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Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
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CAS No. : | 88040-86-2 | MDL No. : | MFCD00060552 |
Formula : | C8H9ClO3S | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 220.67 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P321-P363-P405-P501 | UN#: | 1759 |
Hazard Statements: | H314 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
64% | With chlorosulfonic acid at 0 - 23℃; for 5.5h; | |
64% | With chlorosulfonic acid at 0 - 20℃; Schlenk technique; Inert atmosphere; | |
61% | With chlorosulfonic acid at 0 - 25℃; for 0.5h; |
With chlorosulfonic acid at 0℃; | ||
With chlorosulfonic acid for 3h; Ambient temperature; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
EXAMPLE 18 5-Methyl-2-methoxyl-[4-(1-piperazinyl)-1H-indol-1-yl]sulfonyl}phenyl Ether Hydrochloride (Scheme 1) The title compound was prepared from 4-(4-boc-piperazinyl)-indole and 5-methyl-2-methoxyphenylsulfonyl chloride according to Method 3: 1H NMR (270 MHz, DMSO-d6) delta 9.45 (br, 1H), 7.92 (d, J=8 Hz, 1H), 7.70 (d, J=5 Hz, 1H), 7.30 (d, J=8 Hz, 1H), 7.13 (t,J=8Hz, 1H), 7.01-6.92 (m, 2H), 6.83 (d,J=5Hz, 1H), 6.73 (d,J=8Hz, 1H), 3.70 (s, 3H), 3.26 (m, 8H), 3.32 (s, 3H); MS (ESI+) for m/z 386 (M+H)+. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
54% | With sodium hydrogencarbonate In diethyl ether; water at 20℃; for 72h; | 14.a a) a) 3-(2-Methoxy-5-methylphenylsulfonyloxy)-5-methylphenol To a solution of 1.00 g (8.05 mmol) of orcinol monohydrate and 1.63 g (7.38 mmol) of 2-methoxy-m-toluenesulfonyl chloride in 20 mL of diethyl ether was added 20 mL of saturated aqueous NaHCO3 and the biphasic mixture stirred vigorously at ambient temperature for 3 days. The layers were separated and the aqueous layer extracted with 2 x 30 mL of ethyl acetate. The combined organic layers were washed with 50 mL of brine, dried (Na2SO4) and concentrated to give 2.2 g of an orange syrup. Crystallization from dichloromethane-hexane (two crops) afforded 1.24 g (54%) of the title compound as a light orange powder: 1H-NMR (300 MHz; CDCl3) δ 7.62 (d, 1 H, J = 2.0 Hz), 7.40 (m, 1 H), 6.96 (d, 1 H, J = 8.5 Hz), 6.52 (m, 2 H), 6.42 (t, 1 H, J = 2.1 Hz), 5.13 (s, 1 H), 3.96 (s, 3 H), 2.29 (s, 3 H) and 2.23 (s, 3 H). |