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Chemical Structure| 889869-30-1 Chemical Structure| 889869-30-1

Structure of 889869-30-1

Chemical Structure| 889869-30-1

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Product Details of [ 889869-30-1 ]

CAS No. :889869-30-1
Formula : C9H9Br
M.W : 197.07
SMILES Code : CC1=CC=CC=C1/C=C/Br
MDL No. :MFCD09032576

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Application In Synthesis of [ 889869-30-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 889869-30-1 ]

[ 889869-30-1 ] Synthesis Path-Downstream   1~5

  • 2
  • [ 201230-82-2 ]
  • [ 889869-30-1 ]
  • [ 939-57-1 ]
  • 3
  • [ 1006-68-4 ]
  • [ 889869-30-1 ]
  • [ 1059544-26-1 ]
  • 4
  • [ 2243-82-5 ]
  • [ 889869-30-1 ]
  • [ 1393689-87-6 ]
  • 5
  • [ 939-57-1 ]
  • [ 889869-30-1 ]
  • [ 87212-83-7 ]
YieldReaction ConditionsOperation in experiment
With ammonium bromide; In water; acetonitrile; at 75℃; for 1h;Electrochemical reaction; General procedure: Substrate 1 (0.5mmol), NH4Br (3mmol) were added to an undivided cell which equipped with platinum anode and cathode. Followed by addition of MeCN (7mL) and H2O (3mL). The mixture was electrolyzed under continuous stirring at 75C under a constant current of 40mA for 1h. The solution was cooled to r.t., condensed under vacuum, extracted with DCM (3×10mL), washed with saturated sodium chloride solution. And the organic layers were dried over Na2SO4, filtered and evaporated under vacuum. The residue was purified by column chromatography on silica gel (petroleum ether:ethyl acetate=50:1-30:1) to afford the desired product 3.
 

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