elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
82% | In acetonitrile 1 equiv. of N-base and Mn-compd. were stirred in MeCN overnight; elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
98% | In acetonitrile 3 equiv. of N-base and Ni-compd. were stirred in MeCN overnight; ppt. was filtered off, dried and recrystd. from water, elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
91% | In acetonitrile 3 equiv. of N-base and Zn-compd. were stirred in MeCN overnight; ppt. was filtered off, dried in vac. and recrystd. from water, elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | In acetonitrile 3 equiv. of N-base and Co-compd. were stirred in MeCN overnight; ppt. was filtered off, dried and recrystd. from water, elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
73% | In acetonitrile 1 equiv. of N-base and Mn-compd. were stirred in MeCN overnight; elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86% | In acetonitrile 1 equiv. of N-base and Zn-compd. were stirred in MeCN overnight; ppt. was centrifuged and dried in vac., elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
78% | In tetrahydrofuran Inert atmosphere; Reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
69% | In tetrahydrofuran for 36h; Inert atmosphere; Reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
62% | With triethylamine In dichloromethane at 5℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
73% | In ethanol at 20 - 35℃; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With triethylamine In diethyl ether at 0 - 20℃; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
72% | In methanol for 10h; Reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1.34 g | With triethylamine In dichloromethane at 5℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
73% | With triethylamine In dichloromethane at 0 - 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | With triethylamine In dichloromethane at 0 - 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
20% | Stage #1: 2,2'-bipyridine-3,3'-diamine With sulfuric acid; sodium nitrite In acetic acid at 20℃; for 1h; Cooling with ice; Stage #2: With hydrogenchloride; copper(l) chloride In water; acetic acid at 0 - 70℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
10% | Stage #1: 2,2'-bipyridine-3,3'-diamine With sulfuric acid; sodium nitrite In acetic acid at 20℃; for 1h; Cooling with ice; Stage #2: With hydrogenchloride; copper(I) bromide In water; acetic acid at 0 - 70℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
9% | Stage #1: 2,2'-bipyridine-3,3'-diamine With n-butyllithium In tetrahydrofuran; hexane at -78℃; Stage #2: 1,8-bis(p-toluenesulfonyloxy)-3,6-bis(p-toluenesulfonyl)-3,6-diazaoctane In tetrahydrofuran; hexane at 20℃; for 3h; Reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
61% | With triethylamine In dichloromethane at 0 - 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; | |
80% | With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 2h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
60% | With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane for 0.5h; | |
60% | With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
54% | In methanol; toluene for 6h; Reflux; | |
48% | In dichloromethane for 18h; Reflux; Darkness; | |
42% | In chloroform for 8h; Reflux; | Synthesis of 1 A suspension of 3,3′-diamino-2,2′-bipyridine (0.10 g,0.54 mmol) and pentacarbonylchlororhenium(I) (0.19 g,0.54 mmol) was allowed to reflux in chloroform (20 mL)for 8 h. After which time the solution was cooled and filteredto give (1) as a pale yellow solid (0.11 g, 42%).17 1HNMR (500 MHz, (CD3)2SO) δH 8.38 (dd, J = 5.0, 1.2 Hz,2H, py), 7.58 (dd, J = 8.5, 1.2 Hz, 2H, py), 7.40 (dd, J = 8.5,5.0 Hz, 2H, py), 6.19 (s, 4H, NH2); 13C (240 MHz,(CD3)2SO) 199.10 (C=O), 191.99 (C=O), 144.0 (py, quaternary),142.35 (py, CH), 139.96, (py, quaternary), 128.30(py, CH), 125.81 (py CH); IR (ATR, νCO) 2017, 1910 and1863 cm-1; ESI-MS: m/z 457 [M-Cl]+. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
65% | With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.5h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
92% | Stage #1: 2-Picolinic acid; 2,2'-bipyridine-3,3'-diamine In pyridine at 45℃; for 0.75h; Inert atmosphere; Stage #2: With triphenyl phosphite at 95℃; for 4h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
73% | Stage #1: 2,2'-bipyridine-3,3'-diamine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: 1-bromo-butane In tetrahydrofuran; hexane at 35℃; for 4h; Inert atmosphere; | |
3.5 g | Stage #1: 2,2'-bipyridine-3,3'-diamine With n-butyllithium In tetrahydrofuran at -78℃; for 2h; Inert atmosphere; Stage #2: 1-bromo-butane at 65℃; for 24h; Reflux; | Compound 2 synthetic (R1 =- C4 H9 ): Under the protection of argon, will 2g compound 1 dissolved in tetrahydrofuran, and cooling to the -78 °C, slowly dropping 2.2 times equivalent n-BuLi, in this temperature 2 hours and adding 3 times equivalent Br - C4 H9 , Gradually raising the temperature to 65 °C reflux 24 hours. The restoration of the room temperature, evaporating solvent, column chromatography (methylene chloride: hexane as the mobile phase) purification 3.5g compound 2. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
50% | With triethylamine In dichloromethane Cooling with ice; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
77% | With triethylamine In dichloromethane at 0 - 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
