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[ CAS No. 887587-50-0 ]

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type HazMat fee
Excepted Quantity Free
Inaccessible (Haz class 6.1), Domestic USD 41.00
Inaccessible (Haz class 6.1), International USD 64.00
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 83.00
Accessible (Haz class 3, 4, 5 or 8), International USD 133.00
Chemical Structure| 887587-50-0
Chemical Structure| 887587-50-0
Structure of 887587-50-0 * Storage: {[proInfo.prStorage]}

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Product Details of [ 887587-50-0 ]

CAS No. :887587-50-0 MDL No. :MFCD07783793
Formula : C11H7BrClNO2 Boiling Point : -
Linear Structure Formula :- InChI Key :N/A
M.W :300.54 g/mol Pubchem ID :-
Synonyms :

Safety of [ 887587-50-0 ]

Signal Word:Danger Class:6.1
Precautionary Statements:P261-P264-P270-P271-P280-P302+P352-P304+P340-P310-P330-P361-P403+P233-P405-P501 UN#:2811
Hazard Statements:H301-H311-H331 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 887587-50-0 ]

  • Downstream synthetic route of [ 887587-50-0 ]

[ 887587-50-0 ] Synthesis Path-Downstream   1~7

  • 1
  • [ 929-59-9 ]
  • [ 887587-50-0 ]
  • [ 1259093-42-9 ]
YieldReaction ConditionsOperation in experiment
84% With toluene-4-sulfonic acid In methanol; chloroform at 20℃; for 24h;
  • 2
  • [ 887587-50-0 ]
  • [ 930-69-8 ]
  • [ 1259093-43-0 ]
YieldReaction ConditionsOperation in experiment
In N,N-dimethyl-formamide at 20℃;
  • 3
  • [ 887587-50-0 ]
  • [ 5188-07-8 ]
  • [ 1259093-41-8 ]
YieldReaction ConditionsOperation in experiment
85% In N,N-dimethyl-formamide at 20℃; for 3h;
  • 4
  • methyl 6-bromo-4-oxo-1,4-dihydroquinoline-2-carboxylate [ No CAS ]
  • [ 887587-50-0 ]
YieldReaction ConditionsOperation in experiment
95% With trichlorophosphate at 100℃; for 1.5h;
  • 5
  • [ 1694-31-1 ]
  • [ 887587-50-0 ]
  • methyl 6-bromo-4-(1-(tert-butoxy)-1,3-dioxobutan-2-yl)quinoline-2-carboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
34% With caesium carbonate In dimethyl sulfoxide at 100℃; for 0.333333h; 1 Step 1 : Methyl 6-bromo-4-(l-(tert 2-yl)quinoline-2-carboxylate fert-Butyl 3-oxobutanoate (0.083 mL, 0.50 mmol), methyl 6-bromo-4- chloroquinoline-2-carboxylate (15 mg, 0.050 mmol) and cesium carbonate (33 mg, 0.10 mmol) in DMSO (0.5 mL) were heated to 100 °C. After 20 min, the reaction mixture was diluted with water (5 mL), extracted with ethyl acetate (2 xlO mL), dried over Na2S04, filtered, and concentrated. The reaction mixture was purified using silica gel chromatography to isolate methyl 6-bromo-4-(l-(tert-butoxy)-l,3-dioxobutan-2- yl)quinoline-2-carboxylate (7.2 mg, 34% yield). MS (ESI) m/z: 422 A [M+H]+; NMR (500 MHz, CDCh) δ 8.23-8.17 (m, IH), 8.06-8.03 (m, IH), 8.03-8.00 (m, IH), 7.89-7.84 (m, IH), 4.13-4.10 (s, 3H), 4.04-4.02 (m, IH), 1.85 (s, 3H), 1.31-1.26 (m, 9H).
  • 6
  • [ 887587-50-0 ]
  • methyl 6-bromo-4-(2-oxopropyl)quinoline-2-carboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: caesium carbonate / dimethyl sulfoxide / 0.33 h / 100 °C 2: trifluoroacetic acid / dichloromethane / 3 h
  • 7
  • [ 887587-50-0 ]
  • methyl 6-bromo-4-(2-hydroxypropyl)quinoline-2-carboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: caesium carbonate / dimethyl sulfoxide / 0.33 h / 100 °C 2: trifluoroacetic acid / dichloromethane / 3 h 3: methanol; sodium tetrahydroborate / 0.25 h
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