Alternatived Products of [ 786709-32-8 ]
Product Details of [ 786709-32-8 ]
CAS No. : | 786709-32-8 |
MDL No. : | MFCD18825657 |
Formula : |
C10H15NO3S
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
229.30
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 786709-32-8 ]
Signal Word: | |
Class: | N/A |
Precautionary Statements: | |
UN#: | N/A |
Hazard Statements: | |
Packing Group: | N/A |
Application In Synthesis of [ 786709-32-8 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 786709-32-8 ]
- 1
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[ 35320-23-1 ]
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[ 98-59-9 ]
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[ 786709-32-8 ]
Yield | Reaction Conditions | Operation in experiment |
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With pyridine |
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- 2
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[ 786709-32-8 ]
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[ 177971-32-3 ]
Yield | Reaction Conditions | Operation in experiment |
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With potassium carbonate In acetone |
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- 3
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(Z)-(R)-4-(Toluene-4-sulfonylamino)-pent-2-ene-1-sulfinic acid methyl ester
[ No CAS ]
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[ 786709-32-8 ]
Yield | Reaction Conditions | Operation in experiment |
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Stage #1: (Z)-(R)-4-(Toluene-4-sulfonylamino)-pent-2-ene-1-sulfinic acid methyl ester With ozone In methanol at -78℃; for 0.75h;
Stage #2: With sodium tetrahydroborate In methanol at -78 - 20℃; |
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- 4
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(Z)-(2S,5R)-5-(Toluene-4-sulfonylamino)-hex-3-ene-2-sulfinic acid methyl ester
[ No CAS ]
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[ 786709-32-8 ]
Yield | Reaction Conditions | Operation in experiment |
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Stage #1: (Z)-(2S,5R)-5-(Toluene-4-sulfonylamino)-hex-3-ene-2-sulfinic acid methyl ester With ozone In methanol at -78℃; for 0.75h;
Stage #2: With sodium tetrahydroborate In methanol at -78 - 20℃; |
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- 5
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[ 4104-47-6 ]
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[ 786709-32-8 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 3 steps
1.1: (R)-2,2'-isopropylidenebis(4-phenyl-2-oxazoline); Cu(OTf)2 / CH2Cl2 / 22 h / -85 °C
2.1: 0.5 h / 20 °C
3.1: O3 / methanol / 0.75 h / -78 °C
3.2: NaBH4 / methanol / -78 - 20 °C |
|
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Multi-step reaction with 3 steps
1.1: 68 percent / (R)-2,2'-isopropylidenebis(4-phenyl-2-oxazoline); Cu(OTf)2 / CH2Cl2 / 25 h / -85 °C
2.1: 0.5 h / 20 °C
3.1: O3 / methanol / 0.75 h / -78 °C
3.2: NaBH4 / methanol / -78 - 20 °C |
|
Reference:
[1]Bayer, Annette; Endeshaw, Molla Mellese; Gautun, Odd R.
[Journal of Organic Chemistry, 2004, vol. 69, # 21, p. 7198 - 7205]
[2]Bayer, Annette; Endeshaw, Molla Mellese; Gautun, Odd R.
[Journal of Organic Chemistry, 2004, vol. 69, # 21, p. 7198 - 7205]
- 6
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(1S,3R)-3,6-dihydro-3-methyl-2-tosyl-1λ4,2-thiazine 1-oxide
[ No CAS ]
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[ 786709-32-8 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1.1: 0.5 h / 20 °C
2.1: O3 / methanol / 0.75 h / -78 °C
2.2: NaBH4 / methanol / -78 - 20 °C |
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- 7
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[ 786709-29-3 ]
-
[ 786709-32-8 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1.1: 0.5 h / 20 °C
2.1: O3 / methanol / 0.75 h / -78 °C
2.2: NaBH4 / methanol / -78 - 20 °C |
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- 8
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[ 786709-32-8 ]
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[ 214190-58-6 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1: K2CO3 / acetone
2: CuI / diethyl ether |
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- 9
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[ 786709-32-8 ]
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N-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methyl-N-((R)-1-methyl-dec-9-enyl)-benzenesulfonamide
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 3 steps
1: K2CO3 / acetone
2: CuI / diethyl ether
3: NaH |
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- 10
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1-(1-phenylvinyl)hexahydrothiopyrylium tetraphenylborate
[ No CAS ]
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[ 786709-32-8 ]
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(+)-(3R,5S)-3-methyl-5-phenyl-4-tosylmorpholine
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
72% |
With caesium carbonate In dichloromethane at 20℃; for 6h; regioselective reaction; |
|
Reference:
[1]Matlock, Johnathan V.; Svejstrup, Thomas D.; Songara, Pradip; Overington, Sarah; McGarrigle, Eoghan M.; Aggarwal, Varinder K.
