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Chemical Structure| 84175-10-0 Chemical Structure| 84175-10-0

Structure of 84175-10-0

Chemical Structure| 84175-10-0

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Product Details of [ 84175-10-0 ]

CAS No. :84175-10-0
Formula : C12H12N2O4
M.W : 248.23
SMILES Code : COC1=CC=[N+]([O-])C(C2=CC(OC)=CC=[N+]2[O-])=C1

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Application In Synthesis of [ 84175-10-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 84175-10-0 ]

[ 84175-10-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 84175-10-0 ]
  • [ 17217-57-1 ]
YieldReaction ConditionsOperation in experiment
19% A mixture of 4,4?-dimethoxy-2,2?-bipyridine1,1?-dioxide (10) (2.50 g, 10.1 mmol), palladium on carbon (5percentPd, 5.16 g, 2.42 mmol, 0.24 equiv),and ethanol (290 mL) was refluxed for 5 min. To the mixture an ethanol solution (170 mL) ofhydrazine monohydrate (39.3 g, 0.785 mol) was added dropwise over 1 h. The reaction mixture wasrefluxed for 18 h and filtered through Celite®. The residue on the Celite was washed with hotethanol. Evaporation of the solvent from the combined filtrate and washings, and recrystallization ofthe residue from methanol gave 7f (0.412 g, 19percent). 7f: pale yellow crystals. 1H NMR (300 MHz,CDCl3) delta 8.48 (d, J = 5.4 Hz, 2H), 7.98 (d, J = 2.4 Hz, 2H), 6.86 (dd, J = 5.4 Hz, 2.4 Hz, 2H), 3.96(s, 6H).
 

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