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[ CAS No. 7731-28-4 ] {[proInfo.proName]}

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Chemical Structure| 7731-28-4
Chemical Structure| 7731-28-4
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Product Details of [ 7731-28-4 ]

CAS No. :7731-28-4 MDL No. :MFCD00064170
Formula : C7H14O Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 114.19 Pubchem ID :-
Synonyms :

Safety of [ 7731-28-4 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P280-P305+P351+P338 UN#:N/A
Hazard Statements:H227-H302+H312+H332-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 7731-28-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 7731-28-4 ]

[ 7731-28-4 ] Synthesis Path-Downstream   1~16

  • 1
  • [ 589-92-4 ]
  • [ 7731-29-5 ]
  • [ 7731-28-4 ]
YieldReaction ConditionsOperation in experiment
94% With potassium 9-t-butyl-9-boratabicyclo<3.3.1>nonane In tetrahydrofuran at 0℃; Yield given. Title compound not separated from byproducts;
94% With potassium 9-t-butyl-9-boratabicyclo<3.3.1>nonane In tetrahydrofuran at 0℃; Yields of byproduct given. Title compound not separated from byproducts;
1: 67% 2: 5% With isopropoxydiisobutylaluminum In dichloromethane; toluene at 25℃; for 6h;
1: 23% 2: 42% With ammonium hydroxide; titanium(III) chloride In methanol at 0 - 20℃; for 0.0833333h;
18.5% With potassium hydride In tetrahydrofuran for 0.0833333h; Yield given;
With isopropyl alcohol at 25℃; for 24h; other cyclic ketones, other catalysts, other reaction times, other temperatures; reactivity and stereoselectivity of neutral transition metal polyhydrides in the catalytic transfer hydrogenation;
at 25℃; for 1176h; Aspergillus repens MA0197;
With 9-fluorenyloxy-AlCl2 In diethyl ether for 0.25h; Ambient temperature; other reducing reagents;
With tert-butylmagnesium chloride; bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum In diethyl ether; toluene by variation of the reaction conditions;
With chloro-trimethyl-silane; sodium hydride; zinc(II) chloride In tetrahydrofuran at 45℃; for 0.25h; other reducing agents, rection times, temperatures;
With tri-tert-butoxyaluminum hydride In tetrahydrofuran at 9.9℃; var. temp., ΔG(excit.), ΔH(excit.), ΔS(excit.);
With ZnCRASi (t-amylalcohol, NaH, ZnCl2, Me3SiCl) In tetrahydrofuran at 45℃; for 0.25h; other complex reducing agents;
With ethanol at 25℃;
In ethanol; water at 0 - 45℃; in Tris-HCl buffer at pH 8,5; studied: stereochemistry, effect of substituent chain length and branching; determined: k, EA, ΔH*, ΔS*, ΔG*;
With sodium tetrahydroborate In methanol; dichloromethane at -78℃; Competition with ..(aldehydes 1a, 1b, 1c, 1d).. and ..(enones 4a, 4b, 4c, 4d, 4e, 4f, 4g);
1: 15 % Chromat. 2: 85 % Chromat. With sodium tetrahydroborate; 1,2,4,5-tetramethylbenzene; oxygen In tetrahydrofuran
With isopropoxydiisobutylaluminum In diethyl ether at 25℃; for 3h; stereoselectivity; various periods of time (3-120 h); further ketones;
With 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol In chloroform at 30℃; for 6h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With tert-butylmagnesium chloride; bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum In diethyl ether; hexane; toluene at -23℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With chloro-trimethyl-silane; sodium alkoxide of 2,5 hexanediol; nickel diacetate In tetrahydrofuran at 63℃; for 18h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen In ethanol at 25℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With sodium borohydride-mandelic acid In isopropyl alcohol for 2h; Heating; Yield given;
With polydibenzo-18-crown-6-borohydride In ethanol at 40 - 50℃; for 22h; Yield given. Yields of byproduct given;
With ZnCRASi (t-AmOH, NaH, ZnCl2, Me3SiCl) In tetrahydrofuran at 45℃; for 0.25h; other complex reducing agents; Yield given. Yields of byproduct given;