[Organic Letters, 2015, vol. 17, # 20, p. 5044 - 5047]
- 11
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1-(1-phenylvinyl)hexahydrothiopyrylium tetraphenylborate
[ No CAS ]
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[ 786709-32-8 ]
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(+)-(3R,5S)-3-methyl-5-phenyl-4-tosylmorpholine
[ No CAS ]
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C18H21NO3S
[ No CAS ]
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(2S,5R)-trans-5-methyl-4-(4-methylbenzenesulfonyl)-2-phenylmorpholine
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
1: 31%
2: 14% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0 - 20℃; for 21h; Inert atmosphere; diastereoselective reaction; |
|
Reference:
[1]Matlock, Johnathan V.; Svejstrup, Thomas D.; Songara, Pradip; Overington, Sarah; McGarrigle, Eoghan M.; Aggarwal, Varinder K.
[Organic Letters, 2015, vol. 17, # 20, p. 5044 - 5047]
- 12
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[ 1590449-58-3 ]
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[ 786709-32-8 ]
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C32H38N2O8S
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
98 % de |
With silver trifluoromethanesulfonate In neat (no solvent) at 20℃; for 10h; Inert atmosphere; stereoselective reaction; |
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- 13
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[ 1590450-42-2 ]
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[ 786709-32-8 ]
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C32H37ClN2O8S
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
96 % de |
With silver trifluoromethanesulfonate In neat (no solvent) at 20℃; for 10h; Inert atmosphere; stereoselective reaction; |
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- 14
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[ 786709-32-8 ]
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(2S,5R)-trans-5-methyl-4-(4-methylbenzenesulfonyl)-2-phenylmorpholine
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 4 steps
1: silver trifluoromethanesulfonate / neat (no solvent) / 10 h / 20 °C / Inert atmosphere
2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere
3: triethylamine; dmap / dichloromethane / 10 h / 20 °C / Inert atmosphere
4: potassium carbonate / acetonitrile / 48 h / 20 °C / Inert atmosphere |
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- 15
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[ 786709-32-8 ]
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(2S,5R)-trans-2-(4-chlorophenyl)-5-methyl-4-(4-methylbenzenesulfonyl)morpholine
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 4 steps
1: silver trifluoromethanesulfonate / neat (no solvent) / 10 h / 20 °C / Inert atmosphere
2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere
3: triethylamine; dmap / dichloromethane / 10 h / 20 °C / Inert atmosphere
4: potassium carbonate / acetonitrile / 48 h / 20 °C / Inert atmosphere |
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- 16
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[ 786709-32-8 ]
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C18H22ClNO4S
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1: silver trifluoromethanesulfonate / neat (no solvent) / 10 h / 20 °C / Inert atmosphere
2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere |
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- 17
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[ 786709-32-8 ]
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C25H28ClNO6S2
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 3 steps
1: silver trifluoromethanesulfonate / neat (no solvent) / 10 h / 20 °C / Inert atmosphere
2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere
3: triethylamine; dmap / dichloromethane / 10 h / 20 °C / Inert atmosphere |
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- 18
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[ 786709-32-8 ]
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C18H23NO4S
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1: silver trifluoromethanesulfonate / neat (no solvent) / 10 h / 20 °C / Inert atmosphere
2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere |
|
- 19
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[ 786709-32-8 ]
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C25H29NO6S2
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 3 steps
1: silver trifluoromethanesulfonate / neat (no solvent) / 10 h / 20 °C / Inert atmosphere
2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere
3: triethylamine; dmap / dichloromethane / 10 h / 20 °C / Inert atmosphere |
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- 20
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[ 932-87-6 ]
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[ 786709-32-8 ]
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(R)-N-(1-hydroxypropan-2-yl)-4-methyl-N-(phenylethynyl)benzenesulfonamide
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
32% |
With 1,10-Phenanthroline; copper(ll) sulfate pentahydrate; potassium carbonate In toluene at 80℃; for 12h; Inert atmosphere; |
|
Reference:
[1]Ao, Chaoqun; Yang, Xiaohan; Jia, Shikun; Xu, Xinfang; Yuan, Yanqiu; Zhang, Dan; Hu, Wenhao
[Journal of Organic Chemistry, 2019, vol. 84, # 23, p. 15331 - 15342]
- 21
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[ 786709-32-8 ]
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(R)-2-((4-methylphenyl)sulfonamido)propyl-(Z)-2-(1-methyl-2-oxoindolin-3-ylidene)-2-phenylacetate
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1: potassium carbonate; 1,10-Phenanthroline; copper(ll) sulfate pentahydrate / toluene / 12 h / 80 °C / Inert atmosphere
2: zinc trifluoromethanesulfonate / 1,2-dichloro-ethane / 40 °C / Molecular sieve |
|
Reference:
[1]Ao, Chaoqun; Yang, Xiaohan; Jia, Shikun; Xu, Xinfang; Yuan, Yanqiu; Zhang, Dan; Hu, Wenhao
[Journal of Organic Chemistry, 2019, vol. 84, # 23, p. 15331 - 15342]