Home Cart Sign in  
Chemical Structure| 859851-01-7 Chemical Structure| 859851-01-7

Structure of 859851-01-7

Chemical Structure| 859851-01-7

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 859851-01-7 ]

CAS No. :859851-01-7
Formula : C7H8O3S
M.W : 172.20
SMILES Code : OCC1=C2C(OCCO2)=CS1

Safety of [ 859851-01-7 ]

Application In Synthesis of [ 859851-01-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 859851-01-7 ]

[ 859851-01-7 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 204905-77-1 ]
  • [ 859851-01-7 ]
YieldReaction ConditionsOperation in experiment
Under argon atmosphere, NaBH4 (0.40 g, 10.59 mmol) was added to a solution of EDOT-CHO (1.50 g, 8.82 mmol) in 92 mL of a mixture of CH2Cl2/ MeOH (1:1) and stirred at room temperature for 1h. The reaction was hydrolized with water and the aqueous phase extracted with chloroform. The organic phase was dried over MgSO4, and the solvent was removed under vacuum. Without further purification, the obtained alcohol (1.60 g, 9.3 mmol) was added over a mixture of triethylphosphate (2 mL/mmol) and iodine (2.36 g, 9.3 mmol). The reaction mixture was cooled at -20ºC and stirred for 2 hours and afterwards overnight at r.t. After removal of triethyl phosphate at reduced pressure, the crude was purified by column chromatography (silica gel, hexane:AcOEt, 1:1) giving 2.60 g of EDOT-phosphonate 3 as yellow oil (95% yield).
  • 2
  • [ 859851-01-7 ]
  • [ 204905-77-1 ]
 

Historical Records