With methylaluminum bis(2,6-di-tert-butylphenoxide); tert-butylmagnesium chloride In diethyl ether; toluene at -23℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With lithium methyl trihydrido borate In diethyl ether at -78℃; for 2h; Yield given. Yields of byproduct given;
With sodium tetrahydroborate; copper(II) exchange resin In ethanol; water for 4.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With lithium dimethylamino borohydride In tetrahydrofuran at 0℃; for 1h;
With Li(n-Pr)2BH3 In tetrahydrofuran at 0℃; for 0.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With potassium hydroxide; tris(triphenylphosphine)ruthenium(II) chloride; hydrogen; ethylenediamine In isopropyl alcohol at 28℃; for 1h; Title compound not separated from byproducts;
With polymethylhydrosiloxane; tetrabutyl ammonium fluoride 1.) THF, -70 deg C, 30 min, 2.) THF, -70 deg C -> room temperature, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
With thexyl-s-butoxyborane In tetrahydrofuran at 25℃; for 168h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With sodium hydroxide; 1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]trisiloxane; tetrabutyl ammonium fluoride 1.) THF, room t., 2.) THF; Yield given. Multistep reaction. Yields of byproduct given;
With diisobutylaluminium hydride In diethyl ether for 5h; Heating; Yield given. Yields of byproduct given;
With lithium aluminium tetrahydride; (+/-)-threo-1,16-dibenzyloxy-7,8-dihydroxyhexadecane In tetrahydrofuran Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With nickel at 125 - 130℃; Hydrogenation.Reinigung ueber das 4-Benzoyl-Derivat nach Abtrennung durch partielle Acetylierung mit 2-Nitro-benzoylchlorid in Pyridin;
With hydrogenchloride; acetic acid; platinum at 125 - 130℃; Hydrogenation;
With 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol In chloroform at 30℃; for 1h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With chloro-trimethyl-silane; sodium hydride; cadmium(II) chloride In tetrahydrofuran at 63℃; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With LiBH3NC(CH3)2(CH2)3C(CH3)2 In tetrahydrofuran at 0℃; for 1h;
With sodium hydroxide; polymethylhydrosiloxane; N-benzyl-trimethylammonium hydroxide 1.) THF, room t., 2.) THF; Yield given. Multistep reaction;
With manganese(III) (Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate; phenylsilane; oxygen In 1,2-dichloro-ethane; isopropyl alcohol at 23℃; Title compound not separated from byproducts;
With sodium hydroxide; 1,2-(4-H2O3PC6H4)2-N,N'-dimethylethane-1,2-diamine; hydrogen In methanol; water at 50℃; for 21h;
With SBA-15; Zr(OPr); isopropyl alcohol for 0.5h; Heating;
With hydrogenchloride; isopropyl alcohol for 0.266667h; Heating; Title compound not separated from byproducts.;
Stage #1: 1-methylcyclohexan-4-one With Al-trifluoromethanesulfonyldiisobutylalane In diethyl ether at 25℃; for 72h; Inert atmosphere; Stage #2: With hydrogenchloride; water In diethyl ether optical yield given as %de; diastereoselective reaction;
70 % de With potassium hydroxide In isopropyl alcohol at 85℃; for 12h; Catalyst Testing General procedure: In a typical reaction, substrate (10 mmol), Ru/Carbon (100 mg, 0.005 mmol of Ruthenium from ICP analysis), 0.01 g KOH and 100 mmol of 2-propanol were placed in a round bottom flask (batch reactor) fitted with reflux condenser, equipped with a magnetic stirrer and immersed in a thermostatic oil bath for maintaining the desired reaction temperature. The reactions was conducted at the desired temperature and the progress of the reaction was monitored by withdrawing reaction mixture samples periodically, centrifuged and analyzed for their compositions a Agilent gas chromatograph with a capillary column (cross-linked methyl silicone gum, HP1, 50 m × 0.2 mm i.d.) and a flame ionization detector (FID). The product identification was achieved by using standards and GCMS (Agilent).
With methanol; sodium tetrahydroborate at 0℃; for 1h;

