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Chemical Structure| 794485-43-1 Chemical Structure| 794485-43-1

Structure of 794485-43-1

Chemical Structure| 794485-43-1

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Product Details of [ 794485-43-1 ]

CAS No. :794485-43-1
Formula : C12H10N4
M.W : 210.23
SMILES Code : N1=CNC(=C1)C=2C=CC=C(C2)C3=CN=CN3

Safety of [ 794485-43-1 ]

Application In Synthesis of [ 794485-43-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 794485-43-1 ]

[ 794485-43-1 ] Synthesis Path-Downstream   1~3

  • 1
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 610-09-3 ]
  • [ 794485-43-1 ]
  • [Zn(1,3-di(1H-imidazol-4-yl)benzene)(cis-1,2-cyclohexanedicarboxylic acid)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
49% With sodium hydroxide; In water; at 100℃; for 72h;High pressure; A mixture of L (21.0mg, 0.1mmol), Zn(NO3)2·6H2O (29.7mg, 0.1mmol), 1,2-H2CHDA (17.2mg, 0.1mmol) and NaOH (8.0mg, 0.2mmol) in 10mL of H2O was sealed in a 16mL Teflon lined stainless steel container and heated at 100C for 3d. After the reaction mixture was cooled to room temperature, block crystals of 1 were collected with a yield of 49% by filtration and washed with water and ethanol several times. Anal. Calc. for C20H20N4O4Zn: C, 53.89, H, 4.52, N, 12.57. Found: C, 53.71, H, 4.68, N, 12.36%. IR (KBr pellet, cm-1): 3423 (w, br), 3107-2852 (m), 1572 (s), 1474 (s), 1447 (s), 1421 (s), 1347 (m), 1296 (m), 1195 (w), 1142 (s), 971 (m), 876 (w), 838 (m), 649 (m), 589 (w), 501 (w), 416 (w).
  • 2
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 610-09-3 ]
  • [ 794485-43-1 ]
  • [ 7732-18-5 ]
  • [Cd(1,3-di(1H-imidazol-4-yl)benzene)(cis-1,2-cyclohexanedicarboxylic acid)]*3H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
41% With sodium hydroxide; at 100℃; for 72h;High pressure; General procedure: A mixture of L (21.0mg, 0.1mmol), Zn(NO3)2·6H2O (29.7mg, 0.1mmol), 1,2-H2CHDA (17.2mg, 0.1mmol) and NaOH (8.0mg, 0.2mmol) in 10mL of H2O was sealed in a 16mL Teflon lined stainless steel container and heated at 100C for 3d. After the reaction mixture was cooled to room temperature, block crystals of 1 were collected with a yield of 49% by filtration and washed with water and ethanol several times. Anal. Calc. for C20H20N4O4Zn: C, 53.89, H, 4.52, N, 12.57. Found: C, 53.71, H, 4.68, N, 12.36%. IR (KBr pellet, cm-1): 3423 (w, br), 3107-2852 (m), 1572 (s), 1474 (s), 1447 (s), 1421 (s), 1347 (m), 1296 (m), 1195 (w), 1142 (s), 971 (m), 876 (w), 838 (m), 649 (m), 589 (w), 501 (w), 416 (w).
  • 3
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 610-09-3 ]
  • [ 794485-43-1 ]
  • [ 7732-18-5 ]
  • [Cd2(1,3-di(1H-imidazol-4-yl)benzene)2(cis-1,2-cyclohexanedicarboxylic acid)2]*3H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
38% With sodium hydroxide; at 180℃; for 72h;High pressure; General procedure: A mixture of L (21.0mg, 0.1mmol), Zn(NO3)2·6H2O (29.7mg, 0.1mmol), 1,2-H2CHDA (17.2mg, 0.1mmol) and NaOH (8.0mg, 0.2mmol) in 10mL of H2O was sealed in a 16mL Teflon lined stainless steel container and heated at 100C for 3d. After the reaction mixture was cooled to room temperature, block crystals of 1 were collected with a yield of 49% by filtration and washed with water and ethanol several times. Anal. Calc. for C20H20N4O4Zn: C, 53.89, H, 4.52, N, 12.57. Found: C, 53.71, H, 4.68, N, 12.36%. IR (KBr pellet, cm-1): 3423 (w, br), 3107-2852 (m), 1572 (s), 1474 (s), 1447 (s), 1421 (s), 1347 (m), 1296 (m), 1195 (w), 1142 (s), 971 (m), 876 (w), 838 (m), 649 (m), 589 (w), 501 (w), 416 (w).
 

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