88% | In methanol Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
81% | Stage #1: para-chlorobenzoic acid With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 0 - 5℃; for 0.0833333h; Stage #2: 2,2'-bipyridine-3,3'-diamine In N,N-dimethyl-formamide at 20℃; Cooling with ice; | 1 Synthesis of N,N'-[(2,2'-bipyridyl)-3,3'-diyl]bis(4-chlorobenzamide) (Compound 3a) 0.20 g of 4-chlorobenzoic acid, 0.14 mL of N,N-diisopropylethylamine (DIEA) was added to a round bottom containing 8 mL of DMF.The flask was stirred to completely dissolve the solid and cooled to 0 to 5 ° C with an ice bath.After adding 0.21 g of 2-(7-oxobenzotriazole)-N,N,N',N'-tetramethyluronium hexafluorophosphate (HATU),Stir for 5min,Further, 0.10 g of 3,3'-diamino-2,2'-bipyridine was added, and the mixture was stirred for 10 minutes in an ice bath, and then naturally heated to room temperature for reaction.TLC was traced, and after the reaction was completed, the reaction liquid was poured into 20 mL of ice water, stirred, and a pale yellow solid was precipitated. The solid was suction filtered, washed with water and dried. The crude product was purified by silica gel chromatography.A pale yellow powder 3a was obtained in a yield of 81%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
58% | Stage #1: 2,2'-bipyridine-3,3'-diamine With tetrafluoroboric acid; sodium nitrite In water at -10℃; for 0.5h; Stage #2: With potassium iodide In water; acetone at 25℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
84% | Stage #1: 2,2'-bipyridine-3,3'-diamine With sodium hydride In tetrahydrofuran at 70℃; for 2h; Inert atmosphere; Stage #2: 3-(iodomethyl)heptane In tetrahydrofuran at 70℃; for 36h; Inert atmosphere; |
Tags: 75449-26-2 synthesis path| 75449-26-2 SDS| 75449-26-2 COA| 75449-26-2 purity| 75449-26-2 application| 75449-26-2 NMR| 75449-26-2 COA| 75449-26-2 structure
Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
P102 | Keep out of reach of children. |
P103 | Read label before use |
Prevention | |
Code | Phrase |
P201 | Obtain special instructions before use. |
P202 | Do not handle until all safety precautions have been read and understood. |
P210 | Keep away from heat/sparks/open flames/hot surfaces. - No smoking. |
P211 | Do not spray on an open flame or other ignition source. |
P220 | Keep/Store away from clothing/combustible materials. |
P221 | Take any precaution to avoid mixing with combustibles |
P222 | Do not allow contact with air. |
P223 | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
P230 | Keep wetted |
P231 | Handle under inert gas. |
P232 | Protect from moisture. |
P233 | Keep container tightly closed. |
P234 | Keep only in original container. |
P235 | Keep cool |
P240 | Ground/bond container and receiving equipment. |
P241 | Use explosion-proof electrical/ventilating/lighting/equipment. |
P242 | Use only non-sparking tools. |
P243 | Take precautionary measures against static discharge. |
P244 | Keep reduction valves free from grease and oil. |
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P260 | Do not breathe dust/fume/gas/mist/vapours/spray. |
P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. |
P262 | Do not get in eyes, on skin, or on clothing. |
P263 | Avoid contact during pregnancy/while nursing. |
P264 | Wash hands thoroughly after handling. |
P265 | Wash skin thouroughly after handling. |
P270 | Do not eat, drink or smoke when using this product. |
P271 | Use only outdoors or in a well-ventilated area. |
P272 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | Avoid release to the environment. |
P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | Use personal protective equipment as required. |
P282 | Wear cold insulating gloves/face shield/eye protection. |
P283 | Wear fire/flame resistant/retardant clothing. |
P284 | Wear respiratory protection. |
P285 | In case of inadequate ventilation wear respiratory protection. |
P231 + P232 | Handle under inert gas. Protect from moisture. |
P235 + P410 | Keep cool. Protect from sunlight. |
Response | |
Code | Phrase |
P301 | IF SWALLOWED: |
P304 | IF INHALED: |
P305 | IF IN EYES: |
P306 | IF ON CLOTHING: |
P307 | IF exposed: |
P308 | IF exposed or concerned: |
P309 | IF exposed or if you feel unwell: |
P310 | Immediately call a POISON CENTER or doctor/physician. |
P311 | Call a POISON CENTER or doctor/physician. |
P312 | Call a POISON CENTER or doctor/physician if you feel unwell. |
P313 | Get medical advice/attention. |
P314 | Get medical advice/attention if you feel unwell. |
P315 | Get immediate medical advice/attention. |
P320 | |
P302 + P352 | IF ON SKIN: wash with plenty of soap and water. |
P321 | |
P322 | |
P330 | Rinse mouth. |
P331 | Do NOT induce vomiting. |
P332 | IF SKIN irritation occurs: |
P333 | If skin irritation or rash occurs: |
P334 | Immerse in cool water/wrap n wet bandages. |
P335 | Brush off loose particles from skin. |
P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | If eye irritation persists: |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
P351 | Rinse cautiously with water for several minutes. |
P352 | Wash with plenty of soap and water. |
P353 | Rinse skin with water/shower. |
P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. |
P361 | Remove/Take off immediately all contaminated clothing. |
P362 | Take off contaminated clothing and wash before reuse. |
P363 | Wash contaminated clothing before reuse. |
P370 | In case of fire: |
P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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