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  • [ 29800-89-3 ]
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  • [ 130275-86-4 ]
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  • [ 106-44-5 ]
  • [ 7731-29-5 ]
  • [ 7731-28-4 ]
  • [ 589-92-4 ]
YieldReaction ConditionsOperation in experiment
88.4% With hydrogen In methyl cyclohexane at 80℃; other pressures, samples of Pd/C of the various sodium content;
With hydrogen In isopropyl alcohol at 80℃; for 8h;
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YieldReaction ConditionsOperation in experiment
With {(η5-C5H5)Re(NO)(PPh3)(OCH3)} In (2)H8-toluene at 91℃; for 40h; other catalyst;
  • 5
  • [ 7731-29-5 ]
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YieldReaction ConditionsOperation in experiment
With 2,5-dimethylhexane-1-ol; DMHD-NiCRA-MgBr2 (NaH; nickel diacetate; magnesium bromide In tetrahydrofuran at 63℃; for 28h; Yield given. Yields of byproduct given;
  • 6
  • [ 7731-28-4 ]
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YieldReaction ConditionsOperation in experiment
With 2,5-dimethyl-2,5-hexanediol; nickel diacetate; sodium hydride; magnesium bromide In tetrahydrofuran at 63℃; for 3h; Yield given;
With {(η5-C5H5)Re(NO)(PPh3)(OCH3)} In (2)H8-toluene at 91℃; for 40h; other catalyst;
at 219.9℃; ΔHr0, ΔSr0, ΔGr0;
With potassium <i>tert</i>-butylate In tetrahydrofuran; (2)H8-toluene

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YieldReaction ConditionsOperation in experiment
With (η4-1,5-cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate; hydrogen In dichloromethane Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
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YieldReaction ConditionsOperation in experiment
1: 45% 2: 48% With barium dihydroxide at 60℃; for 1h; ultrasonication;
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  • [ 18349-20-7 ]
  • [ 7731-29-5 ]
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YieldReaction ConditionsOperation in experiment
15% With sodium hydroxide; N,N'-di(4-bromophenyl)-N,N'-dimethylethylenediamine; hydrogen at 50℃; for 21h;
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YieldReaction ConditionsOperation in experiment
With hydrogen In hexane at 22℃; for 3h; Title compound not separated from byproducts;
With hydrogen; N,N-dimethyl-N-cetyl-N-(2-hydroxyethyl)ammonium chloride In lithium hydroxide monohydrate at 20℃; for 1h; Title compound not separated from byproducts.;
With potassium hydroxide; Raney Ni-Al; lithium hydroxide monohydrate at 90℃; for 12h; optical yield given as %de;
36 % de With 10% Rh/C; hydrogen In isopropanol at 100℃; for 0.166667h; Flow reactor; Overall yield = 77 %; Overall yield = 87.9 mg;
With hydrogen In <i>tert</i>-butyl alcohol at 150℃; for 24h; Autoclave; Overall yield = 94 percent;
58 % de With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; borane-ammonia complex In 2,2,2-trifluoroethanol at 20℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; Overall yield = 51 percent;
82 % de With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; hydrogen In n-heptane at 40℃; for 24h; Overall yield = 77 percentChromat.; diastereoselective reaction;
60 % de With 5% Pd/Al2O3; hydrogen In n-heptane at 80℃; for 24h; Overall yield = 90 percentChromat.; diastereoselective reaction;
12 % de With hydrogen In lithium hydroxide monohydrate; isopropanol at 40℃; for 17h; Autoclave; Overall yield = 96 percent; diastereoselective reaction;

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YieldReaction ConditionsOperation in experiment
68% With potassium hydroxide; Raney Ni-Al; water at 90℃; optical yield given as %de;
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YieldReaction ConditionsOperation in experiment
With potassium hydroxide; Raney Ni-Al alloy In water at 90℃; for 5h;
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  • [ 589-92-4 ]
  • [ 583-60-8 ]
  • [ 625-96-7 ]
YieldReaction ConditionsOperation in experiment
Stage #1: methyl cyclohexane With tert.-butylhydroperoxide; (OC2H4)(OHC2H4)NC2H4N(C2H4OH)Cu(thiocyanate) In water; acetonitrile at 70℃; for 2h; Stage #2: With triphenylphosphine In water; acetonitrile regioselective reaction;
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  • [ 583-60-8 ]
  • [ 625-96-7 ]
YieldReaction ConditionsOperation in experiment
Stage #1: methyl cyclohexane With tert.-butylhydroperoxide; (OC2H4)(OHC2H4)NC2H4N(C2H4OH)Cu(thiocyanate) In water; acetonitrile at 70℃; for 7h; Stage #2: With triphenylphosphine In water; acetonitrile regioselective reaction;
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  • [ 2043-61-0 ]
  • [ 591-24-2 ]
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